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We apply a modified mean-field density functional theory to determine the phase behavior of Stockmayer fluids in slitlike pores formed by two walls with identical substrate potentials. Based on the Carnahan-Starling equation of state, a…

Soft Condensed Matter · Physics 2015-05-13 I. Szalai , S. Dietrich

Using classical density functional theory (DFT) in a modified mean-field approximation we investigate the fluid phase behavior of quasi-two dimensional dipolar fluids confined to a plane. The particles carry three-dimensional dipole moments…

Statistical Mechanics · Physics 2013-06-18 R. Geiger , S. H. Klapp

We have investigated the phase behaviour of a symmetrical binary fluid mixture for the situation where the chemical potentials $\mu_1$ and $\mu_2$ of the two species differ. Attention is focused on the set of interparticle interaction…

Statistical Mechanics · Physics 2015-06-25 Juergen Koefinger , Nigel B. Wilding , Gerhard Kahl

Based on density-functional theory we analyze the full phase diagram, the occurrence of long-ranged orientational order, and the structural properties of dipolar fluids. As a model system we consider the Stockmayer fluid that consists of…

Soft Condensed Matter · Physics 2009-09-25 B. Groh , S. Dietrich

Integral equation theory calculations within the mean spherical approximation (MSA) and grand canonical Monte Carlo (MC) simulations are employed to study the phase behaviour of a symmetrical binary fluid mixture in the presence of a field…

Statistical Mechanics · Physics 2009-11-11 Juergen Koefinger , Gerhard Kahl , Nigel B. Wilding

We investigate fluids of dipolar hard particles by a certain variant of density-functional theory. The proper treatment of the long range of the dipolar interactions yields a contribution to the free energy which favors ferromagnetic order.…

Condensed Matter · Physics 2009-10-28 B. Groh , S. Dietrich

We investigate the crystal structure of classical systems of spherical particles with an embedded point dipole at T=0. The ferroelectric ground state energy is calculated using generalizations of the Ewald summation technique. Due to the…

Soft Condensed Matter · Physics 2009-10-31 B. Groh , S. Dietrich

We investigate a three component fermion mixture in the presence of weak attractive interactions. We use a combination of the equation of motion and the Gaussian variational mean-field approaches, which both allow for simultaneous…

Quantum Gases · Physics 2016-12-13 M. Kanasz-Nagy , G. Zarand

The liquid-gas phase diagram for polydisperse dipolar hard-sphere fluid with polydispersity in the hard-sphere size and dipolar moment is calculated using extension of the recently proposed thermodynamic perturbation theory for central…

Soft Condensed Matter · Physics 2012-07-16 Yu. V. Kalyuzhnyi , S. Hlushak , P. T. Cummings

Phase diagrams of binary mixtures of oppositely charged colloids are calculated theoretically. The proposed mean-field-like formalism interpolates between the limits of a hard-sphere system at high temperatures and the colloidal crystals…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Rene van Roij , Marjolein Dijkstra

We investigate the properties of the liquid-vapor interface in the shifted Stockmayer fluid using molecular dynamics simulations in the canonical ensemble. We study the role of the dipole moment strength and the degree of asymmmetry on…

Soft Condensed Matter · Physics 2025-09-09 Samuel Varner , Pierre J. Walker , Ananya Venkatachalam , Bilin Zhuang , Zhen-Gang Wang

Phase behaviour of the Stockmayer fluid is studied with a method similar to the Monte-Carlo annealing scheme. We introduce a novel order parameter which is sensitive to the local co-orientation of the dipoles of particles in the fluid. We…

Soft Condensed Matter · Physics 2015-06-04 Veniamin Blinov

We systematically study ground state properties of fermionic dipolar gases in a planar array of one-dimensional potential tubes for an arbitrary orientation of dipole moments. Using the Luttinger liquid theory with the generalized…

Quantum Gases · Physics 2009-12-17 Yi-Ping Huang , Daw-Wei Wang

The microscopic approach to the description of the phase behaviour and critical phenomena in binary fluid mixtures is proposed. It is based on the method of collective variables with a reference system. The physical nature of the order…

Condensed Matter · Physics 2009-10-31 O. V. Patsahan

We deduce the mixing-demixing phase diagram for binary liquid mixtures in an electric field for various electrode geometries and arbitrary constitutive relation for the dielectric constant. By focusing on the behavior of the liquid-liquid…

Soft Condensed Matter · Physics 2013-07-18 Jennifer Galanis , Yoav Tsori

Using Monte-Carlo simulation and mean field calculations, we study the liquid-vapour phase diagram of a square well binary fluid mixture as a function of a parameter $\delta$ measuring the relative strength of interactions between particles…

Statistical Mechanics · Physics 2009-10-31 N. B. Wilding , F. Schmid , P. Nieleba

We examine two aspects of Stockmayer fluids which consists of point dipoles that additionally interact via an attractive Lennard-Jones potential. We perform Monte Carlo simulations to examine the effect of an applied field on the liquid-gas…

mtrl-th · Physics 2016-09-07 Mark J. Stevens , Gary S. Grest

We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations…

Statistical Mechanics · Physics 2015-03-19 Richard L. C. Vink , A. J. Archer

Compared to pure fluids, binary mixtures display a very diverse phase behavior, which depends sensitively on the parameters of the microscopic potential. Here we investigate the phase diagrams of simple model mixtures by use of a…

Soft Condensed Matter · Physics 2009-11-07 A. Parola , D. Pini , L. Reatto , M. Tau

The liquid-to-ordered phase transition in a bilayer system of fermions is studied within the context of a recently proposed density-functional theory [Phys. Rev. A {\bf 92}, 023614 (2015)]. In each two-dimensional layer, the fermions…

Quantum Gases · Physics 2016-06-01 B. P. van Zyl , W. Ferguson
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