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We investigate the origin of asymmetry in various measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry, with particular focus on a recent break junction measurement. We argue that such asymmetry…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 F. Zahid , A. W. Ghosh , M. Paulsson , E. Polizzi , S. Datta

This tutorial article presents a "bottom-up" view of electrical resistance starting from something really small, like a molecule, and then discussing the issues that arises as we move to bigger conductors. Remarkably, no serious quantum…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Supriyo Datta

We develop nonequilibribrium Green's function based transport theory, which includes effects of nonadiabatic nuclear motion in the calculation of the electric current in molecular junctions. Our approach is based on the separation of slow…

Mesoscale and Nanoscale Physics · Physics 2017-12-20 Vincent F. Kershaw , Daniel S. Kosov

Using the tight-binding model and the generalized Green's function formalism, the effect of quantum interference on the electron transport through the benzene molecule in a semiconductor/benzene/semiconductor junction is numerically…

Mesoscale and Nanoscale Physics · Physics 2016-08-09 Javad Vahedi , Zahra Sartipi

Redox molecular junctions are molecular conduction junctions that involve more than one oxidation state of the molecular bridge. This property is derived from the ability of the molecule to transiently localize transmitting electrons,…

Mesoscale and Nanoscale Physics · Physics 2013-06-21 Agostino Migliore , Abraham Nitzan

The conductance through a molecular device including electron-electron and electron-phonon interactions is calculated using the Numerical Renormalization Group method. At low temperatures and weak electron-phonon coupling the properties of…

Strongly Correlated Electrons · Physics 2007-05-23 P. S. Cornaglia , H. Ness , D. R. Grempel

An electron transport is studied in the system which consists of scanning tunneling microscopy-single molecule magnet-metal. Due to quantum tunneling of magnetization in single-molecule magnet, linear response conductance exhibits stepwise…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Gwang-Hee Kim , Tae-Suk Kim

The concept of transmission eigenchannels is described in a tight-binding nonequilibrium Green's function (NEGF) framework. A simple procedure for calculating the eigenchannels is derived using only the properties of the device subspace and…

Mesoscale and Nanoscale Physics · Physics 2011-11-09 Magnus Paulsson , Mads Brandbyge

We have investigated charge transport in ultrasmall superconducting single and double Josephson junctions coupled to resonant modes of the electromagnetic environment. We observe pronounced current peaks in the transport characteristics of…

Superconductivity · Physics 2011-02-03 Yu. A. Pashkin , H. Im , J. Leppäkangas , T. F. Li , O. Astafiev , A. A. Abdumalikov , E. Thuneberg , J. S. Tsai

Single-molecule electronics has been envisioned as the ultimate goal in the miniaturisation of electronic circuits. While the aim of incorporating single-molecule junctions into modern technology still proves elusive, recent developments in…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Jakub K. Sowa , Jan A. Mol , G. Andrew D. Briggs , Erik M. Gauger

Off-resonant charge transport through molecular junctions has been extensively studied since the advent of single-molecule electronics and it is now well understood within the framework of the non-interacting Landauer approach. Conversely,…

The electronic transport properties and switching mechanism of single photochromic diarylethene derivatives sandwiched between two gold surfaces with closed and open configurations are investigated by a fully self-consistent nonequilibrium…

Other Condensed Matter · Physics 2009-11-13 Jing Huang , Qunxiang Li , Hao Ren , Haibin Su , Q. W. Shi , Jinlong Yang

In our theoretical study in which we combine a nonequilibrium Green's function (NEGF) approach with density functional theory (DFT) we investigate branched compounds containing Ru or Os metal complexes in two branches, which due to their…

Chemical Physics · Physics 2019-03-27 Xin Zhao , Robert Stadler

Novel organic materials formed from functional molecules are attractive for various nanoelectronic applications because they are environmentally friendly, widely available and inexpensive. Recent advancement in bottom-up fabrication methods…

Mesoscale and Nanoscale Physics · Physics 2022-12-14 Abdalghani Daaoub , Renhang Wang , Ross Davidson , Sara Sangtarash , Hatef Sadeghi

We present ab-initio transport calculations for molecular junctions that include graphene as a protecting layer between a single molecule and gold electrodes. This vertical setup has recently gained significant interest in experiment for…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

The electron transport between two zigzag graphene nanoribbons (ZGNRs) connected by carbon atomic chains has been investigated by the nonequilibrium Green's function method combined with the density functional theory. The symmetry of the…

Mesoscale and Nanoscale Physics · Physics 2013-09-13 Yao-Jun Dong , Xue-Feng Wang , Ming-Xing Zhai , Jian-Chun Wu , Liping Zhou , Qin Han , Xue-Mei Wu

We analyze the effect of a gate on the conductance of molecules by separately evaluating the gate-induced polarization and the potential shift of the molecule relative to the leads. The calculations use ab initio density functional theory…

Materials Science · Physics 2007-05-23 San-Huang Ke , Harold U. Baranger , Weitao Yang

Understanding the properties of electronic transport across metal-molecule interfaces is of central importance for controlling a large variety of molecular-based devices such as organic light emitting diodes, nanoscale organic spin-valves…

Mesoscale and Nanoscale Physics · Physics 2016-02-03 T. Yelin , R. Korytar , N. Sukenik , R. Vardimon , B. Kumar , C. Nuckolls , F. Evers , O. Tal

Electron transport properties of a non-interacting mesoscopic ring sandwiched between two metallic electrodes are investigated by the use of Green's function formalism. We introduce a parametric approach based on the tight-binding model to…

Mesoscale and Nanoscale Physics · Physics 2009-11-06 Santanu K. Maiti
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