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We have performed photoemission studies of the electronic structure in LiC$_6$ and KC$_8$, a non-superconducting and a superconducting graphite intercalation compound, respectively. We have found that the charge transfer from the…

Superconductivity · Physics 2011-05-20 Z. -H. Pan , J. Camacho , M. H. Upton , A. V. Fedorov , C. A. Howard , M. Ellerby , T. Valla

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Superconductivity · Physics 2015-06-25 Thomas E. Weller , Mark Ellerby , Siddharth S. Saxena , Robert P. Smith , Neal T. Skipper

Graphite intercalation compounds (GICs) have long been recognized as promising candidates for high-temperature superconductivity by intercalation or charge doping, yet experimental progress has stalled with transition temperatures (Tc)…

Motivated by the recent discovery of superconductivity in Ca- and Yb-intercalated graphite (CaC$_{6}$ and YbC$_{6}$) and from the ongoing debate on the nature and role of the interlayer state in this class of compounds, in this work we…

Superconductivity · Physics 2016-08-14 Lilia Boeri , Giovanni B. Bachelet , Matteo Giantomassi , Ole K. Andersen

The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6…

We study the superconducting phase transition, both in a graphene bilayer and in graphite. For that purpose we derive the mean-field effective potential for a stack of graphene layers presenting hopping between adjacent sheets. For…

Superconductivity · Physics 2020-10-05 Lizardo H. C. M. Nunes , E. C. Marino , A. L. Mota

This work introduces a new class of two-dimensional crystals with the structure AC$_8$XC$_8$, consisting of two layers of graphene, a chalcogen (X = O, S, Se, Te) intercalation layer, and an alkaline earth (A = Be, Ca, Mg, Sr, Ba) adlayer.…

Mesoscale and Nanoscale Physics · Physics 2025-03-11 Tommy Li

We report experimental results indicating possible high-temperature superconductivity in graphite intercalation compounds synthesized with lithium-based alloys. Temperature-dependent measurements of magnetization, trapped magnetic flux, and…

A recent ab initio investigation of Na-C binary compounds under moderate pressures has uncovered a possible stable NaC$_4$ superconductor with an estimated critical temperature up to 41K. We revisit this promising binary system by…

The discovery of superconductivity in CaC6 with a critical temperature (Tc) of 11.5 K reignites much interest in exploring high-temperature superconductivity in graphite intercalation compounds (GICs). Here we identify a GIC NaC4,…

First-principles calculations of the electronic structure and vibrational modes, in a system of graphene bilayers and trilayers intercalated with alkaline earth atoms, are resented. It is found that, in similarity to the case of…

Superconductivity · Physics 2011-07-12 R. A. Jishi , D. M. Guzman , H. M. Alyahyaei

Ca-intercalation has opened a way for superconductivity in graphene on SiC. However, the atomic and electronic structures being critical for superconductivity are still under discussion. We find the essential role of the interface between…

The 2D Fermi surface of 1st stage PdAl2Cl8 acceptor-type graphite intercalation compounds (GICs) has been investigated using the Shubnikov-de Haas (SdH) effect. One fundamental frequency is observed, the angular variation of which confirms…

Materials Science · Physics 2007-05-23 R. T. F. van Schaijk , A. de Visser , E. McRae , B. Sundqvist , T. Wagberg , R. Vangelisti

We investigate the structural and electronic properties of Li-intercalated monolayer graphene on SiC(0001) using combined angle-resolved photoemission spectroscopy and first-principles density functional theory. Li intercalates at room…

Electrons in isolated graphene layers are a two-dimensional gas of massless Dirac Fermions. In realistic devices, however, the electronic properties are modified by elastic deformations, interlayer coupling and substrate interaction. Here…

The high pressure phase diagram of CsC8 graphite intercalated compound has been investigated at ambient temperature up to 32 GPa. Combining X-ray and neutron diffraction, Raman and X- ray absorption spectroscopies, we report for the first…

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

Superconductivity · Physics 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

Superconductivity in graphite intercalated compounds has been studied for more than 40 years and it is still not fully understood, despite the recent progress and the discovery of relatively high Tc superconductivity in CaC6 and YbC6.…

Superconductivity · Physics 2009-04-14 T. Valla , J. Camacho , Z-H. Pan , A. V. Fedorov , A. C. Walters , C. A. Howard , M. Ellerby

Using density functional theory calculations, we have investigated the structural, energetic, and electronic properties of ternary graphite intercalation compounds (GICs) containing alkali atoms (AM) and normal alkylamine molecules (nC$x$),…

Materials Science · Physics 2017-09-20 Gum-Chol Ri , Chol-Jun Yu , Jin-Song Kim , Song-Nam Hong , Un-Gi Jong , Mun-Hyok Ri
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