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The nonequilibrium fluctuation relation is a cornerstone of quantum thermodynamics. It is widely believed that the system-bath heat exchange obeys the famous Jarzynski-W\'{o}jcik fluctuation theorem. However, this theorem is established in…

Quantum Physics · Physics 2024-08-01 Wei Wu , Jun-Hong An

The rates at which energy and particle densities move to equalize arbitrarily large temperature and chemical potential differences in an isolated quantum system have an emergent thermodynamical description whenever energy or particle…

Strongly Correlated Electrons · Physics 2015-12-31 Romain Vasseur , Christoph Karrasch , Joel E. Moore

We present a Green's function method for the evaluation of the particle density profile and of the higher moments of the one-body density matrix in a mesoscopic system of N Fermi particles moving independently in a linear potential. The…

Statistical Mechanics · Physics 2009-10-31 Anna Minguzzi , Patrizia Vignolo , M. P. Tosi

Chemical theories involving thermodynamical equilibrium states invariably utilize statistical mechanical equilibrium density distributions. Here, a definition of heat-work transformation termed thermo mechanical coherence is first made, and…

Chemical Physics · Physics 2007-05-23 Christopher G. Jesudason

In the last ten years, a number of ``Conventional Fluctuation Theorems'' have been derived for systems with deterministic or stochastic dynamics, in a transient or in a non-equilibrium stationary state. These theorems gave explicit…

Statistical Mechanics · Physics 2007-05-23 R. van Zon , E. G. D. Cohen

The problem of the expansion and assimilation of a cryogenic fuel pellet injected into a hot plasma is considered. Due to the transparency of the plasmoid to ambient particles, it is found that electrons reach a `quasi-equilibrium' (QE)…

Plasma Physics · Physics 2023-10-10 A. M. Arnold , P. Aleynikov , B. N. Breizman

The existence and uniqueness of a steady state for nonequilibrium systems (NESS) is a fundamental subject and a main theme of research in statistical mechanics for decades. For Gaussian systems, such as a chain of harmonic oscillators…

Statistical Mechanics · Physics 2015-10-13 J. -T. Hsiang , B. L. Hu

We describe some general results that constrain the dynamical fluctuations that can occur in non-equilibrium steady states, with a focus on molecular dynamics. That is, we consider Hamiltonian systems, coupled to external heat baths, and…

Statistical Mechanics · Physics 2017-11-22 Robert L. Jack , Marcus Kaiser , Johannes Zimmer

We continue the investigation of kinetic models of a system in contact via stochastic interactions with several spatially homogeneous thermal reservoirs at different temperatures. Considering models different from those investigated in…

Mathematical Physics · Physics 2017-04-18 Eric A. Carlen , Raffaelle Esposito , Joel L. Lebowitz , Rossana Marra , Clement Mouhot

In this paper, we show that a nonequilibrium steady state (NESS) exists at late times in open quantum systems with weak nonlinearity by following its nonequilibrium dynamics with a perturbative analysis. Here we consider an oscillator chain…

Quantum Physics · Physics 2020-09-14 Jing Yang , Jen-Tsung Hsiang , Andrew N. Jordan , B. L. Hu

Molecular motors drive mechanical motions utilizing the free energy liberated from chemical reactions such as ATP hydrolysis. Although it is essential to know the efficiency of this free energy transduction, it has been a challenge due to…

Non-equilibrium thermodynamics provides a general framework for understanding non-equilibrium processes, particularly in small systems that are typically far from equilibrium and dominated by fluctuations. However, the experimental…

Optics · Physics 2023-09-08 Yu Zheng , Lyu-Hang Liu , Xiang-Dong Chen , Guang-Can Guo , Fang-Wen Sun

The equilibrium free energy landscape of off-lattice model heteropolymers as a function of an internal coordinate, namely the end-to-end distance, is reconstructed from out-of-equilibrium steered molecular dynamics data. This task is…

Statistical Mechanics · Physics 2008-09-17 Stefano Luccioli , Alberto Imparato , Alessandro Torcini

Most non-equilibrium processes in thermodynamics are quantified only by inequalities, however the Jarzynski relation presents a remarkably simple and general equality relating non-equilibrium quantities with the equilibrium free energy, and…

Quantum Physics · Physics 2018-04-04 T. P. Xiong , L. L. Yan , F. Zhou , K. Rehan , D. F. Liang , L. Chen , W. L. Yang , Z. H. Ma , M. Feng , V. Vedral

Activation/deactivation by inelastic collisions have been extensively studied at unimolecular reactions in gas phase where they are crucial for equilibration. As equilibration means an increase of entropy, the mechanism can also be…

Statistical Mechanics · Physics 2011-12-12 Jürgen Schlitter

Nonequilibrium work-Hamiltonian connection for a microstate plays a central role in diverse branches of statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.). We show that the change in…

Statistical Mechanics · Physics 2017-02-03 P. D. Gujrati

Exchange energy statistics between two bodies at different thermal equilibrium obey the Jarzynski-W\'ojcik fluctuation theorem. The corresponding energy scale factor is the difference of the inverse temperatures associated to the bodies at…

We study the stochastic dynamics of Brownian particles in a heat bath and subject to an active feedback control by an external, Maxwell's demon-like agent. The agent uses the information of the velocity of a particle and reduces its thermal…

Classical Physics · Physics 2007-05-23 Kyung Hyuk Kim , Hong Qian

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

Statistical Mechanics · Physics 2007-05-23 D. Reguera , J. M. Rubi , J. M. G. Vilar

We study the non-equilibrium thermodynamics of single Brownian macromolecules immersed in water solvent. They are under both a hydrodynamic interaction and a feedback control on their movement by an external agent. The macromolecules are…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kyung Hyuk Kim