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Local density approximation for the exchange energy is made for treatment of excited-states in density-functional theory. It is shown that taking care of the state-dependence of the LDA exchange energy functional leads to accurate…

Other Condensed Matter · Physics 2007-05-23 Manoj K. Harbola , Prasanjit Samal

The accuracy of the Faddeev random phase approximation (FRPA) method is tested by calculating the total and ionization energies of a set of light atoms up to Ar. Comparisons are made with the results of coupled-cluster singles and doubles…

Chemical Physics · Physics 2015-05-18 C. Barbieri , D. Van Neck , M. Degroote

Resonant energy transfer between cold Rydberg atoms was used to determine Rydberg atom energy levels, at precisions approaching those obtainable in microwave spectroscopy. Laser cooled Rb atoms from a magneto-optical trap were optically…

Atomic Physics · Physics 2007-05-23 K. Afrousheh , P. Bohlouli-Zanjani , J. A. Petrus , J. D. D. Martin

Electric-field-controlled F\"orster resonance energy transfer (FRET) between Rydberg helium (He) atoms and ground-state ammonia (NH$_3$) molecules has been studied at translational temperatures below 100 mK. The experiments were performed…

Atomic Physics · Physics 2022-11-21 J. Zou , S. D. Hogan

The resonant transfer of energy from the inversion sublevels in NH$_3$ to He atoms in triplet Rydberg states with principal quantum number $n=38$ has been controlled using electric fields below 15 V/cm in intrabeam collisions at…

Chemical Physics · Physics 2020-01-24 K. Gawlas , S. D. Hogan

For the kinetic energy of 1d model finite systems the leading corrections to local approximations as a functional of the potential are derived using semiclassical methods. The corrections are simple, non-local functionals of the potential.…

Other Condensed Matter · Physics 2010-06-25 Attila Cangi , Donghyung Lee , Peter Elliott , Kieron Burke

Recently, Rydberg atom has emerged as an attractive choice to realize quantum sensing of low-frequency electric field. The progress so far has mostly utilized the intensity and phase changes in probe laser and the corresponding detection…

Atomic Physics · Physics 2026-03-11 Ding Wang , Shenchao Jin , Xiayang Fan , Hongjing Li , Jiatian Liu , Jingzheng Huang , Guihua Zeng , Yuan Sun

We show that optical spectroscopy of Rydberg states can provide accurate {\em in situ} thermometry at room-temperature. Transitions from a metastable state to Rydberg states with principal quantum numbers of 25 to 30 have 200 times larger…

Quantum Physics · Physics 2011-08-24 Vitali D. Ovsiannikov , Andrei Derevianko , Kurt Gibble

We study linear-response time-dependent density-functional theory (DFT) based on the single-determinant range-separated hybrid (RSH) scheme, i.e. combining a long-range Hartree-Fock exchange kernel with a short-range DFT…

Chemical Physics · Physics 2015-06-15 Elisa Rebolini , Andreas Savin , Julien Toulouse

Comparison of precision frequency measurements to quantum electrodynamics (QED) predictions for Rydberg states of hydrogen-like ions can yield information on values of fundamental constants and test theory. With the results of a calculation…

Atomic Physics · Physics 2009-02-02 U. D. Jentschura , P. J. Mohr , J. N. Tan , B. J. Wundt

We present a local density approximation (LDA) for one-dimensional (1D) systems interacting via the soft-Coulomb interaction based on quantum Monte-Carlo calculations. Results for the ground-state energies and ionization potentials of…

Strongly Correlated Electrons · Physics 2015-05-27 N. Helbig , J. I. Fuks , M. Casula , M. J. Verstraete , M. A. L. Marques , I. V. Tokatly , A. Rubio

We develop an approach to realize a quantum switch for Rydberg excitation in atoms with $Y$-typed level configuration. We find that the steady population on two different Rydberg states can be reversibly exchanged in a controllable way by…

Atomic Physics · Physics 2017-09-14 Jing Qian

We combine a limited number of accurately measured transition frequencies in hydrogen and deuterium, recent quantum electrodynamics (QED) calculations, and, as an essential additional ingredient, a generalized least-squares analysis, to…

Atomic Physics · Physics 2007-05-23 U. D. Jentschura , S. Kotochigova , E. -O. Le Bigot , P. J. Mohr , B. N. Taylor

We calculate the $\Lambda \Lambda \to YN$ transition rate of ${^{\phantom{\Lambda}6}_{\Lambda \Lambda}}$He by the hybrid picture, the $\pi$ and $K$ exchanges plus the direct quark processes. It is found that the hyperon-induced decay is…

Nuclear Theory · Physics 2010-04-05 K. Sasaki , T. Inoue , M. Oka

We report our measurements of the absolute transition frequencies of 5P_3/2,F = 3 to nS and nD Rydberg states of 87Rb with high principal quantum numbers in a wide range of values (n = 45-124). The measurements were performed using Rydberg…

Atomic Physics · Physics 2022-05-19 Silpa B S , Shovan Kanti Barik , Saptarishi Chaudhuri , Sanjukta Roy

We present a new density-functional method of the self-consistent electronic-structure calculation which does not exploit any local density approximations (LDA). We use the exchange-correlation energy which consists of the exact exchange…

Statistical Mechanics · Physics 2009-10-30 Takao Kotani

The estimation of power spectra from LDA data provides signal processing challenges for fluid dynamicists for several reasons: acquisition is dictated by randomly arriving particles, the registered particle velocities tend to be biased…

Fluid Dynamics · Physics 2019-06-14 Clara M. Velte , William K. George , Preben Buchhave

We study nonequilibrium properties of small and chaotic quantum systems, i.e., non-integrable systems whose size is small in the sense that the separations of energy levels are non-negligible as compared with other relevant energy scales.…

chao-dyn · Physics 2007-05-23 Yasuhiro Higashiyama , Akira Shimizu

We report the creation of heteronuclear ultralong-range Rydberg-molecule dimers by excitation of minority $^{88}\text{Sr}$ atoms to $5sns\,^3S_1$ Rydberg states ($n=31-39$) in a dense background of $^{84}\text{Sr}$. We observe an isotope…

Atomic Physics · Physics 2020-07-01 J. D. Whalen , S. K. Kanungo , Y. Lu , S. Yoshida , J. Burgörfer , F. B. Dunning , T. C. Killian

We assess the performance of a recently proposed renormalized adiabatic local density approximation (rALDA) for \textit{ab initio} calculations of electronic correlation energies in solids and molecules. The method is an extension of the…

Materials Science · Physics 2014-05-30 Thomas Olsen , Kristian S. Thygesen