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We have fabricated a variety of novel molecular tunnel junctions based on self-assembled-monolayers (SAM) of two-component solid-state mixtures of molecular wires (1,4 methane benzene-dithiol; Me-BDT with two thiol anchoring groups), and…

Materials Science · Physics 2009-11-11 Vladimir Burtman , Alexander S. Ndobe , Valy Z. Vardeny

We present a theoretical study of spin-dependent transport through molecular wires bridging ferromagnetic metal nanocontacts. We extend to magnetic systems a recently proposed model that provides a em quantitative explanation of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Eldon Emberly , George Kirczenow

We present measurements of magnetic tunnel junctions made using a self-assembled-monolayer molecular barrier. Ni/octanethiol/Ni samples were fabricated in a nanopore geometry. The devices exhibit significant changes in resistance as the…

Mesoscale and Nanoscale Physics · Physics 2010-10-05 J. R. Petta , S. K. Slater , D. C. Ralph

We report on electronic transport calculations for self-assembled mono-layers (SAM) of 1,4-phenylene diisocyanide on Au(111) contacts. Experimentally one observes more structure (i.e peaks) within the measured conductance curve for this…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Robert Dahlke , Ulrich Schollwoeck

We present a theoretical analysis aimed at understanding electrical conduction in molecular tunnel junctions. We focus on discussing the validity of coherent versus incoherent theoretical formulations for single-level tunneling to explain…

Mesoscale and Nanoscale Physics · Physics 2016-06-06 Alvar R. Garrigues , Li Yuan , Lejia Wang , Eduardo R. Mucciolo , Damien Thompson , Enrique del Barco , Christian A. Nijhuis

We study the electronic and transport properties of two novel molecular wires made of atomic chains of carbon atoms (polyynes) capped with either, benzene-thiols or pyridines. While both molecules are structurally similar, the electrical…

Mesoscale and Nanoscale Physics · Physics 2008-10-14 V. M. García-Suárez , C. J. Lambert

We use first principles density functional theory to calculate the electronic structure of the phenylthiolate (S-C$_6$H$_5$) self-assembled monolayer (SAM) on Cu(111) and Au(111) substrates. We find significant lateral dispersion of the SAM…

Materials Science · Physics 2009-11-10 Vasili Perebeinos , Marshall Newton

Electrically stimulated switching of a charge injection barrier at the interface between an organic semiconductor and an electrode modified with a disordered monolayer (DM) is studied by using various benzenethiol derivatives as DM…

Materials Science · Physics 2016-08-04 Ryo Nouchi , Takaaki Tanimoto

In this paper, equilibrium molecular dynamics simulations were performed on Au-SAM (self-assembly monolayer)-Au junctions. The SAM consisted of alkanedithiol molecules. The out-of-plane (z-direction) thermal conductance and in-plane (x- and…

Mesoscale and Nanoscale Physics · Physics 2011-11-22 Tengfei Luo , John R. Lloyd

The realization of self-assembled molecular-electronic films, whose room-temperature transport properties are controlled by quantum interference (QI), is an essential step in the scale-up QI effects from single molecules to parallel arrays…

Two-dimensional (2D) materials are a new class of materials with interesting physical properties and applications ranging from nanoelectronics to sensing and photonics. In addition to graphene, the most studied 2D material, monolayers of…

Materials Science · Physics 2022-04-12 Lianhua Zhang , Jian Chen , Fei Liu , Zhengyang Du , Yilun Jiang , Min Han

We report an investigation of electron conduction in oligophenyl based double barrier molecular device. We have carried out analytical calculations and numerical simulations on isolated molecules, consisting of aromatic "pi" conjugated…

Materials Science · Physics 2010-07-14 Aranya B Bhattacherjee , Suman Dudeja

We present a simple and reliable method for making electrical contacts to small organic molecules with thiol endgroups. Nanometer-scale gaps between metallic electrodes have been fabricated by passing a large current through a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Subhasis Ghosh , Henny Halimun , Jaewon Choi , Saurabh Lodha , David Janes

Motivated by recent experiments, we present here a systematic ab-initio study of the length dependence of the thermal conductance of single-molecule junctions. We make use of a combination of density functional theory with non-equilibrium…

Mesoscale and Nanoscale Physics · Physics 2016-11-30 J. C. Klöckner , M. Bürkle , J. C. Cuevas , F. Pauly

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

Materials Science · Physics 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

Monolayer semiconductors of group-VA elements (As, Sb, Bi) with graphenelike buckled structure offer a potential to achieve nanoscale electronic, optoelectronic and thermoelectric devices. Motivated by recently-fabricated Sb monolayer, we…

Materials Science · Physics 2017-02-10 Dong-Chen Zhang , Ai-Xia Zhang , San-Dong Guo

The surface a thin-film is attached to and the surrounding monolayer causes geometrical confinement of a interrogated molecule; we look at the base case of a SC$_{18}H_{37}$ in a SC$_{18}H_{37}$ monolayer on Au[111]. Normal mode analysis…

Chemical Physics · Physics 2017-06-29 Ella M Gale

To quantify charge transport through molecular junctions fabricated using the conducting probe atomic force microscopy (CP-AFM) platform, information on the number of molecules $N$ per junction is absolutely necessary. $N$ can be currently…

Mesoscale and Nanoscale Physics · Physics 2021-03-30 Ioan Bâldea

We report a combined experimental (C-AFM and SThM) and theoretical (DFT) study of the thermoelectric properties of molecular junctions made of self-assembled monolayers on Au of thiolated benzothieno-benzothiophene (BTBT) and alkylated BTBT…

Mesoscale and Nanoscale Physics · Physics 2024-11-13 Sergio Gonzalez-Casal , Rémy Jouclas , Imane Arbouch , Yves Geerts , Colin van Dyck , Jérôme Cornil , Dominique Vuillaume

The study of electron transport through single molecules is essential to the development of molecular electronics. Indeed, trends in electronic conductance through organic nanowires have emerged with the increasing reliability of electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-24 Jordan R. Quinn , Frank W. Foss , Latha Venkataraman , Mark S. Hybertsen , Ronald Breslow
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