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Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

Nonadditive Tsallis $q$-statistics has successfully been applied for a plethora of systems in natural sciences and other branches of knowledge. Nevertheless, its foundations have been severely criticised by some authors based on the…

Statistical Mechanics · Physics 2020-05-20 J. A. S. Lima , A. Deppman

Chemical reaction network theory is a powerful framework to describe and analyze chemical systems. While much about the concentration profile in an equilibrium state can be determined in terms of the graph structure, the overall reaction's…

Molecular Networks · Quantitative Biology 2024-02-29 Tomoharu Suda

To know the statistical distribution of a variable is an important problem in management of resources. Distributions of the power law type are observed in many real systems. However power law distributions have an infinite variance and thus…

Statistical Mechanics · Physics 2008-12-02 Hari M. Gupta , Jose R. Campanha

We propose the deterministic rate equation of three-species in the reaction - diffusion system. For this case, our purpose is to carry out the decay process in our three-species reaction-diffusion model of the form $A+B+C\to D$. The…

Statistical Mechanics · Physics 2009-10-31 Kyungsik Kim , K. H. Chang , Y. S. Kong

The principle of detailed balance states that in equilibrium each elementary process is equilibrated by its reverse process. For many real physico-chemical complex systems (e.g. homogeneous combustion, heterogeneous catalytic oxidation,…

Statistical Mechanics · Physics 2011-08-24 A. N. Gorban , G. S. Yablonsky

Many important applications in biochemistry, materials science, and catalysis sit squarely at the interface between quantum and statistical mechanics: coherent evolution is interrupted by discrete events, such as binding of a substrate or…

Chemical Physics · Physics 2020-03-06 Jacob R. Lindale , Shannon L. Eriksson , Christian P. N. Tanner , Warren S. Warren

We study reaction-diffusion processes on graphs through an extension of the standard reaction-diffusion equation starting from first principles. We focus on reaction spreading, i.e. on the time evolution of the reaction product, M(t). At…

Statistical Mechanics · Physics 2015-06-12 R. Burioni , S. Chibbaro , D. Vergni , A. Vulpiani

The general theory of a complex system of nonlinear chemical reactions is a primary language of chemistry that includes chemical engineering and cellular biochemistry. Its significance as an analytical framework, however, has not been fully…

Chemical Physics · Physics 2025-10-21 Liu Hong , Hong Qian

Quasi-power law ensembles are discussed from the perspective of nonextensive Tsallis distributions characterized by a nonextensive parameter $q$. A number of possible sources of such distributions are presented in more detail. It is further…

Statistical Mechanics · Physics 2023-07-19 Grzegorz Wilk , Zbigniew Włodarczyk

We continue our study of the linear response of a nonequilibrium system. This Part II concentrates on models of open and driven inertial dynamics but the structure and the interpretation of the result remain unchanged: the response can be…

Statistical Mechanics · Physics 2010-05-02 Marco Baiesi , Eliran Boksenbojm , Christian Maes , Bram Wynants

The analysis of the linearization effect in multifractal analysis, and hence of the estimation of moments for multifractal processes, is revisited borrowing concepts from the statistical physics of disordered systems, notably from the…

Statistical Mechanics · Physics 2011-07-28 Florian Angeletti , Marc Mézard , Eric Bertin , Patrice Abry

The rate of a chemical reaction can often be determined by the properties of a rank-1 saddle and the associated transition state separating reactants and products. We have found evidence that such rates can be controlled and even enhanced…

Chemical Physics · Physics 2021-09-28 Johannes Reiff , Robin Bardakcioglu , Matthias Feldmaier , Jörg Main , Rigoberto Hernandez

The standard analysis of reaction networks based on deterministic rate equations fails in confined geometries, commonly encountered in fields such as astrochemistry, thin film growth and cell biology. In these systems the small reactant…

Other Condensed Matter · Physics 2007-05-23 Ofer Biham , Joachim Krug , Azi Lipshtat , Thomas Michely

Order \alpha^2 corrections to the decay rate of orthopositronium are calculated in the framework of nonrelativistic QED. The resulting contribution is found to be in significant disagreement with one set of experimental measurements though…

High Energy Physics - Phenomenology · Physics 2009-10-31 G. S. Adkins , R. N. Fell , J. Sapirstein

A system of two cubic reaction-diffusion equations for two independent gene frequencies arising in population dynamics is studied. Depending on values of coefficients, all possible Lie and $Q$-conditional (nonclassical) symmetries are…

Exactly Solvable and Integrable Systems · Physics 2026-03-27 Philip Broadbridge , Roman Cherniha , Vasyl' Davydovych , Ian Marquette

We derive a massive analog of the ALD (Abraham, Lorentz and Dirac) equation, i.e., the equation of motion of a relativistic charged particle with a radiation reaction term induced by emissions of massive fields. We show that the radiation…

High Energy Physics - Theory · Physics 2013-05-30 Satoshi Iso , Sen Zhang

The Kramers' survival probability has been generalized by using nonextensive formalism. This nonextensive survival probability is studied in detail and associated Kramers' rate has been calculated in the high and low viscosity limit. It has…

Statistical Mechanics · Physics 2009-11-13 G. B. Bagci

Models of intermittent behaviour are usually formulated using a set of multiplicative random weights on a Cayley tree. However, intermittency in particle multiproduction from QCD jets is related to fragmentation of an additive quantum…

High Energy Physics - Phenomenology · Physics 2008-11-26 R. Peschanski

We analyze a reaction-diffusion system describing the growth of microbial species in a model of flocculation type that arises in biology. Existence of global classical positive solutions is proved under general growth assumptions, with…

Analysis of PDEs · Mathematics 2023-01-19 Jeffrey Morgan , Samia Zermani
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