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Related papers: The Structure and Dynamics of Flexible Polyelectro…

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We investigate end-effects in the ion distribution around strongly charged, flexible polyelectrolytes with a quenched charge distribution by molecular dynamics simulations of dilute polyelectrolyte solutions. We take the counterions…

Soft Condensed Matter · Physics 2015-06-24 Hans Jörg Limbach , Christian Holm

We investigate the band-gap structure of the frequency spectrum for elastic waves in a high-contrast, two-component periodic elastic medium. We consider two-dimensional phononic crystals consisting of a background medium which is perforated…

Analysis of PDEs · Mathematics 2007-05-23 H. Ammari , H. Kang , H. Lee

We combine small angle scattering experiments and simulations to investigate the internal structure and interactions of composite Poly(N-isopropylacrylamide)-Poly(ethylene glycol) (PNIPAM-PEG) microgels. At low temperatures the…

In this study, we propose a theoretical framework to investigate the interactions between flexible polymer chains, specifically polyelectrolytes (PEs). By calculating the system's free energy while considering position-dependent mutual…

Soft Condensed Matter · Physics 2024-05-13 Souradeep Ghosh

Although it has been established that the multi-chain slip-spring (MCSS) model can reproduce entangled polymer dynamics, the effects of model parameters have not been fully elucidated yet. In this study, we systematically investigated the…

Soft Condensed Matter · Physics 2020-11-09 Yuichi Masubuchi , Yuya Doi , Takashi Uneyama

Using Langevin dynamics simulations, we study elastic response of single semiflexible polyelectrolytes to an external force pulling on the chain ends, to mimic the stretching of DNA molecules by optical tweezers. The linear chains are…

Soft Condensed Matter · Physics 2019-06-19 Paul Cardenas-Lizana , Pai-Yi Hsiao

We show using Brownian dynamics simulations and theory how the shear relaxation modulus G(t) of dilute solutions of relatively stiff semiflexible polymers differs qualitatively from that of rigid rods. For chains shorter than their…

Soft Condensed Matter · Physics 2009-10-31 Matteo Pasquali , V. Shankar , David C. Morse

The non-linear response of entangled polymers to shear flow is complicated. Its current understanding is framed mainly as a rheological description in terms of the complex viscosity. However, the full picture requires an assessment of the…

Computational Physics · Physics 2018-08-21 Airidas Korolkovas , Philipp Gutfreund , Max Wolff

The structure optimization, phonon, and ab initio finite temperature molecular dynamics calculations have been performed to predict that bilayer silicene has stable structure with AB stacking geometry and is more favorable energetically to…

Mesoscale and Nanoscale Physics · Physics 2016-11-26 Wang Rui , Wang Shaofeng , Wu Xiaozhi

We study the conformation and dynamics of a single polymer chain that is pulled by a constant force applied at its one end with the other end free. Such a situation is relevant to the growing technology of manipulating individual…

Soft Condensed Matter · Physics 2015-06-04 Takahiro Sakaue , Takuya Saito , Hirofumi Wada

We present simulations on charged polymers in poor solvent. First we investigate in detail the dilute concentration range with and without imposed extension constraints. The resulting necklace polymer conformations are analyzed in detail.…

Soft Condensed Matter · Physics 2016-08-16 Hans Jörg Limbach , Christian Holm , Kurt Kremer

We study the swelling of a flexible linear chain composed of active particles by analytical theory and computer simulation. Three different situations are considered: a free chain, a chain confined to an external harmonic trap, and a chain…

Soft Condensed Matter · Physics 2015-03-31 Andreas Kaiser , Sonja Babel , Borge ten Hagen , Christian von Ferber , Hartmut Löwen

A variational approach is considered to calculate the free energy and the conformational properties of a polyelectrolyte chain in $d$ dimensions. We consider in detail the case of pure Coulombic interactions between the monomers, when…

Soft Condensed Matter · Physics 2007-05-23 G. Migliorini , V. G. Rostiashvili , T. A. Vilgis

Using molecular dynamics simulations we study the behavior of a dilute solution of strongly charged polyelectrolytes in poor solvents, where we take counterions explicitly into account. We focus on the chain conformational properties under…

Soft Condensed Matter · Physics 2007-05-23 H. -J. Limbach , C. Holm

We introduce a three-dimensional model for polyelectrolyte hydrogel filaments operating in a fluid environment under an electric field. The formulation builds on a morphoelastic framework for inextensible and unshearable rods, such that the…

Droplet coalescence is ubiquitous in nature and the same time key to various technologies, such as inkjet printing. Here, we report on the coalescence of polymer droplets with different chain lengths coalescing on substrates of different…

Soft Condensed Matter · Physics 2023-09-21 Soheil Arbabi , Panagiotis E. Theodorakis

Microfluidic channels are integral to biomedical technology and process engineering, offering versatility in handling fluids with complex properties, often a combination of viscous and elastic attributes. Despite significant advancements in…

Soft Condensed Matter · Physics 2025-09-29 Sampad Laha , Siddhartha Mukherjee , Suman Chakraborty

Single-chain elasticity is of fundamental importance in polymer physics, as it underlies many of the unique properties of polymer systems. Recently, there has been interest in characterizing the elastic properties of catenanes, molecular…

Soft Condensed Matter · Physics 2025-12-23 James M. Polson , Liam MacNevin , Alaaddin Elobeid , Carlos E. Padilla Robles

Polyelectrolytes in poor solvents show a necklace structure where collapsed polymer pearls are linked to stretched strings. In the present paper the elasticity of such chains is studied in detail. Different deformation regimes are…

Soft Condensed Matter · Physics 2007-05-23 T. A. Vilgis , A. Johner , J. -F. Joanny

We consider an electron-phonon system in two and three dimensions on square, hexagonal and cubic lattices. The model is a modification of the standard Holstein model where the optical branch is appropriately curved in order to have a…

Statistical Mechanics · Physics 2009-10-31 N. Macris , C. -A. Piguet