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Ferromagnetism was recently observed at unexpectedly high temperatures in La-doped CaB_6. The starting point of all theoretical proposals to explain this observation is a semimetallic electronic structure calculated for CaB_6 within the…

Condensed Matter · Physics 2016-08-31 H. J. Tromp , P. van Gelderen , P. J. Kelly , G. Brocks , P. A. Bobbert

We present a consistent overall picture of the electronic structure and ferromagnetic interaction in CaB$_6$, based on our joint transport, optical, and tunneling measurements on high-quality {\em defect-controlled} single crystals. Pure…

Strongly Correlated Electrons · Physics 2007-05-23 Jong-Soo Rhyee , B. H. Oh , B. K. Cho , M. H. Jung , H. C. Kim , Y. K. Yoon , Jae Hoon Kim , T. Ekino

We investigate the temperature evolution of the electronic structure of ferromagnetic CaB$_6$ using ultra-high resolution photoemission spectroscopy; electronic structure of paramagnetic LaB$_6$ is used as a reference. High resolution…

Materials Science · Physics 2009-11-13 Kalobaran Maiti , V. R. R. Medicherla , Swapnil Patil , Ravi Shankar Singh

We report calculations of the electronic structure of CaB$_6$ using the weighted density approximation (WDA) to density functional theory. We find a semiconducting band structure with a sizable gap, in contrast to local density…

Strongly Correlated Electrons · Physics 2009-11-10 Z. Wu , D. J. Singh , R. E. Cohen

The formation energy and local magnetic moment of a series of point defects in CaB$_6 $ are computed using a supercell approach within the generalized gradient approximation to density functional theory. Based on these results, speculations…

Materials Science · Physics 2009-11-07 R. Monnier , B. Delley

The heavy fermion material CeB6 shows hidden magnetic ordered phases. Besides well-known Ferromagnetic(FM) and Antiferromagnetic(AFM) phases, CeB6 is speculated to form a unique antiferroquadrupolar (AFQ) phase that is orbital in nature.…

Strongly Correlated Electrons · Physics 2016-12-14 C. K. Barman , Prashant Singh , D. D. Johnson , Aftab Alam

Electron-hole mixing-induced fine structure in alkaline earth hexaborides leads to lower energy (temperature) scales, and thus stronger tendency toward an excitonic instability, than in their doped counterparts (viz. Ca(1-x)La(x)B(6),…

Strongly Correlated Electrons · Physics 2009-10-31 C. O. Rodriguez , Ruben Weht , W. E. Pickett

Ge$_{1-x}$Fe$_{x}$ (Ge:Fe) shows ferromagnetic behavior up to a relatively high temperature of 210 K, and hence is a promising material for spintronic applications compatible with Si technology. We have studied its electronic structure by…

The electronic structure and the magnetism of the novel ferromagnetic semiconductor (Ga,Fe)Sb, whose Curie temperature $T_{\rm C}$ can exceed room temperature, were investigated by means of x-ray absorption spectroscopy (XAS), x-ray…

Cr2Ge2Te6 is an intrinsic ferromagnetic semiconductor with van der Waals type layered structure, thus represents a promising material for novel electronic and spintronic devices. Here we combine scanning tunneling microscopy and…

Materials Science · Physics 2019-05-08 Zhenqi Hao , Haiwei Li , Shunhong Zhang , Xintong Li , Gaoting Lin , Xuan Luo , Yuping Sun , Zheng Liu , Yayu Wang

A ferromagnet with a small spontaneous moment but with a high Curie temperature can be obtained by doping an excitonic insulator made from a spin triplet exciton condensate. Such a condensate can occur in a semimetal with a small overlap or…

Strongly Correlated Electrons · Physics 2009-10-31 M. E. Zhitomirsky , T. M. Rice , V. I. Anisimov

Some doped semiconductors have recently been shown to display superconductivity or weak ferromagnetism. Here we investigate the electronic structure and conditions for magnetism in a supercells of cubic XW_{26}O_{81}, where X=Nb,V and Re.…

Materials Science · Physics 2016-08-31 T. Jarlborg

The electronic structure of the heavy fermion compound CeB6 is probed by resonant inelastic soft X-ray scattering using photon energies across the Ce 3d and 4d absorption edges. The hybridization between the localized 4f orbitals and the…

Materials Science · Physics 2012-01-04 M. Magnuson , S. M. Butorin , J. -H. Guo , A. Agui , J. Nordgren , H. Ogasawara , A. Kotani , T. Takahashi , S. Kunii

A review of new developments in theoretical and experimental electronic structure investigations of half-metallic ferromagnets (HMF) is presented. Being semiconductors for one spin projection and metals for another ones, these substances…

Materials Science · Physics 2008-09-17 M. I. Katsnelson , V. Yu. Irkhin , L. Chioncel , A. I. Lichtenstein , R. A. de Groot

Fully understanding the properties of n-type ferromagnetic semiconductors (FMSs), complementary to the mainstream p-type ones, is a challenging goal in semiconductor spintronics because ferromagnetism in n-type FMSs is theoretically…

We have analyzed the electronic structure of half-metallic magnets based on first principles electronic structure calculations of a series of semi-Heusler alloys. The characteristic feature of the electronic structure of semi-Heusler…

Materials Science · Physics 2007-05-23 B. R. K. Nanda , I. Dasgupta

Cerium-hexaboride (CeB$_6$) f-electron compound displays a rich array of low-temperature magnetic phenomena, including `magnetically hidden' order, identified as multipolar in origin via advanced x-ray scattering. From first-principles…

Materials Science · Physics 2019-02-27 Chanchal Barman , Prashant Singh , Duane D. Johnson , Aftab Alam

The realization of bulk metallic altermagnetism has remained elusive despite the growing number of candidate materials. Here, we present evidence that moderate cobalt substitution ($\sim$15%) drives the correlated narrow-gap semiconductor…

We present electronic band structure of Ag$_5$Pb$_2$O$_6$ with layered hexagonal structure containing one-dimensional chains and two-dimensional Kagom\'{e} layers of silver. A half-filled conduction band shows extremely simple, single…

Strongly Correlated Electrons · Physics 2009-11-11 Tamio Oguchi

We present angle-resolved photoemission studies on the rare-earth hexaboride YbB$_6$, which has recently been predicted to be a topological Kondo insulator. Our data do not agree with the prediction and instead show that YbB$_6$ exhibits a…

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