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The concept of vibrational density of states in glasses has been mirrored in liquids by the instantaneous-normal-mode spectrum. While in glasses instantaneous configurations correspond to minima of the potential-energy hypersurface and all…

Disordered Systems and Neural Networks · Physics 2023-02-07 Stefano Mossa , Taras Bryk , Giancarlo Ruocco , Walter Schirmacher

We review recent developments in structural-dynamical phase transitions in trajectory space. An open question is how the dynamic facilitation theory of the glass transition may be reconciled with thermodynamic theories that posit a…

Statistical Mechanics · Physics 2020-08-04 C. Patrick Royall , Francesco Turci , Thomas Speck

A model system with fast and slow processes is introduced. After integrating out the fast ones, the considered dynamics of the slow variables is exactly solvable. In statics the system undergoes a Kauzmann transition to a glassy state. The…

Statistical Mechanics · Physics 2007-05-23 Theo M. Nieuwenhuizen

A two-dimensional lattice gas model is proposed. The ground state of this model with a fixed density is neither periodic nor quasi-periodic. It also depends on system size in an irregular manner. On the other hand, it is ordered in the…

Statistical Mechanics · Physics 2015-05-19 Shin-ichi Sasa

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

We use computer simulations to study the thermodynamic properties of a glass former in which a fraction $c$ of the particles has been permanently frozen. By thermodynamic integration, we determine the Kauzmann, or ideal glass transition,…

Soft Condensed Matter · Physics 2018-02-28 Misaki Ozawa , Walter Kob , Atsushi Ikeda , Kunimasa Miyazaki

A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasi-equilibrium at an effective temperature. It…

Statistical Mechanics · Physics 2009-10-31 Th. M. Nieuwenhuizen

Glass-forming liquids have been extensively studied in recent decades, but there is still no theory that fully describes these systems, and the diversity of treatments is in itself a barrier to understanding. Here we introduce a new simple…

Disordered Systems and Neural Networks · Physics 2011-03-28 Davide Cellai , Andrzej Z. Fima , Aonghus Lawlor , Kenneth A. Dawson

We introduce a lattice spin model where frustration is due to multibody interactions rather than quenched disorder in the Hamiltonian. The system has a crystalline ground state and below the melting temperature displays a dynamic behaviour…

Statistical Mechanics · Physics 2009-11-07 Andrea Cavagna , Irene Giardina , Tomas Grigera

The glass transition is considered as a phase transition in the system of topologically protected excitations in matter structure. The critical behavior of the system is considered both in statics and dynamics cases. It is shown in the…

Statistical Mechanics · Physics 2022-04-20 Mikail Vasin

We present results from molecular dynamics simulations exploring the supercooled dynamics of the Gaussian Core Model in the low- and intermediate-density regimes. In particular, we discuss the transition from the low-density…

Soft Condensed Matter · Physics 2024-03-18 Vittoria Sposini , Christos N. Likos , Manuel Camargo

Glass-to-glass and liquid-to-liquid phase transitions were observed many years ago in bulk and confined water with or without applied pressure. It is shown that they result from the competition of two-liquid phases separated by an enthalpy…

Disordered Systems and Neural Networks · Physics 2017-03-21 Robert F Tournier

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

Soft Condensed Matter · Physics 2015-08-20 M. Pica Ciamarra , Peter Sollich

The short- and long-time dynamics of model systems undergoing a glass transition with apparent inversion of Kauzmann and dynamical arrest glass transition lines is investigated. These models belong to the class of the spherical mean-field…

Disordered Systems and Neural Networks · Physics 2016-01-06 Corrado Rainone , Ulisse Ferrari , Matteo Paoluzzi , Luca Leuzzi

We present a three-dimensional lattice-gas model with trivial thermodynamics, but nontrivial dynamics. The model is characterized by each particle having its own random energy landscape. The equilibrium dynamics of the model were…

Soft Condensed Matter · Physics 2012-03-27 Ulf R. Pedersen , Tina Hecksher , Jeppe C. Dyre , Thomas B. Schrøder

We present a quantum statistical analysis of a microscopic mean-field model of structural glasses at low temperatures. The model can be thought of as arising from a random Born von Karman expansion of the full interaction potential. The…

Disordered Systems and Neural Networks · Physics 2015-05-14 J. van Baardewijk , R. Kuehn

We show in numerical simulations that a system of two coupled replicas of a binary mixture of hard spheres undergoes a phase transition in equilibrium at a density slightly smaller than the glass transition density for an unreplicated…

Disordered Systems and Neural Networks · Physics 2014-03-03 G. Parisi , B. Seoane

Whether the glass transition is caused by an underlying singularity or is a purely kinetic phenomenon is a significant outstanding question. Studying an atomistic glass former, we introduce a sampling method to access temperatures…

Statistical Mechanics · Physics 2017-09-20 Thomas Speck , C. Patrick Royall , Stephen R. Williams

Using the mapping of the Fokker-Planck description of classical stochastic dynamics onto a quantum Hamiltonian, we argue that a dynamical glass transition in the former must have a precise definition in terms of a quantum phase transition…

Statistical Mechanics · Physics 2010-08-10 Claudio Castelnovo , Claudio Chamon , David Sherrington

We show that a glass transition, signaled by a peak in the specific heat vs. temperature, can occur because a glassy system that shows no signs of aging progresses so slowly through the energy landscape that the time needed to obtain an…

Disordered Systems and Neural Networks · Physics 2007-05-23 Clare C. Yu , Herve M. Carruzzo