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Related papers: Polymer adsorption onto random planar surfaces: In…

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We study the response of an adsorbed monolayer on a disordered substrate under a driving force using Brownian molecular-dynamics simulation. We find that the sharp longitudinal and transverse depinning transitions with hysteresis still…

Materials Science · Physics 2009-11-10 Enzo Granato , S. C. Ying

We investigate adsorption of a gas on the flat surface of a solid deformable adsorbent taking into account thermal fluctuations and analyze in detail the effect of thermal fluctuations on the adsorbent deformation in adsorption. The…

Materials Science · Physics 2017-02-13 A. S. Usenko

Hybrid molecular dynamics/Monte Carlo simulations used to study melts of unentangled, thermoreversibly associating supramolecular polymers. In this first of a series of papers, we describe and validate a model that is effective in…

Soft Condensed Matter · Physics 2015-05-13 Robert S. Hoy , Glenn H. Fredrickson

The adsorption of a collagen fragment on both a hydrophobic, hydrogen-terminated and a hydrophilic, natively oxidised Si surface is investigated using all-atom molecular dynamics. While favourable direct protein-surface interactions via…

Soft Condensed Matter · Physics 2019-03-27 Daniel J. Cole , Mike C. Payne , Lucio Colombi Ciacchi

Experimental methods allow the shape and chemical composition of solid surfaces to be controlled at a mesoscopic level. Exposing such structured substrates to a gas close to coexistence with its liquid can produce quite distinct adsorption…

Condensed Matter · Physics 2009-10-31 C. Rascon , A. O. Parry

Surface energy is fundamental in controlling surface properties and surface-driven processes like heterogeneous catalysis, as adsorption energy is. It is thus crucial to establish an effective scheme to determine surface energy and its…

Materials Science · Physics 2020-09-22 Bo Li , Xin Li , Wang Gao , Qing Jiang

Fluids with spatial density variations of single or mixed molecules play a key role in biophysics, soft matter and materials science. The fluid structures usually form via spinodal decomposition or nucleation following an instantaneous…

Chemical Physics · Physics 2018-01-24 Charley Schaefer

We study surface effects in amorphous polymer systems by means of computer simulation. In the framework of molecular dynamics, we present two different methods to prepare such surfaces. {\em Free} surfaces are stabilized solely by…

Condensed Matter · Physics 2009-10-28 Thorsten Hapke , Andreas Linke , Gerald Paetzold , Dieter W. Heermann

We present results of a new model of sequential adsorption in which the adsorbing particles are correlated with the particles attached to the substrate. The strength of the correlations is measured by a tunable parameter $\sigma$. The model…

Statistical Mechanics · Physics 2009-11-07 R. Pastor-Satorras , J. M. Rubi

Soft membranes are commonly employed in shape-morphing applications, where the material is programmed to achieve a target shape upon activation by an external trigger, and as coating layers that alter the surface characteristics of bulk…

Soft Condensed Matter · Physics 2016-02-05 Alessandro Lucantonio , Luciano Teresi , Antonio DeSimone

Self-assembly of polypeptides into fibrillar structures can be initiated by planar surfaces that interact favorably with certain residues. Using a coarse grained model, we systematically studied the folding and adsorption behavior of a…

Soft Condensed Matter · Physics 2017-10-12 Ran Ni , J. Mieke Kleijn , Sanne Abeln , Martien A. Cohen Stuart , Peter G. Bolhuis

Monte Carlo simulations using an explicit solvent model indicate a new pathway for translocation of a polymer chain through a lipid bilayer. We consider a polymer chain composed of repeat units with a given hydrophobicity and a…

Soft Condensed Matter · Physics 2012-05-22 Jens-Uwe Sommer , Marco Werner , Vladimir A. Baulin

We show that it is possible to derive the stationary coverage of an adsorption-desorption process of dimers with diffusional relaxation with a very simple ansatz for the stationary distribution of the process supplemented by a hypothesis of…

Statistical Mechanics · Physics 2011-05-24 J. Ricardo G. de Mendonça , Mário J. de Oliveira

A simple multiscale approach to the diffusion-driven adsorption from a solution to a solid surface is presented. The model combines two important features of the adsorption process: (i) the kinetics of the chemical reaction between…

Chemical Physics · Physics 2009-11-13 Radek Erban , S. Jonathan Chapman

DNA adsorption on solid or liquid surfaces is a topic of broad fundamental and applied interest. Here we study by x-ray reflectivity the adsorption of monodisperse double-stranded DNA molecules a positively-charged surface, obtained through…

Soft Condensed Matter · Physics 2008-09-29 Carine Douarche , Robert Cortès , Steven J. Roser , Jean-Louis Sikorav , Alan Braslau

In this work, protein-surface interactions were probed in terms of adsorption and desorption of a model protein, bovine serum albumin, on a low-fouling surface with single-molecule localization microscopy. Single-molecule experiments enable…

Chemical Physics · Physics 2020-02-26 Mohammadhasan Hedayati , Matt J. Kipper , Diego Krapf

We consider fluid wetting on a corrugated substrate using effective interfacial Hamiltonian theory and show that breaking the translational invariance along the wall can induce an 'unbending' phase transition in addition to unbinding. Both…

Soft Condensed Matter · Physics 2009-10-31 C. Rascon , A. O. Parry , A. Sartori

We consider a model of two (fully) compact polymer chains, coupled through an attractive interaction. These compact chains are represented by Hamiltonian paths (HP), and the coupling favors the existence of common bonds between the chains.…

Statistical Mechanics · Physics 2009-10-31 S. Franz , T. Garel , H. Orland

Using molecular dynamic simulation, we study the stretching of an adsorbed homopolymer in a poor solvent with one end held at a distance $z_e$ from the substrate. We measure the vertical force $f$ on the end of the chain as a function of…

Soft Condensed Matter · Physics 2009-11-10 Franck Celestini , Thoma Frisch , Xabier Oyharcabal

Advanced chain-growth computer simulation methodologies have been employed for a systematic statistical analysis of the critical behavior of a polymer adsorbing at a substrate. We use finitesize scaling techniques to investigate the…

Soft Condensed Matter · Physics 2017-05-09 J. A. Plascak , Paulo H. L. Martins , Michael Bachmann