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By combining first-principles electronic-structure calculations with the model Hamiltonian approach, we systematically study the magnetic properties of sodium superoxide (NaO2), originating from interacting superoxide molecules. We show…

Materials Science · Physics 2013-12-19 I. V. Solovyev , Z. V. Pchelkina , V. V. Mazurenko

The superconducting current has been observed in mesa-heterostructures Nb/Au/Sr2IrO4/YBa2Cu3Ox with Sr2IrO4 interlayer thickness d=5 and 7 nm and in-plane sizes L=10-50 mcm. A strontium iridate, Sr2IrO4, is known as a canted…

We fabricated the c axis and ab-plane biaxially aligned Sr0.6K0.4Fe2As2 superconductor using a two-step magnetic field procedure. The effect of magnetic fields on the structure and superconducting properties of Sr0.6K0.4Fe2As2 has been…

Studies of the NMR Knight shift K of Na0.3CoO2.yH2O have been carried out in detail. The suppression of K by the occurrence of the superconductivity reported previously by the present authors in both magnetic field directions perpendicular…

Superconductivity · Physics 2009-11-11 Yoshiaki Kobayashi , Taketo Moyoshi , Hidekazu Watanabe , Mai Yokoi , Masatoshi Sato

NaxCoO2 has emerged as a material of exceptional scientific interest due to the potential for thermoelectric applications, and because the strong interplay between the magnetic and superconducting properties has led to close comparisons…

Temperature dependent electrical resistivity, crystal structure and heat capacity measurements reveal a resistivity drop and metal to semiconductor transition corresponding to first order structural phase transition near 400 K in Ca3Co4O9.…

Materials Science · Physics 2012-04-17 Tao Wu , Trevor A. Tyson , Haiyan Chen , Jianming Bai , Hsin Wang , Cherno Jaye

Structural properties of the spin chain and ladder compound Sr$_{14}$Cu$_{24}$O$_{41}$ have been studied using diffraction with hard x-rays. Strong incommensurate modulation reflections are observed due to the lattice mismatch of the chain…

Strongly Correlated Electrons · Physics 2007-05-23 M. v. Zimmermann , J. Geck , S. Kiele , R. Klingeler , B. Büchner

We have compared by $^{23}$Na NMR and magnetic susceptibility the magnetic properties of oriented powder samples of Na$_{x}$CoO$_{2}$ compounds. The NMR spectra are found identical for various samples with nominal $0.50\leq x\leq 0.70,$…

Strongly Correlated Electrons · Physics 2007-05-23 I. R. Mukhamedchine , H. Alloul , G. Collin , N. Blanchard

The magnetic properties and structure of LixCoO2 for x between 0.5 and 1.0 are reported. Co4+ is found to be high-spin in LixCoO2 for x between 0.94 and 1.0 and low-spin for x between 0.50 and 0.78. Weak antiferromagnetic coupling is…

Strongly Correlated Electrons · Physics 2009-02-12 J. T. Hertz , Q. Huang , T. McQueen , T. Klimczuk , J. W. G. Bos , L. Viciu , R. J. Cava

The structure and magnetic properties of nanocrystalline PrCo$_3$ obtained from high energy milling technique are investigated by X-ray diffraction, Curie temperature determination and magnetic properties measurements are reported. The…

Materials Science · Physics 2015-05-28 K. Younsi , V. Russier , L. Bessais , J. -C. Crivello

Polycrystalline samples of a new superconducting EuAsFeO0.85F0.15 compound with critical temperature Tc=11K were prepared by solid state synthesis. Its electric and magnetic properties have been investigated in magnetic fields from 0.1 to…

The results of magnetic susceptibility, electrical resistivity ($\rho$), heat-capacity (C) and thermopower (S) measurements on CeCuAs2, forming in ZrCuSi2-type tetragonal structure, are reported. Our investigations reveal that Ce is…

Neutron scattering studies have been carried out on polycrystalline samples of a series of rare earth intermetallic compounds RCuAs$_2$ (R = Pr, Nd, Dy, Tb, Ho and Yb) as a function of temperature to determine the magnetic structures and…

Materials Science · Physics 2017-07-19 Y. Zhao , J. W. Lynn , Gohil S. Thakur , Zeba Haque , L. C. Gupta , A K Ganguli

The crystal structure of Na0.5CoO2, determined by powder neutron diffraction, is reported. The structure consists of layers of edge-shared CoO6 octahedra in a triangular lattice, with Na ions occupying ordered positions in the interleaving…

Strongly Correlated Electrons · Physics 2009-11-10 Q. Huang , M. L. Foo , J. W. Lynn , H. W. Zandbergen , G. Lawes , Yayu Wang , B. H. Toby , A. P. Ramirez , N. P. Ong , R. J. Cava

We report on the investigation of morphology, magnetic and conductive properties of the mutilayered nanostructures [(Co$_{40}$Fe$_{40}$B$_{20}$)$_{34}$(SiO$_2$)$_{66}$]/[C]$_{47}$ consisting of the contacting magnetic…

The structural and magnetic properties of the hexagonal four-layer form of SrMnO$_3$ have been investigated by combining magnetization measurements, electron diffraction and high-resolution synchrotron X-ray and neutron powder diffraction.…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , C. Martin , L. C. Chapon , M. Hervieu , K. S. Knight , M. Brunelli , P. G. Radaelli

Measurements of electrical resistivity ($\rho$), DC magnetization ($M$) and specific heat ($C$) have been performed on layered oxide Li$_x$CoO$_2$ (0.25$\leq$$x$$\leq$0.99) using single crystal specimens. The $\rho$ versus temperature ($T$)…

Strongly Correlated Electrons · Physics 2015-05-19 K. Miyoshi , C. Iwai , H. Kondo , M. Miura , S. Nishigori , J. Takeuchi

We report an experimental and computational study of magnetic and electronic properties of the layered Ru(V) oxide SrRu2O6 (hexagonal, P-3 1m), which shows antiferromagnetic order with a N\'eel temperature of 563(2) K, among the highest for…

Single crystals of Na$_{0.5}$CoO$_2$ were obtained through a flux method followed by de-intercalation of sodium. The Na$_{0.5}$CoO$_2$ samples were found to be vulnerable to water in the air and a hydration process in which H$_2$O molecules…

Strongly Correlated Electrons · Physics 2007-05-23 X. Z. Chen , Z. A. Xu , G. H. Cao , J. Q. Shen , L. M. Qiu , Z. H. Gan

Here we report the magnetic properties of the layered cobalt oxide system, LixCoO2, in the whole range of Li composition, 0 <= x <= 1. Based on dc-magnetic susceptibility data, combined with results of 59Co-NMR/NQR observations, the…

Strongly Correlated Electrons · Physics 2009-10-17 T. Motohashi , T. Ono , Y. Sugimoto , Y. Masubuchi , S. Kikkawa , R. Kanno , M. Karppinen , H. Yamauchi