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We show that fundamental thermodynamic relations can be derived from deterministic mechanics for a non-ergodic system. This extend a similar derivation for ergodic systems and suggests that ergodicity should not be considered as a…

Statistical Mechanics · Physics 2018-11-13 V. L. Kulinskii , K. S. Glavatskiy

Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges…

Quantum Physics · Physics 2025-06-17 Giulia Rubino , Karen V. Hovhannisyan , Paul Skrzypczyk

We provide a rigorous generalization of the quantum adiabatic theorem for open systems described by a Markovian master equation with time-dependent Liouvillian $\mathcal{L}(t)$. We focus on the finite system case relevant for adiabatic…

Quantum Physics · Physics 2016-03-21 Lorenzo Campos Venuti , Tameem Albash , Daniel A. Lidar , Paolo Zanardi

In this paper, a theory for systems in contact with a thermal reservoir is developed. We call such systems "thermostated systems." Interest in these systems has been vigorous for about the last 20 years and is illustrated by the Crooks…

Statistical Mechanics · Physics 2014-09-30 Ronald F. Fox

We prove a robust extension of the quantum adiabatic theorem. The theorem applies to systems that have resonances instead of bound states, and to systems for which just an approximation to a bound state is known. To demonstrate the…

Mathematical Physics · Physics 2010-02-24 Alexander Elgart , George Hagedorn

We define common thermodynamic concepts purely within the framework of general Markov chains and derive Jarzynski's equality and Crooks' fluctuation theorem in this setup. In particular, we regard the discrete time case that leads to an…

Statistical Mechanics · Physics 2022-12-14 Pedro Hack , Sebastian Gottwald , Daniel A. Braun

We derive a time-dependent master equation for an externally driven system whose subsystems weakly interact with each other and locally connect to the thermal reservoirs. The nonadiabatic equation obtained here can be viewed as a…

Quantum Physics · Physics 2024-10-01 Chao Jiang , Lei Shao

Adiabaticity occurs when, during its evolution, a physical system remains in the instantaneous eigenstate of the hamiltonian. Unfortunately, existing results, such as the quantum adiabatic theorem based on a slow down evolution (H(epsilon…

Quantum Physics · Physics 2009-06-25 Daniel Comparat

We establish a connection between macroscopic "heating or cooling" of a finite many-body quantum system and the non-adiabatic Landau-Zener-St\"{u}ckelberg transitions between its quantum states. We have considered the well-known Nilsson…

Nuclear Theory · Physics 2019-11-12 Nishchal R. Dwivedi , Sudhir R. Jain

We discuss the stochastic thermodynamics of systems that are described by a time-dependent density field, for example simple liquids and colloidal suspensions. For a time-dependent change of external parameters, we show that the Jarzynski…

Statistical Mechanics · Physics 2014-03-18 T. Leonard , B. Lander , U. Seifert , T. Speck

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

We investigate a solvable model for energy conserving non-equilibrium steady states. The time-reversal asymmetry of the dynamics leads to the violation of detailed balance and to ergodicity breaking, as manifested by the presence of…

Statistical Mechanics · Physics 2011-11-09 Yair Shokef , Gal Shulkind , Dov Levine

We describe some solvable models which illustrate the Jarzynski theorem and related fluctuation theorems. We consider a charged particle in the presence of magnetic field in a two dimensional harmonic well. In the first case the centre of…

Statistical Mechanics · Physics 2015-06-25 A. M. Jayannavar , Mamata Sahoo

When a small dynamical system that is initially in contact with a heat bath is detached from this heat bath and then caused to undergo a quasi-static adiabatic processes, the statistical distribution of the system's energy differs from that…

Statistical Mechanics · Physics 2007-05-23 K. Sato , K. Sekimoto , T. Hondou , F. Takagi

The quantum Jarzynski equality and the Crooks relation are fundamental laws connecting equilibrium processes with nonequilibrium fluctuations. They are promising tools to benchmark quantum devices and measure free energy differences. While…

Statistical Mechanics · Physics 2023-11-07 Dominik Hahn , Maxime Dupont , Markus Schmitt , David J. Luitz , Marin Bukov

The probability densities of work that can be exerted on a quantum system initially staying in thermal equilibrium are constrained by the fluctuation relations of Jarzynski and Crooks, when the work is determined by two projective energy…

Quantum Physics · Physics 2019-03-20 Kosuke Ito , Peter Talkner , B. Prasanna Venkatesh , Gentaro Watanabe

We apply adiabatic theorems developed for quantum mechanics to stochastic annealing processes described by the classical master equation with a time-dependent generator. When the instantaneous stationary state is unique and the minimum…

Statistical Mechanics · Physics 2024-03-21 Kazutaka Takahashi

The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…

Statistical Mechanics · Physics 2007-05-23 V. M. Somsikov

The adiabatic theorem shows that the instantaneous eigenstate is a good approximation of the exact solution for a quantum system in adiabatic evolution. One may therefore expect that the geometric phase calculated by using the eigenstate…

Quantum Physics · Physics 2009-11-10 D. M. Tong , K. Singh , L. C. Kwek , C. H. Oh

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum…

Quantum Physics · Physics 2020-08-10 Akira Sone , Yi-Xiang Liu , Paola Cappellaro