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Ubiquitous Van der Waals interactions between atoms and molecules are important for many molecular and solid structures. These systems are often studied from first principles using the Density Functional Theory (DFT). However, the commonly…

Materials Science · Physics 2009-11-13 Pier Luigi Silvestrelli

We propose an algorithm to determine Maximally Localized Wannier Functions (MLWFs). This algorithm, based on recent theoretical developments, does not require any physical input such as initial guesses for the Wannier functions, unlike…

Materials Science · Physics 2017-03-13 Éric Cancès , Antoine Levitt , Gianluca Panati , Gabriel Stoltz

We show that an optimized projection functions method can automatically construct maximally localized Wannier functions even for bands with nontrivial topology. We demonstrate this method on a tight-binding model of a two-dimensional…

Materials Science · Physics 2016-10-05 Jamal I. Mustafa , Sinisa Coh , Marvin L. Cohen , Steven G. Louie

We show that real polarization method can be effectively used to geometrically quantize physical systems with compact phase space, like the spin. Our method enables us to construct a wave function of a qubit in both position and momentum…

Mathematical Physics · Physics 2015-12-10 Jerzy Kijowski , Piotr Waluk , Katarzyna Senger

We present a theoretical method for calculating optical absorption spectra based on maximally localized Wannier functions, which is suitable for large periodic systems. For this purpose, we calculate the exciton Hamiltonian, which…

Mesoscale and Nanoscale Physics · Physics 2023-09-14 Konrad Merkel , Frank Ortmann

We have developed a linear scaling algorithm for calculating maximally-localized Wannier functions (MLWFs) using atomic orbital basis. An O(N) ground state calculation is carried out to get the density matrix (DM). Through a projection of…

Materials Science · Physics 2007-05-23 H. J. Xiang , Zhenyu Li , W. Z. Liang , Jinlong Yang , J. G. Hou , Qingshi Zhu

We present an automatic, high-order accurate, and adaptive Brillouin zone integration algorithm for the calculation of the optical conductivity with a non-zero but small broadening factor $\eta$, focusing on the case in which a Hamiltonian…

Materials Science · Physics 2024-06-25 Lorenzo Van Muñoz , Jason Kaye , Alex Barnett , Sophie Beck

A modified Green operator is proposed as an improvement of Fourier-based numerical schemes commonly used for computing the electrical or thermal response of heterogeneous media. Contrary to other methods, the number of iterations necessary…

Materials Science · Physics 2014-08-22 François Willot , Bassam Abdallah , Yves-Patrick Pellegrini

Wannier functions that are maximally localized help in understanding many properties of crystalline materials. In the absence of topological obstructions, they are at least exponentially localized. In some cases such as flat-band…

Mesoscale and Nanoscale Physics · Physics 2021-07-30 Pratik Sathe , Fenner Harper , Rahul Roy

We formulate Wannier orbital overlap population and Wannier orbital Hamilton population to describe the contribution of different orbitals to electron distribution and their interactions. These methods, which are analogous to the well known…

Computational Physics · Physics 2021-03-31 Sudipta Kundu , Satadeep Bhattacharjee , Seung-Cheol Lee , Manish Jain

We present a numerical implementation, based on Wannier interpolation, of a Kubo-Greenwood formalism for computing the spatially dispersive optical conductivity in crystals at first order in the wave vector of light. This approach is more…

Materials Science · Physics 2025-04-21 Andrea Urru , Ivo Souza , Óscar Pozo Ocaña , Stepan S. Tsirkin , David Vanderbilt

Position scaling-eigenfunctions are generated by transforming compactly supported orthonormal scaling functions and utilized for faster alternatives to maximally localized Wannier functions (MLWFs). The position scaling-eigenfunctions are…

Mesoscale and Nanoscale Physics · Physics 2023-12-18 Yuji Hamai , Katsunori Wakabayashi

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

We present a new variational model for computing the electronic first-order density matrix of a crystalline material in presence of a local defect. A natural way to obtain variational discretizations of this model is to expand the…

Other Condensed Matter · Physics 2009-11-13 Eric Cances , Amelie Deleurence , Mathieu Lewin

In this work, we use Wannier functions to analyze topological phase transitions in one dimensional photonic crystals. We first review the construction of exponentially localized Wannier functions in one dimension, and show how to…

Optics · Physics 2022-06-07 Vaibhav Gupta , Barry Bradlyn

We present a method for evaluating the partition function in a varying external field. Specifically, we look at the case of a non-interacting, charged, massive scalar field at finite temperature with an associated chemical potential in the…

High Energy Physics - Theory · Physics 2009-11-10 J. J. Mckenzie-Smith , Wade Naylor

Functionals that strive to correct for such self-interaction errors, such as those obtained by imposing the Perdew-Zunger self-interaction correction or the generalized Koopmans' condition, become orbital dependent or orbital-density…

Materials Science · Physics 2011-08-30 Cheol-Hwan Park , Andrea Ferretti , Ismaila Dabo , Nicolas Poilvert , Nicola Marzari

We demonstrate an enhancement of the plane wave expansion method treating two-dimensional photonic crystals by applying Fourier factorization with generally elliptic polarization bases. By studying three examples of periodically arranged…

Optics · Physics 2010-12-16 Roman Antos , Martin Veis

Wannier functions have widespread utility in condensed matter physics and beyond. Topological physics, on the other hand, has largely involved the related notion of compactly-supported Wannier-type functions, which arise naturally in flat…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Pratik Sathe , Rahul Roy

By use of conformal field theory, we discover several exact factorizations of higher-order density correlation functions in critical two-dimensional percolation. Our formulas are valid in the upper half-plane, or any conformally equivalent…

Mathematical Physics · Physics 2008-11-26 Jacob J. H. Simmons , Peter Kleban , Robert M. Ziff