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Developing realistic and precise models of the electronic properties of organic molecular crystals is crucial for understanding the full range of strongly correlated phases that they exhibit. By using \textit{ab initio} model construction…

Strongly Correlated Electrons · Physics 2015-09-01 A. C. Jacko

The construction of exponentially localized Wannier functions for a set of bands requires a choice of Bloch-like functions that span the space of the bands in question, and are smooth and periodic functions of k in the entire Brillouin…

Mesoscale and Nanoscale Physics · Physics 2016-02-03 Georg W. Winkler , Alexey A. Soluyanov , Matthias Troyer

We prove the existence of higher-order topological insulators in: {\it i}) fourfold rotoinversion invariant bulk crystals, and {\it ii}) inversion-symmetric systems with or without an additional three-fold rotation symmetry. These states of…

Mesoscale and Nanoscale Physics · Physics 2018-08-22 Guido van Miert , Carmine Ortix

Topological phases, such as Chern insulators, are defined in terms of additive indices that are stable against the addition of trivial degrees of freedom. Such topology presents an obstruction to any Wannier representation, namely, the…

Mesoscale and Nanoscale Physics · Physics 2018-09-20 Hoi Chun Po , Haruki Watanabe , Ashvin Vishwanath

We introduce a Wannier-type formulation of periodic local vibrational mode theory that yields real-space-localized vibrational modes associated with individual internal coordinates in crystalline solids. These modes are constructed as…

Materials Science · Physics 2026-05-12 Mateusz Mojsak , Elfi Kraka , Adam A. L. Michalchuk

We revisit the electronic structure and band topology of monolayer 1H-NbSe$_2$, which hosts both superconductivity and charge density wave, and its related compounds 1H-MoS$_2$, NbS$_2$, TaS$_2$, TaSe$_2$ and WS$_2$. We construct a 6-band,…

We calculate the electronic structure of the narrow gap semiconductors PbTe, SnTe and GeTe in the cubic phase using density functional theory (DFT) and the $G_0W_0$ method. Within DFT, we show that the band ordering obtained with a…

Mesoscale and Nanoscale Physics · Physics 2020-10-21 Pablo Aguado-Puente , Stephen Fahy , Myrta Grüning

The electronic ground state of a periodic crystalline solid is usually described in terms of extended Bloch orbitals; localized Wannier functions can alternatively be used. These two representations are connected by families of unitary…

Materials Science · Physics 2009-10-31 Nicola Marzari , David Vanderbilt

To solve the Kohn-Sham equation within the framework of density functional theory, we develop a scheme to construct numerical atomic orbital (NAO) basis sets by contracting truncated spherical waves (TSWs). The contraction minimizes the…

Chemical Physics · Physics 2026-04-10 Yike Huang , Zuxin Jin , Linfeng Zhang , Mohan Chen , Rui Chen , Ling Li

The theory of orbital magnetization is reconsidered by defining additional quantities that incorporate a non-Hermitian effect due to anomalous operators that break the domain of definition of the Hermitian Hamiltonian. As a result, boundary…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 K. Kyriakou , K. Moulopoulos

Recent interest in point and line node semimetals has led to the proposal and discovery of these phenomena in numerous systems. Frequently, though, these nodal systems are described in terms of individual properties reliant on specific…

Mesoscale and Nanoscale Physics · Physics 2016-10-12 Benjamin J. Wieder , C. L. Kane

We investigate the electronic structure of SrMnO$_3$ with Density Functional Theory (DFT) plus Dynamical Mean-Field Theory (DMFT). Within this scheme the selection of the correlated subspace and the construction of the corresponding Wannier…

Strongly Correlated Electrons · Physics 2018-06-20 Daniel Bauernfeind , Robert Triebl , Manuel Zingl , Markus Aichhorn , Hans Gerd Evertz

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

Screened spherical wave (SSW) of the Hankel function features the complete, minimal and short-ranged basis set, presenting a compact representation for electronic systems. In this work, we report the implementation of full-potential (FP)…

Materials Science · Physics 2025-03-11 Aixia Zhang , Qingyun Zhang , Zhiyi Chen , Yong Wu , Youqi Ke

Nonsymmorphic symmetries can enforce band connectivity that obstructs a single-band Wannier description. We show that a fractional translation $\mathcal{L}$ connecting distinct high-symmetry Wyckoff positions generically renders the Wannier…

Superconductivity · Physics 2026-01-06 Qinghua He , Jie Zhang , Shengdan Tao , Hai-yao Deng , Qifeng Liang , Wenlong Gao , Feng Liu

Construction of maximally localized Wannier functions (MLWFs) has been implemented within the linear combination of pseudo-atomic orbital (LCPAO) method. Detailed analysis using MLWFs is applied to three closely related materials, single…

Materials Science · Physics 2013-05-29 Hongming Weng , Taisuke Ozaki , Kiyoyuki Terakura

For a large class of physically relevant operators on a manifold with discrete group action, we prove general results on the (non-)existence of a basis of smooth well-localised Wannier functions for their spectral subspaces. This turns out…

Mathematical Physics · Physics 2022-01-19 Matthias Ludewig , Guo Chuan Thiang

While topology can impose obstructions to exponentially localized Wannier functions, certain topological insulators are exempt from such Wannier obstructions. The absence of the Wannier obstructions can further accompany topological…

Mesoscale and Nanoscale Physics · Physics 2025-08-29 Daichi Nakamura , Ken Shiozaki , Kenji Shimomura , Masatoshi Sato , Kohei Kawabata

We propose a unique scheme to construct fully optimized atomic basis sets for density-functional calculations. The shapes of the radial functions are optimized by minimizing the {\it spillage} of the wave functions between the atomic…

Materials Science · Physics 2015-05-19 Mohan Chen , G-C Guo , Lixin He

The paper presents the group theory of best localized and symmetry-adapted Wannier functions in a crystal of any given space group G or magnetic group M. Provided that the calculated band structure of the considered material is given and…

Strongly Correlated Electrons · Physics 2015-05-22 Ekkehard Krüger , Horst P. Strunk
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