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We report on the magnetic and Mossbauer properties of polycrystalline HoFe1-xCrxO3 compounds. Magnetization data reveals the continuous tailoring of magnetic transition due to weakening of Ho3+ Fe3+ and Fe3+ Fe3+ interactions in the entire…

Materials Science · Physics 2017-03-08 Ganesh Kotnana , V. Raghavendra Reddy , S. Narayana Jammalamadaka

The electronic structure and magnetism of chromia (corundum-type Cr2O3) are studied using full-potential first-principles calculations. The electronic correlations are included within the LSDA+U method. The energies of different magnetic…

Materials Science · Physics 2009-03-08 Siqi Shi , A. L. Wysocki , K. D. Belashchenko

LiCu$_3$O$_3$ is a novel 2D S=1/2 antiferromagnet with randomly depleted square lattice. The crystal structure contains two types of square planes with different Cu$^{2+}\rightarrow$ Li$^{+}$ substitution rates (20% and 40%). $^7$Li NMR and…

Strongly Correlated Electrons · Physics 2024-09-09 A. A. Bush , S. K. Gotovko , V. Yu. Ivanov , V. I. Kozlov , E. G. Nikolaev , L. E. Svistov

We perform a symmetry analysis of the ABC-stacked kagome planes of Mn atoms common to the $L1_2$ Mn$_3$X and antiperovskite Mn$_3$AB alloys. In addition to the single-ion-anisotropy and Kitaev-type anisotropic exchange known to stabilize…

Strongly Correlated Electrons · Physics 2023-02-22 J. S. R. McCoombs , A. Zelenskiy , M. L. Plumer , B. W. Southern , T. L. Monchesky

We report single crystal growth and magnetic susceptibility and neutron diffraction studies of the S=1/2 quasi-1D antiferromagnet CaCu2O3. The structure of this material is similar to that of the prototype two-leg spin-ladder compound…

Condensed Matter · Physics 2009-10-31 V. Kiryukhin , Y. J. Kim , K. J. Thomas , F. C. Chow , R. W. Erwin , Q. Huang , M. A. Kastner , R. J. Birgeneau

The dc magnetization (M) and electrical resistivity (\rho) as functions of magnetic field and temperature are reported for a series of lightly electron dopedCa(1-x)La(x)MnO(3) (0<=x<=0.10) specimens for which magnetization [Phys. Rev. B…

Strongly Correlated Electrons · Physics 2007-05-23 C. Chiorescu , J. J. Neumeier , J. L. Cohn

To elucidate the spin dynamics of La$_{2-x}$Sr$_x$CuO$_4$, which couples with the charge degree of freedom, the spin excitations spanning the characteristic energy ($E_{\rm cross}$ $\sim$35-40 meV) are investigated for underdoped $x$ = 0.10…

The dimensionality of the electronic and magnetic structure of a given material is generally predetermined by its crystal structure. Here, using elastic and inelastic neutron scattering combined with magnetization measurements, we find…

We report magnetization measurements, full-potential band structure calculations, and microscopic modeling for the spin-1/2 Heisenberg magnets A2CuP2O7 (A = Na, Li). Based on a quantitative evaluation of the leading exchange integrals and…

Strongly Correlated Electrons · Physics 2011-11-30 S. Lebernegg , A. A. Tsirlin , O. Janson , R. Nath , Yu. Skourski , G. Amthauer , H. Rosner

We have deployed density functional theory, Wannier function analysis and mean-field calculations to investigate the double-double perovskite compound CaMnCrSbO_{6}. The crystallographically non-equivalent Mn atoms in the unit cell have…

Materials Science · Physics 2022-06-14 Rakshanda Dhawan , Padmanabhan Balasubramanian , Tashi Nautiyal

The complex magnetic structures, spin-reorientation and associated exchange interactions have been investigate in Er$_{0.5}$Dy$_{0.5}$FeO$_3$ using bulk magnetization, neutron diffraction, specific heat measurements and density functional…

Strongly Correlated Electrons · Physics 2022-07-13 Sarita Rajput , Padmanabhan Balasubramanian , Ankita Singh , Francoise Damay , C. M. N. Kumar , W. Tabis , T. Maitra , V. K. Malik

YBaCo4O7 belongs to a new class of geometrically frustrated magnets like the pyrochlores, in which Co-spins occupy corners of tetrahedra. The structure can be viewed as an alternating stacking of Kagome and triangular layers. Exactly half…

Materials Science · Physics 2009-11-11 L. C. Chapon , P. G. Radaelli , H. Zheng , J. F. Mitchell

Two new transition-metal tellurium oxy-chlorides of the general formula Ni_5(TeO_3)_4X_2 (X=Cl, Br) have been isolated during the investigation of the ternary phase diagram NiO-NiCl2-TeO2. They crystallize in the monoclinic system, space…

Strongly Correlated Electrons · Physics 2010-03-09 M. Johnsson , K. W. Toernroos , P. Lemmens , P. Millet

The magnetic behavior of a solid solution, Ca3-xYxCo2O6, based on an exotic spin-chain compound, Ca3Co2O6, crystallizing in K4CdCl6-derived rhombohedral structure is investigated. Among the compositions investigated (x= 0.0, 0.3, 0.5, 0.75…

Strongly Correlated Electrons · Physics 2009-11-11 S. Rayaprol , E. V. Sampathkumaran

Magnetic ordering phenomena have a profound influence on the macroscopic properties of correlated-electron materials, but their realistic prediction remains a formidable challenge. An archetypical example is the ternary nickel oxide system…

Interesting magnetic properties and spin-exchange interactions along various possible pathways in half-integral spin quantum magnetic tetramer system: A$_{2}$PO$_{4}$OH (A = Co, Cu) are investigated. Interplay of structural distortion and…

Materials Science · Physics 2015-06-05 Debjani Karmakar , J. V. Yakhmi

We performed susceptibility, magnetization, specific heat, and single crystal neutron diffraction measurements on single crystalline BaMn$_2$Si$_2$O$_7$. Based on the results, we revisited its spin structure with a more accurate solution…

Strongly Correlated Electrons · Physics 2019-07-31 G. H. Wang , C. Y. Xu , H. B. Cao , T. Hong , Q. Huang , Q. Y. Ren , J. Q. Xu , H. D. Zhou , W. D. Luo , D. Qian , J. Ma

We investigate how the ligand substitution affects the intra-molecular spin exchange interactions, studying a prototypal family of single-molecule magnets comprising dodecanuclear cluster molecules [Mn12O12(COOR)16]. We identify a simple…

Strongly Correlated Electrons · Physics 2011-03-08 D. W. Boukhvalov , V. V. Dobrovitski , P. Kögerler , M. Al-Saqer , M. I. Katsnelson , A. I. Lichtenstein , B. N. Harmon

Electronic structure of strongly correlated transition metal oxides (TMOs) is a complex phenomenon due to competing interaction among the charge, spin, orbital and lattice degrees of freedom. Often individual compounds are examined to…

Strongly Correlated Electrons · Physics 2018-10-17 Priyadarshini Parida , Ravi Kashikar , Ajit Jena , B. R. K. Nanda

Recent magnetic measurements on tetra-nickel molecular magnets [Ni(hmp)(ROH)Cl]$_4$, where R=CH$_3$, CH$_2$CH$_3$, or (CH$_2$)$_2$C(CH$_3$)$_3$ and hmp$^-$ is the monoanion of 2-hydroxymethylpyridine, revealed a strong exchange bias prior…

Materials Science · Physics 2009-11-10 Kyungwha Park , En-Che Yang , David N. Hendrickson