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We report on a detailed single crystal x-ray diffraction study of the unconventional spin-Peierls compound TiOCl. The intermediate phase of TiOCl is characterized by an incommensurate modulation which is virtually identical to that recently…

Strongly Correlated Electrons · Physics 2007-05-23 A. Krimmel , J. Strempfer , B. Bohnenbuck , B. Keimer , M. Hoinkis , M. Klemm , S. Horn , A. Loidl , M. Sing , R. Claessen , M. v. Zimmermann

We report on the magnetic, thermodynamic and optical properties of the quasi-one-dimensional quantum antiferromagnets TiOCl and TiOBr, which have been discussed as spin-Peierls compounds. The observed deviations from canonical spin-Peierls…

Strongly Correlated Electrons · Physics 2009-11-11 R. Rückamp , J. Baier , M. Kriener , M. W. Haverkort , T. Lorenz , G. S. Uhrig , L. Jongen , A. Möller , G. Meyer , M. Grüninger

In this sturdy, we determine the roles of two successive phase transitions in the new spin-Peierls system TiOBr by electron and synchrotron X-ray diffraction analyses. Results show an incommensurate superstructure along the h- and…

Strongly Correlated Electrons · Physics 2009-11-11 T. Sasaki , M. Mizumaki , T. Nagai , T. Asaka , K. Kato , M. Takata , Y. Matsui , J. Akimitsu

The sequence of phase transitions and the symmetry of in particular the low temperature incommensurate and spin-Peierls phases of the quasi one-dimensional inorganic spin-Peierls system TiOX (TiOBr and TiOCl) have been studied using…

Temperature-dependent x-ray diffraction of the low-dimensional spin 1/2 quantum magnet TiOCl shows that the phase transition at T_{c2} = 90 K corresponds to a lowering of the lattice symmetry. Below T_{c1} = 66 K a twofold superstructure…

Materials Science · Physics 2009-11-11 M. Shaz , S. van Smaalen , L. Palatinus , M. Hoinkis , M. Klemm , S. Horn , R. Claessen

Going beyond a recently proposed microscopic model for the incommensurate transition in the spin-Peierls TiOX (X=Cl, Br) compounds, in the present work we start by studying the thermodynamics of the model with XY spins and adiabatic…

Strongly Correlated Electrons · Physics 2009-10-02 D. M. Mastrogiuseppe , M. E. Torio , C. J. Gazza , A. O. Dobry

In the present work we aim to characterize the lattice configurations and the magnetic behavior in the incommensurate phase of spin-Peierls systems. This phase emerges when the magnetic exchange interaction is coupled to the distortions of…

Strongly Correlated Electrons · Physics 2011-04-26 D. Mastrogiuseppe , C. Gazza , A. Dobry

X-ray scattering measurements on single crystals of TiOCl reveal the presence of commensurate dimerization peaks within both the incommensurate spin-Peierls phase and the so-called pseudogap phase above T_c2. This scattering is relatively…

Strongly Correlated Electrons · Physics 2016-08-05 J. P. Clancy , B. D. Gaulin , K. C. Rule , J. P. Castellan , F. C. Chou

We have performed detailed x-ray scattering measurements on single crystals of the spin-Peierls compound TiOBr in order to study the critical properties of the transition between the incommensurate spin-Peierls state and the paramagnetic…

Strongly Correlated Electrons · Physics 2016-08-05 J. P. Clancy , B. D. Gaulin , F. C. Chou

We have investigated non-equilibrium properties of proper uniaxial Sn$_2$P$_2$(Se$_x$S$_{1-x}$)$_6$ ferroelectrics with the Type II incommensurate phase above Lifshitz point $x_{\rm LP} \sim 0.28$. We measured dielectric susceptibility with…

The interest in the study of spin-Peierls phenomenon has increased with the discovery of copper germanium oxide (CuGeO_3) as an example of spin-Peierls systems. The availability of this inorganic compound as large, high quality single…

Strongly Correlated Electrons · Physics 2007-05-23 J. Srivatsava

The magnetic phase transitions reported below 230 K in cupric oxide are analyzed theoretically at the macroscopic and microscopic levels. The incommensurate multiferroic and lock-in commensurate phases are shown to realize an inverted…

We investigated the magnetic and structural properties of the quasi-one dimensional 3$d^1$-quantum chain system TiPO$_4$ ($J \sim$ 965 K) by magnetic susceptibility, heat capacity, ESR, x-ray diffraction, NMR measurements, and by density…

Strongly Correlated Electrons · Physics 2019-09-25 J. M. Law , C. Hoch , R. Glaum , I. Heinmaa , R. Stern , J. Kang , C. Lee , M. -H. Whangbo , R. K. Kremer

Incommensurate magnetism in CrB$_2$ is studied in terms of a spin model based on density functional theory calculations. Heisenberg exchange interactions derived from the paramagnetic phase using the disordered local moment theory show…

Strongly Correlated Electrons · Physics 2022-10-12 András Deák , Jerome Jackson , Bendegúz Nyári , László Szunyogh

On the basis of ab initio density functional theory (DFT) calculations, we derive the underlying microscopic model Hamiltonian for TiOCl, a unique system that shows two consecutive phase transitions from a Mott insulator to a spin-Peierls…

Strongly Correlated Electrons · Physics 2008-11-07 Yu-Zhong Zhang , Harald O. Jeschke , Roser Valenti

Neutron scattering studies of single-crystal LiNiPO$_4$ reveal a spontaneous first-order commensurate-incommensurate magnetic phase transition. Short- and long-range incommensurate phases are intermediate between the high temperature…

Strongly Correlated Electrons · Physics 2009-11-10 D. Vaknin , J. L. Zarestky , J. -P. Rivera , H. Schmid

Two phase transitions in the tetragonal strongly correlated electron system CeNiAsO were probed by neutron scattering and zero field muon spin rotation. For $T <T_{N1}$ = 8.7(3) K, a second order phase transition yields an incommensurate…

Using neutron scattering techniques, we have studied incommensurate spin ordering as well as low energy spin dynamics in single crystal underdoped \LBCO with x$\sim$0.095 and 0.08; high temperature superconductors with T$_C \sim$ 27 K and…

Superconductivity · Physics 2009-11-13 S. R. Dunsiger , Y. Zhao , Z. Yamani , W. J. L. Buyers , H. Dabkowska , B. D. Gaulin

Using elastic and inelastic neutron scattering we show that a cubic spinel, CdCr$_2$O$_4$, undergoes an elongation along the c-axis ($c > a = b$) at its spin-Peierls-like phase transition at $T_N$ = 7.8 K. The N\'{e}el phase ($T < T_N$) has…

Strongly Correlated Electrons · Physics 2009-11-11 J. -H. Chung , M. Matsuda , S. -H. Lee , K. Kakurai , H. Ueda , T. J. Sato , H. Takagi , K. -P. Hong , S. Park

The magnetostructural transitions and magnetoelectric effects reported in TbMn2O5 are described theoretically and shown to correspond to two essentially different mechanisms for the induced ferroelectricity. The incommensurate and…

Materials Science · Physics 2010-01-22 P. Toledano , W. Schranz , G. Krexner
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