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We discuss the current status of the theory of the "high-temperature" superconductivity in intercalated graphites YbC6 and CaC6. We emphasize that while the general picture of conventional, phonon-driven superconductivity has already…

Superconductivity · Physics 2009-11-11 I. I. Mazin , L. Boeri , O. V. Dolgov , A. A. Golubov , G. B. Bachelet , M. Giantomassi , O. K. Andersen

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Superconductivity · Physics 2015-06-25 Thomas E. Weller , Mark Ellerby , Siddharth S. Saxena , Robert P. Smith , Neal T. Skipper

The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs),…

Superconductivity · Physics 2015-05-20 M. H. Upton , T. R. Forrest , A. C. Walters , C. A. Howard , M. Ellerby , A. H. Said , D. F. McMorrow

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the…

Superconductivity · Physics 2009-11-11 J. S. Kim , R. K. Kremer , L. Boeri , F. S. Razavi

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

Superconductivity · Physics 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

We report the discovery of superconductivity below 1.65(6) K in Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp) measurements. In comparison with CaC6, we found that the anisotropy of the upper critical fields for…

Superconductivity · Physics 2009-11-13 J. S. Kim , L. Boeri , J. R. O'Brien , F. S. Razavi , R. K. Kremer

The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6…

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

Using density functional theory we investigate the occurrence of superconductivity in AC$_6$ with A=Mg,Ca,Sr,Ba. We predict that at zero pressure, Ba and Sr should be superconducting with critical temperatures (T$_c$) 0.2 K and 3.0 K,…

Superconductivity · Physics 2009-11-11 Matteo Calandra , Francesco Mauri

The low energy phonons of two different graphite intercalation compounds (GICs) have been measured as a function of temperature using inelastic x-ray scattering (IXS). In the case of the non-superconductor BaC6, the phonons observed are…

Using density functional theory we demonstrate that superconductivity in C6Ca is due to a phonon-mediated mechanism with electron-phonon coupling 0.83 and phonon-frequency logarithmic-average 24.7 meV. The calculated isotope exponents are…

Superconductivity · Physics 2007-05-23 Matteo Calandra , Francesco Mauri

The deposition and intercalation of metal atoms can induce superconductivity in monolayer and bilayer graphenes. For example, it has been experimentally proved that Li-deposited graphene is a superconductor with critical temperature $T_{c}$…

Superconductivity · Physics 2024-05-07 Jin-Han Tan , Hao Wang , Ying-Jie Chen , Na Jiao , Meng-Meng Zheng , Hong-Yan Lu , Ping Zhang

Recent observation of proximity effect \cite{Morpurgo:2007} has ignited interest in superconductivity in graphene and its derivatives. We consider Ca-intercalated graphene bilayer and argue that it is a superconductor, and likely with a…

Superconductivity · Physics 2008-03-27 I. I. Mazin , A. V. Balatsky

We have studied the evolution, with hydrostatic pressure, of the recently discovered superconductivity in the graphite intercalation compounds C$_6$Yb and C$_6$Ca. We present pressure-temperature phase diagrams, for both superconductors,…

On the basis of the model that was successfully applied to KC8, RbC8, and CsC8 in 1982, we have calculated the superconducting transition temperature Tc for CaC6 and YbC6 to find that the same model reproduces the observed Tc in those…

Superconductivity · Physics 2016-01-13 Yasutami Takada

Ca-intercalation has opened a way for superconductivity in graphene on SiC. However, the atomic and electronic structures being critical for superconductivity are still under discussion. We find the essential role of the interface between…

The discovery of superconductivity in CaC6 with a critical temperature (Tc) of 11.5 K reignites much interest in exploring high-temperature superconductivity in graphite intercalation compounds (GICs). Here we identify a GIC NaC4,…

Superconductivity in intercalated graphite CaC6 and H under extreme pressure, in the framework of superconducting density functional theory, is discussed. A detailed analysis on how the electron-phonon and electron-electron interactions…

We have measured the Ca isotope effect in the newly discovered superconductor CaC6. The isotope effect coefficient is 0.50(7). If one assumes that this material is a conventional electron-phonon coupled superconductor, this result shows…

Superconductivity · Physics 2015-06-25 D. G. Hinks , D. Rosenmann , H. Claus , M. S. Bailey , J. D. Jorgensen

We report the superconductivity in Ca-intercalated bilayer graphene C$_6$CaC$_6$, the thinnest limit of Ca graphite intercalation compound. We performed \textit{in situ} electrical transport measurements on pristine bilayer graphene,…

Superconductivity · Physics 2016-02-02 S. Ichinokura , K. Sugawara , A. Takayama , T. Takahashi , S. Hasegawa
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