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We use molecular simulations to demonstrate the connection between transverse water-water correlations and wetting phenomena for a range of hydrophobic to hydrophilic solid surfaces.Near superhydrophobic surfaces, the correlations are long…

Soft Condensed Matter · Physics 2014-09-10 Rahul Godawat , Sumanth N. Jamadagni , Vasudevan Venkateshwaran , Shekhar Garde

When two solid surfaces are brought in contact, water vapor present in the ambient air may condense in the region of the contact to form a liquid bridge connecting the two surfaces : this is the so-called capillary condensation. This…

Soft Condensed Matter · Physics 2007-05-23 F. Restagno , L. Bocquet , J. Crassous , E. Charlaix

Water near hydrophobic surfaces is like that at a liquid-vapor interface, where fluctuations in water density are substantially enhanced compared to that in bulk water. Here we use molecular simulations with specialized sampling techniques…

An analysis of water clustering is used to study the quasi-2D percolation transition of water adsorbed at planar hydrophilic surfaces. Above the critical temperature of the layering transition (quasi-2D liquid-vapor phase transition of…

Statistical Mechanics · Physics 2009-11-11 A. Oleinikova , I. Brovchenko , A. Geiger

The Leidenfrost effect is a phenomenon in which a liquid, poured onto a surface significantly hotter than the liquid's boiling point, produces a layer of vapor that prevents the liquid from rapid evaporation. Rather than making physical…

Statistical Mechanics · Physics 2022-11-24 Sergey Gavrilyuk , Henri Gouin

We provide a complete description of the low temperature wetting transition for the two dimensional Solid-On-Solid model. More precisely we study the integer-valued field $(\phi(x))_{x\in \mathbb Z^2}$, associated associated to the energy…

Mathematical Physics · Physics 2018-07-04 Hubert Lacoin

Numerical analysis of a shear layer between a cool liquid n-decane hydrocarbon and a hot oxygen gas at supercritical pressures shows that a well-defined phase equilibrium can be established. Variable properties are considered with the…

Fluid Dynamics · Physics 2020-06-04 Branson Davis , Jordi Poblador-Ibanez , William A. Sirignano

We consider the spreading of a thin two-dimensional droplet on a solid substrate. We use a model for viscous fluids where the evolution is governed by Darcy's Law. At the triple point where air and liquid meet the solid substrate, the…

Analysis of PDEs · Mathematics 2012-04-12 Hans Knüpfer , Nader Masmoudi

A continuous surface wetting transition, pinned to a solid/liquid/liquid/vapor tetra coexistence point, is studied by x-ray reflectivity in liquid Ga-Bi binary alloys. The short-range surface potential is determined from the measured…

Statistical Mechanics · Physics 2009-11-07 Patrick Huber , Oleg G. Shpyrko , Peter S. Pershan , Benjamin M. Ocko , Elaine DiMasi , Moshe Deutsch

The dry frictional contact between two solid surfaces is well-known to obey Coulomb friction laws. In particular, the static friction force resisting the relative lateral (tangential) motion of solid surfaces, initially at rest, is known to…

Statistical Mechanics · Physics 2010-11-16 Jean-Christophe Géminard , Eric Bertin

As a first step towards a microscopic understanding of the effective interaction between colloidal particles suspended in a solvent we study the wetting behavior of one-component fluids at spheres and fibers. We describe these phenomena…

Condensed Matter · Physics 2015-06-25 T. Bieker , S. Dietrich

Collective motion over increasing length scales is a signature of the vitrification process of liquids. We demonstrate the emergence of distinct static and dynamic length scales probed near the free surface in fully equilibrated…

Statistical Mechanics · Physics 2022-11-28 Hailong Peng , Huashan Liu , Thomas Voigtmann

We report extensive simulation studies of phase behaviour in single component systems of particles interacting via a core-softened interparticle potential. Two recently proposed examples of such potentials are considered; one in which the…

Statistical Mechanics · Physics 2009-11-07 Nigel B. Wilding , James E. Magee

We find a thermodynamic description of gas-liquid criticality that is different from van der Waals and mean-field theories. At the critical temperature there is no critical point; a liquid phase coexists with a vapor phase with densities…

Statistical Mechanics · Physics 2012-07-13 Leslie V. Woodcock

The phase behavior of hard rectangular rods with length L and diameter D is studied in a narrow slit-like pore using the Parsons-Lee density functional theory. Using the restricted orientation approximation, we find strong adsorption at the…

Soft Condensed Matter · Physics 2018-09-12 Hamdollah Salehi , Sakine Mizani , Roohollah Aliabadi , Szabolcs Varga

The density functional approach for classical associating fluids is used to explore the wetting phase diagrams for model systems consisting of water and graphite-like solid surfaces chemically modified by a small amount of grafted chain…

Soft Condensed Matter · Physics 2025-06-26 O. Pizio

A dryout point is recognized as the position where the phase transition from liquid to vapor occurs. In the one-dimensional case, by solving the stationary incompressible Navier-Stokes-Fourier equations with phase transition, we derive a…

Analysis of PDEs · Mathematics 2024-03-26 Yoshikazu Giga , Zhongyang Gu

As was shown in an earlier paper [1], solids dispersed in a drying drop migrate to the (pinned) contact line. This migration is caused by outward flows driven by the loss of the solvent due to evaporation and by geometrical constraint that…

Soft Condensed Matter · Physics 2007-05-23 Yuri O. Popov , Thomas A. Witten

We apply a phenomenological theory of polar liquids to calculate the interaction energy between two plane surfaces at nm-distances. We show that depending on the properties of the surface-liquid interfaces, the interacting surfaces induce…

Soft Condensed Matter · Physics 2013-04-24 P. O. Fedichev , L. I. Menshikov

Some fluids exhibit anomalously low friction when flowing against a certain solid wall. To recover the viscosity of a bulk fluid, slip at the wall is usually postulated. On a macroscopic level, a large slip length can be explained as a…

Soft Condensed Matter · Physics 2009-11-10 D. Andrienko , Burkhard Dünweg , Olga I. Vinogradova