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By using a newly fitted multi-parameter potential to describe the van der Waals interaction between carbon and molecular hydrogen, we study the hydrogen storage inside carbon nanotubes (CNT's) under pressure in gigapascal range. Comparing…

Materials Science · Physics 2007-07-09 X. H. Zhang , X. G. Gong , Z. F. Liu

We report the fabrication details and low-temperature characteristics of the first carbon nanotube (CNT) quantum dots on flakes of hexagonal boron nitride (hBN) as substrate. We demonstrate that CNTs can be grown on hBN by standard chemical…

Mesoscale and Nanoscale Physics · Physics 2014-07-21 A. Baumgartner , G. Abulizi , K. Watanabe , T. Taniguchi , J. Gramich , C. Schoenenberger

We demonstrate a fully tunable diode structure utilizing a fully suspended single-walled carbon nanotube (SWNT). The diode's turn-on voltage under forward bias can be continuously tuned up to 4.3 V by controlling gate voltages, which is ~6…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Chang-Hua Liu , Chung-Chiang Wu , Zhaohui Zhong

The ultra-low intershell shear strength in carbon nanotubes (CNTs) has been the primary obstacle to applications of CNTs as mechanical reinforcements. In this paper we propose a new CNT-system composed of comprising of coaxial cylindrical…

Materials Science · Physics 2009-03-12 Zhiping Xu , Lifeng Wang , Quanshui Zheng

Transparent and conductive films (TCFs) are of great technological importance. The high transmittance, electrical conductivity and mechanical strength make single-walled carbon nanotubes (SWCNTs) a good candidate for their raw material.…

The van der Waals and Casimir interactions of a hydrogen atom (molecule) with a single-walled and a multiwalled carbon nanotubes are compared. It is shown that the macroscopic concept of graphite dielectric permittivity is already…

Statistical Mechanics · Physics 2009-11-13 G. L. Klimchitskaya , E. V. Blagov , V. M. Mostepanenko

Ab initio calculations within the density-functional theory formalism are performed to investigate the ground state, electric charge doping, and electronic properties of titanium and titanium dioxide monolayers adsorbed on a graphene…

Materials Science · Physics 2013-01-17 Jozef Sivek , Ortwin Leenaerts , Bart Partoens , Francois Peeters

Theory predicts peculiar features for excited-state dynamics in one dimension (1D) that are difficult to be observed experimentally. Single-walled carbon nanotubes (SWNTs) are an excellent approximation to 1D quantum confinement, due to…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Giancarlo Soavi , Francesco Scotognella , Daniele Viola , Timo Hefner , Tobias Hertel , Giulio Cerullo , Guglielmo Lanzani

A simple process for chemical vapor deposition of ultra SD single wall carbon nanotubes has been developed. In this process, an iron nitrate nonahydrate solution in isopropyl alcohol with a concentration of 400 ug/mlit was used to catalyze…

Mesoscale and Nanoscale Physics · Physics 2012-07-17 Nima Arjmandi , Pejhman Sasanpour , Bijan Rashidian

Using inelastic electron tunneling spectroscopy with the scanning tunneling microscope (STM-IETS) and density functional theory calculations (DFT), we investigated properties of a single H2 molecule trapped in nanocavities with controlled…

Materials Science · Physics 2018-10-12 Hui Wang , Shaowei Li , Haiyan He , Arthur Yu , Freddy Toledo , Zhumin Han , W. Ho , Ruqian Wu

The complete energy expression of a deformed single-walled carbon nanotube (SWNT) is derived in the continuum limit from the local density approximation model proposed by Lenosky {\it et al.} \lbrack Nature (London) {\bf 355}, 333…

Materials Science · Physics 2007-05-23 Zhan-chun Tu , Zhong-can Ou-Yang

This study investigates hydrogen permeation in titanium aluminium nitride (TiAlN) using ab initio density functional theory (DFT) for cubic and hexagonal crystal structures. Despite the significance of hydrogen barriers, the potential of…

Materials Science · Physics 2024-10-03 Cem Örnek , Rainer Fechte-Heinen

Using a diffusion Monte Carlo (DMC) technique, we calculated the phase diagrams of $^4$He and H$_2$ adsorbed on a single (5,5) carbon nanotube, one of the narrowest that can be obtained experimentally. For a single monolayer, when the…

Other Condensed Matter · Physics 2023-05-31 M. C. Gordillo , J. Boronat

A parametric study of so-called "super growth" of single-walled carbon nanotubes(SWNTs) was done by using combinatorial libraries of iron/aluminum oxide catalysts. Millimeter-thick forests of nanotubes grew within 10 min, and those grown by…

Materials Science · Physics 2009-11-13 S. Noda , K. Hasegawa , H. Sugime , K. Kakehi , Z. Zhang , S. Maruyama , Y. Yamaguchi

Titanium borates show promissing hydrogen storage characteristics. Structural relaxation around individual hydrogen atoms and the binding energies are studied by means of the density functional theory methods for a number of hydrogenated…

Materials Science · Physics 2011-08-02 R. Žitko , H. J. P. Van Midden , E. Zupanič , A. Prodan , S. S. Makridis , D. Niarchos , A. K. Stubos

We predict properties of triplet excited states in single-walled carbon nanotubes (CNTs) using a time-dependent density-functional theory (TD-DFT). We show that the lowest triplet state energy in CNTs to be about 0.2-0.3 eV lower than the…

Materials Science · Physics 2015-06-25 Sergei Tretiak

Carbons are being widely investigated as hydrogen storage material owing to their light weight, fast hydrogen adsorption kinetics and cost effectiveness. However, these materials suffer from low hydrogen storage capacity, particularly at…

Materials Science · Physics 2014-09-26 Viney Dixit , Ashish Bhatnagar , R. R. Shahi , T. P. Yadav , O. N. Srivastava

We report a comprehensive study on the electrochemical performance of four different Transition Metal Oxides encapsulated inside carbon nanotubes (CNT). Irrespective of the type of oxide-encapsulate, all these samples exhibit superior…

We present ab initio calculations on the band structure and density of states of single wall semiconducting carbon nanotubes with high degrees (up to 25%) of B, Si and N substitution. The doping process consists of two phases: different…

Mesoscale and Nanoscale Physics · Physics 2015-01-13 E. Tetik

Double-walled carbon nanotubes (DWCNTs) combined the advantages of multi-walled (MW-) and single-walled (SW-) CNTs can be obtained by transforming the precursors (e.g. fullerene, ferrocene) into thin inner CNTs inside SWCNTs as templates.…

Materials Science · Physics 2019-01-28 Lei Shi , Jinquan Wei , Kazuhiro Yanagi , Takeshi Saito , Kecheng Cao , Ute Kaiser , Paola Ayala , Thomas Pichler