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We report the experimental investigations on a liquid crystal comprised of thiophene-based achiral bent-core banana shaped molecules. The results reveal the presence of a short range nematic phase at high temperatures and a long-range SmA…

Soft Condensed Matter · Physics 2023-07-03 Vishnu Deo Mishra , G. Pratap , Arun Roy

We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast beta process, commonly ascribed to caged…

Soft Condensed Matter · Physics 2013-08-07 M. Köhler , P. Lunkenheimer , Y. Goncharov , A. Loidl

Dilute dipolar systems in three dimensions are expected to undergo a spin glass transition as the temperature decreases. Contrary to this, we find from Wang-Landau Monte Carlo simulations that at low concentrations $x$, dipoles randomly…

Soft Condensed Matter · Physics 2009-11-11 Joseph Snider , Clare C. Yu

We report a computer simulation study of the glass transition for water. To mimic the difference between standard and hyperquenched glass, we generate glassy configurations with different cooling rates and calculate the $T$ dependence of…

Soft Condensed Matter · Physics 2016-08-31 Nicolas Giovambattista , C. Austen Angell , Francesco Sciortino , H. Eugene Stanley

We show that the relaxation dynamics near a glass transition with continuous ergodicity breaking can be endowed with a geometric interpretation based on percolation theory. At mean-field level this approach is consistent with the…

Statistical Mechanics · Physics 2014-09-05 Jeferson J. Arenzon , Antonio Coniglio , Annalisa Fierro , Mauro Sellitto

We numerically elucidate the microscopic mechanisms controlling the relaxation dynamics of a three-dimensional lattice glass model that has static properties compatible with the approach to a random first-order transition. At low…

Disordered Systems and Neural Networks · Physics 2024-02-09 Yoshihiko Nishikawa , Ludovic Berthier

Spin relaxation close to the glass temperature of CuMn and AuFe spin glasses is shown, by neutron spin echo, to follow a generalised exponential function which explicitly introduces hierarchically constrained dynamics and macroscopic…

Disordered Systems and Neural Networks · Physics 2009-02-25 R M Pickup , R Cywinski , C Pappas , B Farago , P Fouquet

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…

The relaxation of polymers around and below their glass transition temperature is governed by a range of correlated unit processes with a wide range of timescales. The fast deformation rates of shock loading can negate a significant…

Materials Science · Physics 2022-07-27 Jalen Macatangay , Brenden W. Hamilton , Alejandro Strachan

A mesoscopic model is proposed to explain the anomalous dynamics in a supercooled liquid as its glass transition temperature is approached from above. The model is based on the assumption of $\beta$ organized $\alpha$ process, with the…

Soft Condensed Matter · Physics 2007-05-23 Dwaipayan Chakrabarti , Biman Bagchi

Mode coupling theory (MCT) has been successful in explaining the observed sequence of time relaxations in dense fluids. Previous expositions of this theory showing this sequence have required the existence of an ideal glass transition…

Condensed Matter · Physics 2009-10-22 Gene F. Mazenko , Joonhyun Yeo

Anomalous temperature dependence of heat capacity of glassy systems during a cooling-heating cycle has remained an ill-understood problem for a long time. Most of the features observed in the experimental measurement of the heat capacity of…

Soft Condensed Matter · Physics 2007-05-23 Dwaipayan Chakrabarti , Biman Bagchi

We performed parallel measurements of the high-frequency shear modulus $G$ and relative volume $\Delta V/V$ for high-entropy Ti$_{20}$Zr$_{20}$Hf$_{20}$Be$_{20}$Cu$_{20}$ and Ti$_{20}$Zr$_{20}$Hf$_{20}$Be$_{20}$Ni$_{20}$ glasses upon…

Disordered Systems and Neural Networks · Physics 2024-08-07 R. S. Khmyrov , A. S. Makarov , J. C. Qiao , N. P. Kobelev , V. A. Khonik

In an earlier preprint (V. V. Ginzburg, O. V. Gendelman, R. Casalini, and A. Zaccone, arxiv:2409.17291), we demonstrated that the dynamic (relaxation time) and volume equations of state for many amorphous polymers are near-universal -- each…

Soft Condensed Matter · Physics 2025-01-03 Valeriy V. Ginzburg , Oleg V. Gendelman , Riccardo Casalini , Alessio Zaccone

The glass transition is a long-standing unsolved problem in materials science. For polymers, our understanding of glass-formation is particularly poor due to the added complexity of chain connectivity and flexibility; structural relaxation…

Soft Condensed Matter · Physics 2022-05-30 Daniel L. Baker , Matthew Reynolds , Robin Masurel , Peter D. Olmsted , Johan Mattsson

In recent decades, the laws of thermodynamics have been pushed down to smaller and smaller scales, within the field of stochastic thermodynamics and state-of-art experiments performed on mesoscopic systems. These measurements concern…

Mesoscale and Nanoscale Physics · Physics 2023-01-26 Ilya Golokolenov , Arpit Ranadive , Luca Planat , Martina Esposito , Nicolas Roch , Xin Zhou , Andrew Fefferman , Eddy Collin

We show numeric evidence that, at low enough temperatures, the potential energy density of a glass-forming liquid fluctuates over length scales much larger than the interaction range. We focus on the behavior of translationally invariant…

Soft Condensed Matter · Physics 2009-04-21 L. A. Fernandez , V. Martin-Mayor , P. Verrocchio

Amorphous materials have a rich relaxation spectrum, which is usually described in terms of a hierarchy of relaxation mechanisms. In this work, we investigate the local dynamic modulus spectra in a model glass just above the glass…

Disordered Systems and Neural Networks · Physics 2019-03-27 Baoshuang Shang , Jörg Rottler , Pengfei Guan , Jean-Louis Barrat

We report on the crossover from the thermal to athermal regime of an artificial spin ice formed from a square array of magnetic islands whose lateral size, 30~nm~$\times$~70~nm, is small enough that they are superparamagnetic at room…

Disordered Systems and Neural Networks · Physics 2017-03-28 S. A. Morley , D. Alba Venero , J. M. Porro , S. T. Riley , A. Stein , P. Steadman , R. L. Stamps , S. Langridge , C. H. Marrows

The local molecular motion of $cis$-polybutadiene, a typical polymeric material exhibiting a glass transition ($T_{\rm g}=168$ K), is investigated by the spin relaxation of muonated radicals, where the relaxation is induced by the…

Materials Science · Physics 2025-06-19 S. Takeshita , H. Okabe , M. Hiraishi , K. M. Kojima , A. Koda , H. Seto , T. Masui , N. Wakabayashi , F. L. Pratt , R. Kadono