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An exchange energy functional is proposed and tested for obtaining a class of excited-state energies using density functional formalism. The functional is the excited-state counterpart of the local-density approximation functional for the…

Materials Science · Physics 2007-05-23 Prasanjit Samal , Manoj K. Harbola

The electron density $n(\rb,t)$, which is the central tool of time-dependent density functional theory, is presently considered to be derivable from a one-body time-dependent potential $V(\rb,t)$, via one-electron wave functions satisfying…

Quantum Physics · Physics 2009-04-28 Thomas A. Niehaus , Norman H. March

We introduce a new class of exchange-correlation potentials for a static and time-dependent Density Functional Theory of strongly correlated systems in 3D. The potentials are obtained via Dynamical Mean Field Theory and, for strong enough…

Strongly Correlated Electrons · Physics 2015-05-18 Daniel Karlsson , Antonio Privitera , Claudio Verdozzi

We study the Kohn-Sham scheme for the calculation of the steady state linear response to a harmonic perturbation that is turned on adiabatically. Although in general the exact time dependent exchange-correlation potential cannot be…

Other Condensed Matter · Physics 2009-11-13 Ryan Requist , Oleg Pankratov

The response of an extended periodic system to a homogeneous field (of wave-vector $q=0$) cannot be obtained from a $q=0$ time-dependent density functional theory (TDDFT) calculation, because the Runge-Gross theorem does not apply.…

Materials Science · Physics 2016-08-31 Neepa T. Maitra , Ivo Souza , Kieron Burke

We derive exact expressions for the local entanglement entropy E in the ground state of the one-dimensional Hubbard model at a quantum phase transition driven by a change in magnetic field h or chemical potential u. The leading divergences…

Strongly Correlated Electrons · Physics 2009-11-11 Daniel Larsson , Henrik Johannesson

A class of generalized non-minimal coupling theories is investigated, in search of scaling attractors able to provide an accelerated expansion at the present time. Solutions are found in the strong coupling regime and when the coupling…

Astrophysics · Physics 2008-11-26 Luca Amendola

According to time-dependent density functional theory, the exact exchange-correlation kernel f$_{xc}$(n, q, $\omega$) determines not only the ground-state energy but also the excited-state energies/lifetimes and time-dependent linear…

Chemical Physics · Physics 2020-07-01 Adrienn Ruzsinszky , Niraj K. Nepal , J. M. Pitarke , John P. Perdew

The combination of density functional theory with other approaches to the many-electron problem through the separation of the electron-electron interaction into a short-range and a long-range contribution is a promising method, which is…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to…

Statistical Mechanics · Physics 2008-08-20 James F. Lutsko

An explicit expression for the quadratic density-response function of a many-electron system is obtained in the framework of the time-dependent density-functional theory, in terms of the linear and quadratic density-response functions of…

Materials Science · Physics 2009-11-10 V. U. Nazarov , J. M. Pitarke , C. S. Kim , Y. Takada

We present a density functional scheme for calculating the pair density (PD) by means of the correlated wave function. This scheme is free from both of problems related to PD functional theory, i.e., (a) the need to constrain the…

Strongly Correlated Electrons · Physics 2015-06-25 Masahiko Higuchi , Katsuhiko Higuchi

Last year I talked at this meeting about a possible time dependence of the QCD coupling constant $\alpha_s$. This year I shall look into the problem once more, without fully repeating the arguments given last year. Astrophysical indications…

High Energy Physics - Phenomenology · Physics 2009-11-10 Harald Fritzsch

We show that as an electron transfers between closed-shell molecular fragments at large separation, the exact correlation potential of time-dependent density functional theory gradually develops a step and peak structure in the bonding…

Chemical Physics · Physics 2014-02-11 Johanna I. Fuks , Peter Elliott , Angel Rubio , Neepa T. Maitra

We simulate the dynamics of a single-electron source, modeled as a quantum dot with on-site Coulomb interaction and tunnel coupling to an adjacent lead, in time-dependent density functional theory. Based on this system, we develop a…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 Niklas Dittmann , Janine Splettstoesser , Nicole Helbig

Standard approximations for the exchange-correlation functional have been found to give big errors for the linearity condition of fractional charges, leading to delocalization error, and the constancy condition of fractional spins, leading…

Strongly Correlated Electrons · Physics 2009-11-13 Paula Mori-Sanchez , Aron J. Cohen , Weitao Yang

Time-dependent response and correlation functions are studied in random quantum systems composed of infinitely many parts without mutual interaction and defined with statistically independent random matrices. The latter are taken within the…

Statistical Mechanics · Physics 2025-12-17 Sudhir Ranjan Jain , Pierre Gaspard

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

Chemical Physics · Physics 2022-09-12 Julien Toulouse

We present a variational formulation of Time-Dependent Density Functional Theory similar to the constrained-search variational formulation of ground-state density-function theory. The formulation is applied to justify the time-dependent…

Other Condensed Matter · Physics 2012-10-26 Jérôme Daligault

The ability to tune quantum tunneling is key for achieving selectivity in manipulation of individual particles in quantum technology applications. In this work we count electron escape events out of a time-dependent confinement potential,…

Mesoscale and Nanoscale Physics · Physics 2026-02-10 Austris Akmentinsh , David Reifert , Thomas Weimann , Klaus Pierz , Vyacheslavs Kashcheyevs , Niels Ubbelohde
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