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The electronic properties of bulk fcc americium and the (111) surface have been investigated with the full-potential linearized augmented plane wave (FP-LAPW) method as implemented in the WIEN2K suite of programs. The study is carried out…

Superconductivity · Physics 2007-05-23 Da Gao , Asok K. Ray

We systematically investigate the electronic structures of americium (Am), curium (Cm), berkelium (Bk), and californium (Cf) in both the ambient-pressure double hexagonal close-packed (dhcp) and high-pressure face-centered cubic (fcc)…

Strongly Correlated Electrons · Physics 2026-04-15 Haiyan Lu

We investigate the electronic structure of americium (Am) across its four experimentally confirmed high-pressure phases Am-I (P63/mmc), Am-II (Fm-3m), Am-III (Fddd), and Am-IV (Pnma) up to 100 GPa, using density functional theory combined…

Strongly Correlated Electrons · Physics 2026-04-15 Haiyan Lu

We provide a straightforward and numerically efficient procedure to perform local density approximation + Hubbard I (LDA+HIA) calculations, including self-consistency over the charge density, within the full potential linearized augmented…

Materials Science · Physics 2009-09-03 Alexander B. Shick , Jindrich Kolorenč , Alexander I. Lichtenstein , Ladislav Havela

The {\em around-mean-field} LSDA+U correlated band theory is applied to investigate the electronic and magnetic structure of $fcc$-Pu-Am alloys. Despite a lattice expansion caused by the Am atoms, neither tendency to 5$f$ localization nor…

The electronic correlation may have essential influence on electronic structures in some materials with special structure and localized orbital distribution. In this work, taking Janus monolayer FeClF as a concrete example, the correlation…

Materials Science · Physics 2022-04-06 San-Dong Guo , Jing-Xin Zhu , Meng-Yuan Yin , Bang-Gui Liu

The electronic and geometric properties of bulk fcc delta-plutonium and the quantum size effects in the surface energies and the work functions of the (001) ultra thin films (UTF) up to 7 layers have been investigated with periodic density…

Strongly Correlated Electrons · Physics 2009-11-10 Xueyuan Wu , Asok K. Ray

An understanding of the phase diagram of elemental plutonium (Pu) must include both the effects of the strong directional bonding and the high density of states of the Pu 5f electrons, as well as how that bonding weakens under the influence…

Strongly Correlated Electrons · Physics 2015-06-18 Jian-Xin Zhu , R. C. Albers , K. Haule , G. Kotliar , J. M. Wills

Plutonium (Pu), in which the 5$f$ valence electrons always wander the boundary between localized and itinerant states, exhibits quite complex crystal structures and unprecedentedly anomalous properties with respect to temperature and…

Strongly Correlated Electrons · Physics 2020-03-26 Li Huang , Haiyan Lu

Including on-site electronic interactions described by the multi-orbital Hubbard model we study the correlation effects in the electronic structure of bulk palladium. We use a combined density functional and dynamical mean field theory,…

Strongly Correlated Electrons · Physics 2016-05-04 A. Östlin , W. H. Appelt , I. Di Marco , W. Sun , M. Radonjic , M. Sekania , L. Vitos , O. Tjernberg , L. Chioncel

We develop a new implementation of the Gutzwiller approximation (GA) and interface it with the local density approximation (LDA). This formulation enables us to study complex $4f$ and $5f$ systems. We perform calculations of praseodymium…

Strongly Correlated Electrons · Physics 2015-05-11 Nicola Lanatà , Yongxin Yao , Cai-Zhuang Wang , Kai-Ming Ho , Gabriel Kotliar

Electronic structure of bcc Np, fcc Pu, Am, and Cm pure metals under pressure has been investigated employing the LDA+U method with spin-orbit coupling (LDA+U+SO). Magnetic state of the actinide ions was analyzed in both LS and jj coupling…

We have investigated the crystal, electronic, and magnetic structure of Mn5O8 by means of state of-the-art density functional theory calculations and neutron powder diffraction (NPD) measurements. This compound stabilizes in the monoclinic…

Materials Science · Physics 2016-09-12 M. R. Ashwin Kishore , H. Okamoto , Lokanath Patra , R. Vidya , Anja O. Sjastad , H. Fjellvag , P. Ravindran

The electronic structure and magnetic properties of a single Fe adatom on a CuN surface have been studied using density functional theory in the local spin density approximation (LSDA), the LSDA+U approach and the local density…

Strongly Correlated Electrons · Physics 2016-04-20 S. K. Panda , I. Di Marco , O. Grånäs , O. Eriksson , J. Fransson

The electronic structures of the actinide elements U, Np, Pu, Am, Cm and Bk are investigated within the self-interaction corrected local spin density approximation. This method allows to describe a dual character of the 5f electrons, some…

Strongly Correlated Electrons · Physics 2009-11-11 A. Svane , L. Petit , Z. Szotek , W. M. Temmerman

By combining the local density approximation (LDA) with dynamical mean field theory (DMFT), we report a systematic analysis of the spectral properties of $\delta$-plutonium with varying $5f$ occupancy. The LDA Hamiltonian is extracted from…

Strongly Correlated Electrons · Physics 2009-11-13 Jian-Xin Zhu , A. K. McMahan , M. D. Jones , T. Durakiewicz , J. J. Joyce , J. M. Wills , R. C. Albers

Anderson models, based on quantum chemical studies of the molecule of U(C_8H_8)_2, are applied to investigate the problem of an U impurity in a metal. The special point here is that the U 5f-orbitals are divided into two subsets: an almost…

Strongly Correlated Electrons · Physics 2009-10-30 Mikito Koga , Wenjian Liu , Michael Dolg , Peter Fulde

We carry out a systematic theoretical investigation of Magneto Crystalline Anisotropy (MCA) of L10 FePt clusters with alternating Fe and Pt planes along the (001) direction. We calculate the structural relaxation and magnetic moment of each…

Mesoscale and Nanoscale Physics · Physics 2015-08-19 Alamgir Kabir , Jun Hu , Volodymyr Turkowski , Ruqian Wu , Talat S. Rahman

By LDA+U method with spin-orbit coupling (LDA+U+SO) the magnetic state and electronic structure have been investigated for plutonium in \delta and \alpha phases and for Pu compounds: PuN, PuCoGa5, PuRh2, PuSi2, PuTe, and PuSb. For metallic…

Strongly Correlated Electrons · Physics 2007-05-23 A. O. Shorikov , A. V. Lukoyanov , M. A. Korotin , V. I. Anisimov

Magnetic anisotropy of uranium monochalcogenides, US, USe and UTe, is studied by means of fully-relativistic spin-polarized band structure calculations within the local spin-density approximation. It is found that the size of the magnetic…

Materials Science · Physics 2009-10-31 Tatsuya Shishidou , Tamio Oguchi
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