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The low temperature physics of parahydrogen (ph2) confined in cylindrical channels of diameter of the order of 1 nm is studied theoretically by Quantum Monte Carlo simulations. On varying the attractive strength of the wall of the…

Chemical Physics · Physics 2016-03-09 Tokunbo Omiyinka , Massimo Boninsegni

Molecular para-hydrogen has been proposed theoretically as a possible candidate for superfluidity, but the eventual superfluid transition is hindered by its crystallization. In this work, we study a metastable non crystalline phase of bulk…

Other Condensed Matter · Physics 2015-06-05 O. N. Osychenko , R. Rota , J. Boronat

Mean field analysis of the effective interfacial Hamiltonian shows that with increasing temperature the adsorption on a periodically corrugated substrate can proceed in two steps: first, there is the filling transition in which the…

Statistical Mechanics · Physics 2009-10-31 K. Rejmer , M. Napiorkowski

Hydrogen is a key player in global strategies to reduce greenhouse gas emissions. In order to make hydrogen a widely-used fuel, we require more efficient methods of storing it than the current standard of pressurized cylinders. An…

Materials Science · Physics 2025-01-14 Yasmine S. Al-Hamdani , Andrea Zen , Angelos Michaelides , Dario Alfè

It is commonly believed that it is unfavourable for adsorbed H atoms on carbonaceous surfaces to form H$_2$ without the help of incident H atoms. Using ring-polymer instanton theory to describe multidimensional tunnelling effects, combined…

Chemical Physics · Physics 2022-04-05 Erxun Han , Wei Fang , Michail Stamatakis , Jeremy O. Richardson , Ji Chen

We present a first-principles study of the atomic hydrogen adsorption onto the Be(10\={1}0) thin film. There are two types of Be(10\={1}0) surfaces according to the interlayer spacing between the surface and its nearest-neighbor layer. We…

Materials Science · Physics 2007-05-23 Ping Zhang , Hong-Zhou Song

The shift from fossil fuels to renewable energy sources is essential for reducing global carbon emissions and addressing climate change. Developing advanced materials for efficient hydrogen storage enables sustainable energy solutions in…

We devise a theory of adsorption of low-energy atoms on suspended graphene membranes maintained at 10 K based on a model of atom-acoustic phonon interactions. Our primary technique includes a non-perturbative method which treats the…

Mesoscale and Nanoscale Physics · Physics 2020-01-06 Sanghita Sengupta

The absorption energy of atomic hydrogen at rotated graphene bilayers is studied using ab initio methods based on the density functional theory including van der Waals interactions. We find that, due to the surface corrugation induced by…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Ivan Brihuega , Felix Yndurain

Multilayer sorption isotherms of 1-propanol on graphite have been measured by means of high-resolution ellipsometry within the liquid regime of the adsorbed film for temperatures ranging from 180 to 260 K. In the first three monolayers the…

Chemical Physics · Physics 2015-03-19 Matthias Wolff , Frank Kruchten , Patrick Huber , Klaus Knorr , Ulrich G. Volkmann

The adsorption and diffusion of F2 molecules on pristine graphene have been studied using first-principles calculations. For the diffusion of F2 from molecular state in gas phase to the dissociative adsorption state on graphene surface, a…

Materials Science · Physics 2018-11-28 Yong Yang , Fuchi Liu , Yoshiyuki Kawazoe

Hydrogenation of graphene on the \alpha-quartz (0001) SiO_2 substrate is studied, considering different surface terminations in order to take into account the amorphic nature of the material. Our ab initio calculations show that the…

Mesoscale and Nanoscale Physics · Physics 2012-01-16 P. Havu , M. Ijäs , A. Harju

Evidence for a new type of superfluid phase in second-layer $^4$He on graphite has been obtained from simultaneous measurements of torsional-oscillator response and heat-capacity on exactly the same sample down to 30 mK, which resolve…

Other Condensed Matter · Physics 2026-01-12 Jun Usami , Hiroshi Fukuyama

A few atomic layers of helium adsorbed on graphite have been attracting much attention as one of the ideal quantum systems in two dimension. Although previous reports on neutron diffraction have shown fundamental structural information in…

We observed surface X-ray diffraction from He-4 submonolayers adsorbed on a single-surface graphite using synchrotron X-rays. Time evolutions of scattering intensities along the crystal truncation rod (CTR) were observed even after reaching…

A reversible thermotropic phase transition in an adsorption melissic acid film at the interface between n-hexane and an aqueous solution of potassium hydroxide (pH=10) is investigated by X-ray reflectometry and diffuse scattering using…

Soft Condensed Matter · Physics 2017-10-27 Aleksey M. Tikhonov

We study a sub monolayer He-4 adsorbed on fluorographene (GF) and on hexagonal boron nitride (hBN) at low coverage. The adsorption potentials have been computed ab-initio with a suitable density functional theory including dispersion…

Other Condensed Matter · Physics 2021-06-09 Saverio Moroni , Francesco Ancilotto , Pier Luigi Silvestrelli , Luciano Reatto

Hydrogen adsorption on graphene-supported metal clusters has brought much controversy due to the complex nature of the bonding between hydrogen and metal clusters. The bond types of hydrogen and graphene-supported Ti clusters are…

The formation of H2 in the interstellar medium proceeds on the surfaces of silicate or carbonaceous particles. To get a deeper insight of its formation on the latter substrate, this letter focuses on H2 desorption from graphite (0001) in…

Solar and Stellar Astrophysics · Physics 2009-07-21 E. Gavardi , H. M. Cuppen , L. Hornekaer

Simulation evidence of an incipient triple point is reported for xenon submonolayers adsorbed on the (111) surface of platinum. This is in stark contrast to the "normal" triple point found in simulations and experiments for xenon on the…

Materials Science · Physics 2016-01-06 Anthony D. Novaco , L. W. Bruch , Jessica Bavaresco