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Related papers: Infrared Conductivity and Charge Ordering in NaCoO…

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We report infrared spectra of a Na$_{0.5}$CoO$_2$ single crystal which exhibits a sharp metal-insulator transition near 50 K due to the formation of charge ordering. In comparison with x=0.7 and 0.85 compounds, we found that the spectral…

Strongly Correlated Electrons · Physics 2009-11-10 N. L. Wang , Dong Wu , G. Li , X. H. Chen , C. H. Wang , X. G. Luo

The optical conductivity of single crystals of Na_xCoO_2 for $x$ = 0.57 is first reported between 295 and 30 K. In the far infrared, an "anomalous Drude" analysis leads to a carrier effective mass of 5 electron masses. That this high value…

Superconductivity · Physics 2009-11-10 S. Lupi , M. Ortolani , P. Calvani

The reflectivity $R (\omega)$ of both the $ab$ plane and the c axis of two single crystals of La$_{1.875}$Ba$_{0.125-y}$Sr$_{y}$CuO$_4$ has been measured down to 5 cm$^{-1}$, using coherent synchrotron radiation below 30 cm$^{-1}$. For $y$…

Superconductivity · Physics 2009-11-11 M. Ortolani , P. Calvani , S. Lupi , U. Schade , A. Perla , M. Fujita , K. Yamada

We present measurements of the optical spectra on Na$_{0.7}$CoO$_2$ single crystals. The optical conductivity shows two broad interband transition peaks at 1.6 eV and 3.2 eV, and a weak midinfrared peak at 0.4 eV. The intraband response of…

Superconductivity · Physics 2009-11-10 N. L. Wang , P. Zheng , D. Wu , Y. C. Ma , T. Xiang , R. Y. Jin , D. Mandrus

The structure of Na0.5CoO2, the low temperature insulator that separates the magnetic and superconducting regions in the NaxCoO2.yH2O phase diagram, is studied by high resolution powder neutron diffraction at temperatures between 10 and 300…

Strongly Correlated Electrons · Physics 2007-05-23 A. J. Williams , J. P. Attfield , M. L. Foo , R. J. Cava

We have utilized neutron powder diffraction to probe the crystal structure of layered Na$_{x}$CoO$_{2}$ near the half doping composition of $x=$0.46 over the temperature range of 2 to 600K. Our measurements show evidence of a dynamic…

Strongly Correlated Electrons · Physics 2008-06-16 D. N. Argyriou , O. Prokhnenko , K. Kiefer , C. J. Milne

The ordering of Na ions in Na$_x$CoO$_2$ is investigated systematically by combining detailed density functional theory (DFT) studies with model calculations. Various ground state ordering patterns are identified, and they are in excellent…

Materials Science · Physics 2009-11-11 Peihong Zhang , Rodrigo B. Capaz , Marvin L. Cohen , Steven G. Louie

The optical properties of the charge-ordering ($CO$) phase of the one-dimensional (1D) half-filled spinless Holstein model are derived at zero temperature within a well-known variational approach improved including second-order lattice…

Strongly Correlated Electrons · Physics 2009-11-10 C. A. Perroni , V. Cataudella , G. De Filippis , G. Iadonisi , V. Marigliano Ramaglia , F. Ventriglia

We investigate the temperature dependent optical properties of NaV2O5, in the energy range 4meV-4eV. The symmetry of the system is discussed on the basis of infrared phonon spectra. By analyzing the optically allowed phonons at temperatures…

Strongly Correlated Electrons · Physics 2009-10-31 A. Damascelli , C. Presura , D. van der Marel , J. Jegoudez , A. Revcolevschi

We present infrared ab-plane conductivity data for the layered cobaltate Na$_x$CoO$_2$ at three different doping levels ($x=0.25, 0.50$, and 0.75). The Drude weight increases monotonically with hole doping, $1-x$. At the lowest hole doping…

Superconductivity · Physics 2009-11-10 J. Hwang , J. Yang , T. Timusk , F. C. Chou

