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We investigate the dynamics of the extended simple point charge (SPC/E) model of water in the supercooled region. The dynamics at negative pressures show a minimum in the diffusion constant $D$ when the density is decreased at constant…

Statistical Mechanics · Physics 2007-05-23 P. A. Netz , F. Starr , H. Eugene Stanley , M. C. Barbosa

It is shown that the drastic distinction in the rotational structure of molecules in the He4 and He3 liquids observed in [1] is due to the difference in the spectral density of excitations regardless of the hydrodynamic properties. The…

Statistical Mechanics · Physics 2009-10-31 V. S. Babichenko , Yu. Kagan

Carbon tetrachloride (CCl$_4$) is one of the simplest compounds having a translationally stable monoclinic phase while exhibiting a rich rotational dynamics below 226 K. Recent nuclear quadrupolar resonance (NQR) experiments revealed that…

Chemical Physics · Physics 2016-03-01 Nirvana B. Caballero , Mariano Zuriaga , Marcelo Carignano , Pablo Serra

Water is vital for life, and without it biomolecules and cells cannot maintain their structures and functions. The remarkable properties of water originate from its ability to form hydrogen-bonding networks and dynamics, which the…

Soft Condensed Matter · Physics 2023-06-01 Nguyen Q. Vinh , Luan C. Doan , Ngoc L. H. Hoang , Jiarong R. Cui , Ben Sindle

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

Granular simulations are used to probe the particle scale dynamics at short, intermediate, and long time scales for gravity driven, dense granular flows down an inclined plane. On approach to the angle of repose, where motion ceases, the…

Soft Condensed Matter · Physics 2009-11-11 L. E. Silbert

We analyze differences in dynamics and in properties of the sampled potential energy landscape between different equilibrium trajectories, for a system of rigid water molecules interacting with a two body potential. On entering in the…

Soft Condensed Matter · Physics 2007-05-23 E. La Nave , F. Sciortino

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

Soft Condensed Matter · Physics 2010-10-01 Luca Cipelletti , Eric R. Weeks

Using molecular dynamics simulation, we study structural and dynamical heterogeneities at melting in two-dimensional one-component systems with 36000 particles. Between crystal and liquid we find intermediate hexatic states, where the…

Statistical Mechanics · Physics 2010-04-07 Hayato Shiba , Akira Onuki , Takeaki Araki

A roughly constant temperature over a wide range of densities is maintained in molecular clouds through radiative heating and cooling. An isothermal equation of state is therefore frequently employed in molecular cloud simulations. However,…

Astrophysics · Physics 2009-11-11 G. Pavlovski , M. D. Smith , M. -M. Mac Low

In temperature range from 0 C to 100 C, abnormality of ambient water properties, at normal pressure, are mainly defined by the physic of hydrogen bonds in supramolecular structures (SMS). Application of Arrhenius approximations and…

Chemical Physics · Physics 2021-01-19 Alexander Kholmanskiy

Performing molecular dynamics simulations for all-atom models, we characterize the conformational and structural relaxations of poly(ethylene oxide) and poly(propylene oxide) melts. The temperature dependence of these relaxation processes…

Soft Condensed Matter · Physics 2009-11-13 Michael Vogel

We {\it analytically} investigate the population and coherence dynamics and relaxations in the vibrational energy transport in molecules. The corresponding two time scales $t_1$ and $t_2$ are explored. Coherence-population entanglement is…

Quantum Physics · Physics 2016-01-06 Zhedong Zhang , Jin Wang

The steady-state homogeneous vapor-to-liquid nucleation and the succeeding liquid droplet growth process are studied for water system by means of the coarse-grained molecular dynamics simulations with the mW-model suggested originally in…

Soft Condensed Matter · Physics 2012-10-03 Anatolii V. Mokshin , Bulat N. Galimzyanov

In this work, we have carried out molecular dynamics (MD) simulation techniques to study the diffusion coefficient of interlayer molecules at different temperature. Within the wider context of water dynamics in soils, and with a particular…

Soft Condensed Matter · Physics 2023-03-23 H. O. Mohammed , K. N. Nigussa

We study the Stokes-Einstein (SE) and the Stokes-Einstein-Debye (SED) relations using molecular dynamics simulations of the extended simple point charge model of water. We find that both the SE and SED relations break down at low…

Statistical Mechanics · Physics 2007-06-01 Marco G. Mazza , Nicolas Giovambattista , H. Eugene Stanley , Francis W. Starr

We have employed molecular dynamics simulations based on the TIP4P/2005 water model to investigate the local structural, dynamical, and dielectric properties of the two recently reported body-centered-cubic and face-centered-cubic plastic…

Soft Condensed Matter · Physics 2019-04-03 Ioannis Skarmoutsos , Stefano Mossa , Elvira Guardia

In the paper the behavior of density (or specific volume), the heat of evaporation and entropy per molecule for normal and heavy water on their coexistence curves is discussed. The special attention is paid on the physical nature of the…

Statistical Mechanics · Physics 2009-10-26 V. L. Kulinskii , N. P. Malomuzh

We develop a transferable machine learning model which predicts structural relaxation from amorphous supercooled liquid structures. The trained networks are able to predict dynamic heterogeneity across a broad range of temperatures and time…

Soft Condensed Matter · Physics 2024-02-27 Gerhard Jung , Giulio Biroli , Ludovic Berthier

The properties of amorphous solid water at and near the calorimetric glass transition temperature, $T_{g}$, of 136 K have been debated for years. One hypothesis is that water turns into a "true" liquid at $T_{g}$ (i.e., it becomes ergodic)…

Soft Condensed Matter · Physics 2025-03-03 Greg A. Kimmel , Megan K. Dunlap , Kirill Gurdumov , R. Scott Smith , Loni Kringle , Bruce D. Kay
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