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We have experimentally checked the Jarzynski equality and the Crooks relation on the thermal fluctuations of a macroscopic mechanical oscillator in contact with a heat reservoir. We found that, independently of the time scale and amplitude…

Statistical Mechanics · Physics 2009-11-11 F. Douarche , S. Ciliberto , A. Petrosyan , I. Rabbiosi

We derive exact fluctuation equalities for open systems that recover free energy differences between two equilibrium endpoints connected by nonequilibrium processes with arbitrary dynamics and coupling. The exponential of the free energy…

Statistical Mechanics · Physics 2025-12-15 Mohammad Rahbar , Christopher J. Stein

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare…

Statistical Mechanics · Physics 2009-06-01 Michele Campisi , Peter Talkner , Peter Hänggi

The work fluctuations of a harmonic oscillator in contact with a thermostat and driven out of equilibrium by an external force are studied experimentally. For the work both the transient and stationary state fluctuation theorems hold. The…

Statistical Mechanics · Physics 2016-08-14 Sylvain Joubaud , Nicolas Garnier , Frédéric Douarche , Artem Petrosyan , Sergio Ciliberto

Crook's Fluctuation Theorem and Jarzynski equality are immensely powerful tools in obtaining equilibrium properties through non-equilibrium transition between two equilibrium states. In this letter, we propose an extension to the Crook's…

Statistical Mechanics · Physics 2017-01-17 Puneet Kumar Patra , Baidurya Bhattacharya

We study two non-equilibrium work fluctuation theorems, the Crooks' theorem and the Jarzynski equality, for a test system coupled to a spatially extended heat reservoir whose degrees of freedom are explicitly modeled. The sufficient…

Statistical Mechanics · Physics 2010-02-22 Punyabrata Pradhan , Yariv Kafri , Dov Levine

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

Quantum Physics · Physics 2025-08-21 Konstantin Beyer , Walter T. Strunz

The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

Statistical Mechanics · Physics 2025-05-13 Stephen Whitelam

The well-known Jarzynski equality, often written in the form $e^{-\beta\Delta F}=\langle e^{-\beta W}\rangle$, provides a non-equilibrium means to measure the free energy difference $\Delta F$ of a system at the same inverse temperature…

Statistical Mechanics · Physics 2017-08-22 Jiawen Deng , Juan D. Jaramillo , Peter Hanggi , Jiangbin Gong

The work fluctuations of an oscillator in contact with a thermostat and driven out of equilibrium by an external force are studied experimentally and theoretically within the context of Fluctuation Theorems (FTs). The oscillator dynamics is…

Statistical Mechanics · Physics 2007-05-23 Frederic Douarche , Sylvain Joubaud , Nicolas B. Garnier , Artem Petrosyan , Sergio Ciliberto

Understanding and manipulating work fluctuations in microscale and nanoscale systems are of both fundamental and practical interest. For example, aspects of work fluctuations will be an important factor in designing nanoscale heat engines.…

Statistical Mechanics · Physics 2014-11-26 Gaoyang Xiao , Jiangbin Gong

Fluctuation relations allow for the computation of equilibrium properties, like free energy, from an ensemble of non-equilibrium dynamics simulations. Computing them for quantum systems, however, can be difficult, as performing dynamic…

Quantum Physics · Physics 2021-09-07 Lindsay Bassman , Katherine Klymko , Diyi Liu , Norman M. Tubman , Wibe A. de Jong

The nonequilibrium work relation, or Jarzynski equality, establishes a statistical relationship between a series of nonequilibrium experiments on a system subjected to thermal fluctuations and a hypothetical experiment at thermodynamic…

Statistical Mechanics · Physics 2024-11-19 Jean-Luc Garden

We study work fluctuation theorems for oscillators in non-Markovian heat baths. By calculating the work distribution function for a harmonic oscillator with motion described by the generalized Langevin equation, the Jarzynski equality (JE),…

Statistical Mechanics · Physics 2009-11-11 Trieu Mai , Abhishek Dhar

In this work, we propose two models of coupled harmonic oscillators under Brownian motion to computationally study the applications of fluctuation theorems. This paper also illustrates how to analytically calculate free energy differences…

Statistical Mechanics · Physics 2025-09-03 Julián David Jiménez-Paz , José Daniel Muñoz-Castaño

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo

The exchange fluctuation theorem for heat exchanged between two systems at different temperatures, when kept in direct contact, has been investigated by C. Jarzynski and D. K. W\'ojcik, in Phys. Rev. Lett. {\bf 92}, 230602 (2004). We extend…

Statistical Mechanics · Physics 2016-01-07 Sourabh Lahiri , A. M. Jayannavar

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

Almost 25 years ago, Jarzynski published a paper in which it was asserted: the work done, W, in driving a system from state A to state B, characterized by the Helmholtz free energies FA and FB, satisfies an equality in which an average over…

General Physics · Physics 2022-06-07 Ronald F. Fox
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