We present a detailed analysis of light scattering experiments performed on the quarter-filled spin ladder compound $\alpha^\prime$-NaV$_{2}$O$_{5}$ for the temperature range 5 K$\le$T$\le$300 K. This system undergoes a phase transition…

Strongly Correlated Electrons · Physics 2009-10-31 M. Fischer , P. Lemmens , G. Els , G. Güntherodt , E. Sherman , E. Morre , C. Geibel , F. Steglich

We report the in-plane optical measurements on Na$_x$CoO$_2$ with 0.18$\leq$x$\leq$0.92. The crystal growth and characterization were described in detail. The spectral weight increases monotonically with decreasing x. For sample with the…

Superconductivity · Physics 2009-11-11 D. Wu , J. L. Luo , N. L. Wang

Using spectral ellipsometry, we have measured the dielectric function of a Na$_{0.82(2)}$CoO$_2$ crystal that exhibits bulk antiferromagnetism with T$_{N}$=19.8 K. We identify two prominent transitions as a function of temperature. The…

Strongly Correlated Electrons · Physics 2009-11-10 C. Bernhard , A. V. Boris , N. N. Kovaleva , G. Khaliullin , A. Pimenov , L. Yu , D. P. Chen , C. T. Lin , B. Keimer

We present angular dependent EPR measurements in NaV2O5 at X-band frequencies in the temperature range 4.2 K < T < 670 K. A detailed analysis in terms of the antisymmetric Dzyaloshinski-Moriya and the anisotropic exchange interactions…

Strongly Correlated Electrons · Physics 2009-10-31 M. Lohmann , H. -A. Krug von Nidda , M. V. Eremin , A. Loidl , G. Obermeier , S. Horn

The strength and effect of Coulomb correlations in the (superconducting when hydrated) x~1/3 and ``enhanced'' x~2/3 regimes of Na(x)CoO2 are evaluated using the correlated band theory LDA+U method. Our results, neglecting quantum…

Strongly Correlated Electrons · Physics 2009-11-10 K. -W. Lee , J. Kunes , W. E. Pickett

The CoO$_{2}$ layers in sodium-cobaltates Na$_{x}$CoO$_{2}$ may be viewed as a spin $S=1/2$ triangular-lattice doped with charge carriers. The underlying physics of the cobaltates is very similar to that of the high $T_{c}$ cuprates. We…

Strongly Correlated Electrons · Physics 2008-10-03 F. L. Ning , S. M. Golin , K. Ahilan , T. Imai , G. J. Shu , F. C. Chou

The strength and effect of Coulomb correlations in the (superconducting when hydrated) x~1/3 regime of Na(x)CoO(2) have been evaluated using the correlated band theory LDA+U method. Our results, neglecting quantum fluctuations, are: (1)…

Strongly Correlated Electrons · Physics 2007-05-23 J. Kunes , K. -W. Lee , W. E. Pickett

The magnetic and transport properties are systematically studied on the single crystal $Na_{0.55}CoO_2$ with charge ordering and divergency in resistivity below 50 K. A long-range ferromagnetic ordering is observed in susceptibility below…

Strongly Correlated Electrons · Physics 2009-11-11 C. H. Wang , X. H. Chen , T. Wu , X. G. Luo , G. Y. Wang , J. L. Luo

The in-plane optical conductivity of seven La(2-x)Sr(x)CuO(4) single crystals with x between 0 and 0.15 has been studied from 30 to 295 K. All doped samples exhibit strong peaks in the far-infrared, which closely resemble those observed in…

Charge ordering behavior is observed in the crystal prepared through the immersion of the $Na_{0.41}CoO_2$ crystal in distilled water. Discovery of the charge ordering in the crystal with Na content less than 0.5 indicates that the…

Materials Science · Physics 2016-08-31 C. H. Wang , H. T. Zhang , X. X. Lu , G. Wu , J. Q. Li , X. H. Chen
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