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Our object is to formulate and analyze a physically plausible and mathematically sound model to better understand the phenomenon of clumping in colloid dispersions. Our model is stochastic but rigorously derived from a deterministic setup…

Materials Science · Physics 2009-09-29 Peter. Kotelenez , Marshall J. Leitman , J. Adin Mann

We present a density functional based closure of the pair Smoluchowski equation for Brownian particles under shear flow. Given an equilibrium free energy functional as input the theory provides first-principles predictions for the…

Soft Condensed Matter · Physics 2013-06-04 J. Reinhardt , F. Weysser , J. M. Brader

We present a diagrammatic formulation of a theory for the time dependence of density fluctuations in equilibrium systems of interacting Brownian particles. To facilitate derivation of the diagrammatic expansion we introduce a basis that…

Soft Condensed Matter · Physics 2009-11-13 Grzegorz Szamel

Using Brownian dynamics (BD) simulations and an analytical approach we investigate the shear-induced, nonequilibrium dynamics of dense colloidal suspensions confined to a narrow slit-pore. Focusing on situations where the colloids arrange…

Soft Condensed Matter · Physics 2017-01-04 Sascha Gerloff , Sabine H. L. Klapp

Computing analytically the $n$-point density correlations in systems of interacting particles is a long-standing problem of statistical physics, with a broad range of applications, from the interpretation of scattering experiments in simple…

Statistical Mechanics · Physics 2025-07-01 Louison Le Bon , Antoine Carof , Pierre Illien

We present a theory for the steady-state dynamics of a two-dimensional system of spherically symmetric active Brownian particles. The derivation of the theory consists of two steps. First, we integrate out the self-propulsions and obtain a…

Soft Condensed Matter · Physics 2019-05-01 Grzegorz Szamel

Equations of motion for the microscopic number density $\hat{\rho}({\bf x},t)$ and the momentum density $\hat{\bf g}({\bf x},t)$ of a fluid have been obtained in the past from the corresponding Langevin equations representing the dynamics…

Statistical Mechanics · Physics 2015-06-15 Shankar P. Das , Akira Yoshimori

A relation between equilibrium, steady-state, and waiting-time dependent dynamical two-time correlation functions in dense glass-forming liquids subject to homogeneous steady shear flow is discussed. The systems under study show pronounced…

Soft Condensed Matter · Physics 2015-05-18 Matthias Krüger , Fabian Weysser , Thomas Voigtmann

Characterising the statistical properties of classical interacting particle systems is a long-standing question. For Brownian particles the microscopic density obeys a stochastic evolution equation, known as the Dean--Kawasaki equation.…

Statistical Mechanics · Physics 2025-09-30 Aurélien Grabsch , Davide Venturelli , Olivier Bénichou

We discuss the stochastic thermodynamics of systems that are described by a time-dependent density field, for example simple liquids and colloidal suspensions. For a time-dependent change of external parameters, we show that the Jarzynski…

Statistical Mechanics · Physics 2014-03-18 T. Leonard , B. Lander , U. Seifert , T. Speck

We discuss the nonlinear rheology of dense colloidal dispersions at the glass transition. A first principles approach starting with interacting Brownian particles in given arbitrary homogeneous (incompressible) flow neglecting hydrodynamic…

Soft Condensed Matter · Physics 2009-11-13 D. Hajnal , O. Henrich , J. J. Crassous , M. Siebenbuerger , M. Drechsler , M. Ballauff , M. Fuchs

A simple theoretical approach is used to investigate active colloids at the free interface and near repulsive substrates. We employ dynamical density functional theory to determine the steady-state density profiles in an effective…

Soft Condensed Matter · Physics 2017-02-03 René Wittmann , Joseph M. Brader

The traction on the surface of a spherical active colloid in a thermally fluctuating Stokesian fluid contains passive, active, and Brownian contributions. Here we derive these three parts systematically, by "projecting out" the fluid using…

Soft Condensed Matter · Physics 2017-09-11 Rajesh Singh , R. Adhikari

We consider a charged Brownian gas under the influence of external and non uniform electric, magnetic and mechanical fields, immersed in a non uniform bath temperature. With the collision time as an expansion parameter, we study the…

Statistical Mechanics · Physics 2013-08-01 R. E. Lagos , Tania P. Simões

Dynamic particle-scale numerical simulations are used to show that the shear thickening observed in dense colloidal, or Brownian, suspensions is of a similar nature to that observed in non-colloidal suspensions, i.e., a stress-induced…

Soft Condensed Matter · Physics 2015-12-04 Romain Mari , Ryohei Seto , Jeffrey F. Morris , Morton M. Denn

We develop an exact Green-Kubo formula relating nonequilibrium averages in systems of interacting active Brownian particles to equilibrium time-correlation functions. The method is applied to calculate the density-dependent average swim…

Soft Condensed Matter · Physics 2016-11-23 A. Sharma , J. M. Brader

The nonlinear rheological properties of dense suspensions are discussed within simplified models, suggested by a recent first principles approach to the model of Brownian particles in a constant-velocity-gradient solvent flow. Shear…

Soft Condensed Matter · Physics 2015-06-24 Matthias Fuchs , Michael E. Cates

We present a comprehensive study of the linear response of interacting underdamped Brownian particles to simple shear flow. We collect six different routes for computing the response, two of which are based on the symmetry of the considered…

Statistical Mechanics · Physics 2021-09-01 Kiryl Asheichyk , Matthias Fuchs , Matthias Krüger

Using Brownian dynamics simulations, we investigate the effects of confinement, adsorption on surfaces and ion-ion interactions on the response of confined electrolyte solutions to oscillating electric fields in the direction perpendicular…

Chemical Physics · Physics 2023-03-10 Thê Hoang Ngoc Minh , Gabriel Stoltz , Benjamin Rotenberg

We investigate the relation between mobility and diffusivity for Brownian particles under steady shear near the glass transition, using mode coupling approximations. For the two directions perpendicular to the shear direction, the particle…

Soft Condensed Matter · Physics 2009-11-10 Matthias Krüger , Matthias Fuchs