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Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

While the variational principle for excited-state energies leads to a route to obtaining excited-state densities from time-dependent density functional theory, relatively little attention has been paid to the quality of the resulting…

Chemical Physics · Physics 2025-09-12 Anna Baranova , Neepa T. Maitra

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

Based on static and dynamical density functional theory, a phase-field-crystal model is derived which involves both the translational density and the orientational degree of ordering as well as a local director field. The model exhibits…

Soft Condensed Matter · Physics 2015-05-19 Hartmut Löwen

The response of an infinite, periodic, insulating, solid to an infinitesimally small electric field is investigated in the framework of Density Functional Theory. We find that the applied perturbing potential is not a unique functional of…

mtrl-th · Physics 2016-09-07 X. Gonze , Ph. Ghosez , R. W. Godby , .

The dynamics of fluctuations is considered for electrons near a positive ion or for charges in a confining trap. The stationary nonuniform equilibrium densities are discussed and contrasted. The linear response function for small…

Statistical Mechanics · Physics 2015-05-13 Jeffrey Wrighton , James Dufty , Christian Henning , Michael Bonitz

We obtain the conductance of a system of electrons connected to leads, within time-dependent density-functional theory, using a direct relation between the conductance and the density response function. Corrections to the non-interacting…

Materials Science · Physics 2007-10-04 P. Bokes , J. Jung , R. W. Godby

The Liouville-Lanczos approach to linear-response time-dependent density-functional theory is generalized so as to encompass electron energy-loss and inelastic X-ray scattering spectroscopies in periodic solids. The computation of virtual…

Materials Science · Physics 2015-06-16 Iurii Timrov , Nathalie Vast , Ralph Gebauer , Stefano Baroni

Linear-response time-dependent density-functional theory (TDDFT) can describe excitonic features in the optical spectra of insulators and semiconductors, using exchange-correlation (xc) kernels behaving as $-1/k^{2}$ to leading order. We…

Materials Science · Physics 2021-08-18 Jiuyu Sun , Cheng-Wei Lee , Alina Kononov , André Schleife , Carsten A. Ullrich

Steady-state density functional theory, called i-DFT, is employed to compute spectral and transmission properties of general interacting nanoscale regions coupled to electronic reservoirs. Exchange-correlation functionals are constructed…

Mesoscale and Nanoscale Physics · Physics 2026-05-20 Nahual Sobrino , Stefan Kurth

We present a novel joint time-dependent density-functional theory for the description of solute-solvent systems in time-dependent external potentials. Starting with the exact quantum-mechanical action functional for both electrons and…

Materials Science · Physics 2012-02-16 Johannes Lischner , T. A. Arias

We show that the time dependent single electron, nuclear density matrix of an interacting electronic system coupled to nuclear degrees of freedom can be exactly reproduced by that of an electronic system with arbitrarily specified…

Materials Science · Physics 2009-02-07 Vinod Krishna

A density functional theory is developed for fermions in one dimension, interacting via a delta-function. Such systems provide a natural testing ground for questions of principle, as the local density approximation should work well for…

Other Condensed Matter · Physics 2007-05-23 R. J. Magyar , K. Burke

The continuum random-phase approximation is extended to the one applicable to deformed nuclei. We propose two different approaches. One is based on the use of the three dimensional (3D) Green's function and the other is the small-amplitude…

Nuclear Theory · Physics 2009-11-10 Takashi Nakatsukasa , Kazuhiro Yabana

Using the newly introduced theory of finite-temperature reduced density matrix functional theory, we apply the first-order approximation to the homogeneous electron gas. We consider both collinear spin states as well as symmetry broken…

Strongly Correlated Electrons · Physics 2015-03-20 Tim Baldsiefen , F. G. Eich , E. K. U. Gross

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari

We present a construction of non-equilibrium steady states in one-dimensional quantum critical systems carrying energy and charge fluxes. This construction is based on a scattering approach within a real-time hamiltonian reservoir…

Mathematical Physics · Physics 2015-07-28 Denis Bernard , Benjamin Doyon

We discuss how to connect the energy levels of two-particle systems trapped by a harmonic-oscillator force to scattering amplitudes, with nucleon-nucleon scattering phase shifts in uncoupled channels as the application. At the center of the…

Nuclear Theory · Physics 2021-10-13 Chenbo Li , Jiexin Yu , Rui Peng , Songlin Lyu , Bingwei Long

We develop a self-consistent first-principle method based on the density functional theory. Physical quantities, such as the density of states, Fermi energy and electron density are obtained using a time-dependent random state method…

Mesoscale and Nanoscale Physics · Physics 2023-02-15 Weiqing Zhou , Shengjun Yuan

Time-dependent density functional theory, proposed recently in the context of atomic diffusion and non-equilibrium processes in solids, is tested against Monte Carlo simulation. In order to assess the basic approximation of that theory, the…

Statistical Mechanics · Physics 2009-11-07 M. Kessler , W. Dieterich , H. L. Frisch , J. F. Gouyet , P. Maass