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We investigated the influence of short- and long-range correlated quenched disorder introduced into the medium on the process of adsorption of long-flexible polymer chains on a wall by using the field theoretical approach in $d=4-\epsilon$…

Disordered Systems and Neural Networks · Physics 2007-05-23 Z. Usatenko , A. Ciach

Hydrodynamic slip of a liquid at a solid surface represents a fundamental phenomenon in fluid dynamics that governs liquid transport at small scales. For polymeric liquids, de Gennes predicted that the Navier boundary condition together…

We study the friction between a flat solid surface where polymer chains have been end-grafted and a cross-linked elastomer at low sliding velocity. The contribution of isolated grafted chains' penetration in the sliding elastomer has been…

Soft Condensed Matter · Physics 2015-06-24 Thomas Vilmin , Elie Raphael

The thermally assisted detachment of a self-avoiding polymer chain from an adhesive surface by an external force applied to one of the chain ends is investigated. We perform our study in the "fixed height" statistical ensemble where one…

Soft Condensed Matter · Physics 2009-08-13 S. Bhattacharya , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

A phase diagram for a surface interacting long flexible partially directed polymer chain in a two-dimensional poor solvent where the possibility of collapse in the bulk exists is determined using exact enumeration method. We used a model of…

Statistical Mechanics · Physics 2020-12-29 Pramod K Mishra , Yashwant Singh

We consider a model of self-avoiding walk on a lattice with on-site repulsion and an attraction for every vertex of the walk visited on the surface to study force-induced desorption of a linear polymer chain adsorbed on an attractive…

Statistical Mechanics · Physics 2007-05-23 P. K. Mishra , Sanjay Kumar , Yashwant Singh

The adsorption of a single ideal polymer chain on energetically heterogeneous and rough surfaces is investigated using a variational procedure introduced by Garel and Orland (Phys. Rev. B 55 (1997), 226). The mean polymer size is calculated…

Statistical Mechanics · Physics 2009-10-31 Gregor Huber , Thomas A. Vilgis

We consider forces acting on objects immersed in, or attached to, long fluctuating polymers. The confinement of the polymer by the obstacles results in polymer-mediated forces that can be repulsive (due to loss of entropy) or attractive (if…

Statistical Mechanics · Physics 2017-08-28 Yacov Kantor , Mehran Kardar

The shape of biological shells, such as cell nuclei, membranes, and vesicles, often deviates from a perfect sphere due to an interplay of complex interactions with a myriad of molecular structures. In particular, semiflexible biopolymers…

Soft Condensed Matter · Physics 2025-09-05 Hadiya Abdul Hameed , Jaroslaw Paturej , Aykut Erbas

Using molecular dynamic simulation, we study the stretching of an adsorbed homopolymer in a poor solvent with one end held at a distance $z_e$ from the substrate. We measure the vertical force $f$ on the end of the chain as a function of…

Soft Condensed Matter · Physics 2009-11-10 Franck Celestini , Thoma Frisch , Xabier Oyharcabal

The static friction between crystalline surfaces separated by a molecularly thin layer of adsorbed molecules is calculated using molecular dynamics simulations. These molecules naturally lead to a finite static friction that is consistent…

Materials Science · Physics 2009-11-07 Gang He , Mark O. Robbins

A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate…

Soft Condensed Matter · Physics 2009-11-13 Jutta Luettmer-Strathmann , Federica Rampf , Wolfgang Paul , Kurt Binder

The behaviour of rod-coil diblock copolymers close to a surface is discussed by using extended scaling methods. The copolymers are immersed in selective solvent such that the rods are likely to aggregate to gain energy. The rods are assumed…

Soft Condensed Matter · Physics 2009-11-11 C. Nowak , T. A. Vilgis

The molecular mechanism of slip at the interface between polymer melts and weakly attractive smooth surfaces is investigated using molecular dynamics simulations. In agreement with our previous studies on slip flow of shear-thinning fluids,…

Soft Condensed Matter · Physics 2010-11-11 Nikolai V. Priezjev

An applied tension force changes the equilibrium conformations of a polymer chain tethered to a planar substrate and thus affects the adsorption transition as well as the coil-globule and crystallization transitions. Conversely, solvent…

Soft Condensed Matter · Physics 2015-06-22 Jutta Luettmer-Strathmann , Kurt Binder

We investigate the folding and forced-unbinding transitions of adsorbed semiflexible polymer chains using theory and simulations. These processes describe biologically relevant phenomena that include adhesive interactions between proteins…

Soft Condensed Matter · Physics 2007-05-23 V. Barsegov , D. Thirumalai

The behavior of a polyelectrolyte adsorbed on a charged substrate of high-dielectric constant is studied by both Monte-Carlo simulation and analytical methods. It is found that in a low enough ionic strength medium, the adsorption…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

The mechanical response of a wet granular layer to imposed shear is studied experimentally at low applied normal stress. The granular material is immersed in water and the shear is applied by sliding a plate resting on the upper surface of…

Condensed Matter · Physics 2009-10-31 J. -C. Geminard , W. Losert , J. P. Gollub

Friction experiments were conducted on hydrogel thin films sliding against a rigid sphere in a low velocity regime where molecular adsorption at the sliding interface sets the friction force, through a dissipative…

Soft Condensed Matter · Physics 2024-12-10 Lola Ciapa , Yvette Tran , Christian Frétigny , Antoine Chateauminois , Emilie Verneuil

We formulate and characterize a model to describe the dynamics of semiflexible polymers in the presence of activity due to motor proteins attached irreversibly to a substrate, and a transverse pulling force acting on one end of the…

Biological Physics · Physics 2016-02-12 Abhishek Chaudhuri , Debasish Chaudhuri