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A geometric foundation thermo-statistics is presented with the only axiomatic assumption of Boltzmann's principle S(E,N,V)=k\ln W. This relates the entropy to the geometric area e^{S(E,N,V)/k} of the manifold of constant energy in the…

Statistical Mechanics · Physics 2017-08-23 D. H. E. Gross

We consider a small Hamiltonian system strongly interacting with a much larger Hamiltonian system (the bath), while being driven by both a time-dependent control parameter and non-conservative forces. The joint system is assumed to be…

Statistical Mechanics · Physics 2025-07-15 Xiangjun Xing

Depending on context, the term entropy is used for a thermodynamic quantity, a~measure of available choice, a quantity to measure information, or, in the context of statistical inference, a maximum configuration predictor. For systems in…

Statistical Mechanics · Physics 2018-11-14 Rudolf Hanel , Stefan Thurner

The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…

Quantum Physics · Physics 2015-05-18 X. L. Huang , B. Cui , X. X. Yi

In this work we study the mathematical aspects of the development in the continuum thermodynamics known as the "Entropy Principle". It started with the pioneering works of B.Coleman, W.Noll and I. Muller in 60th of XX cent. and got its…

Mathematical Physics · Physics 2010-08-03 Serge Preston

Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

Statistical Mechanics · Physics 2009-11-10 S. Goldstein , Joel L. Lebowitz

The configurational entropy is among the key observables to characterize experimentally the formation of a glass. Physically, it quantifies the multiplicity of metastable states in which an amorphous material can be found at a given…

Statistical Mechanics · Physics 2014-08-21 Ludovic Berthier , Daniele Coslovich

For a given topological dynamical system $(X,T)$ over a compact set $X$ with a metric $d$, the "variational principle" states that \begin{equation*} \sup_{\mu}h_\mu(T) = h(T) = h_d(T), \end{equation*} where $h_\mu(T)$ is the…

Dynamical Systems · Mathematics 2016-04-12 André Caldas , Mauro Patrão

We study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on…

Statistical Mechanics · Physics 2024-11-27 Philipp Strasberg , Joseph Schindler

For classical discrete systems under constant composition, a set of microscopic state dominantly contributing to thermodynamically equilibrium structure should depend on temperature and energy through Boltzmann factor, exp(-bE). Despite…

Statistical Mechanics · Physics 2019-09-11 Shouno Ohta , Ryogo Miyake , Koretaka Yuge

The Boltzmann-Gibbs celebrated entropy $S_{BG}=-k\sum_ip_i \ln p_i$ is {\it concave} (with regard to all probability distributions $\{p_i\}$) and {\it stable} (under arbitrarily small deformations of any given probability distribution). It…

Statistical Mechanics · Physics 2015-06-24 A. M. C. Souza , C. Tsallis

We demonstrate that Shannon's information entropy and the thermodynamic entropy of Boltzmann and Gibbs are quantitatively equivalent for real condensed-matter systems. By interpreting atomic configurations as information sources, we compute…

Statistical Mechanics · Physics 2025-12-03 Dallin Fisher , Qi-Jun Hong

We introduce a constructive framework for assigning thermodynamic structure to an arbitrary data system from its measured microstates. Starting from an empirical distribution over configurations, we first infer a data-driven energy function…

Statistical Mechanics · Physics 2026-04-29 George-Rafael Domenikos , Lock Yue Chew , Victoria Leong

The Boltzmann entropy $S^{(B)}$ is true in the case of equal probability of all microstates of a system. In the opposite case it should be averaged over all microstates that gives rise to the Boltzmann--Shannon entropy (BSE). Maximum…

Statistical Mechanics · Physics 2007-05-23 A. G. Bashkirov

Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…

Statistical Mechanics · Physics 2025-10-07 Jürgen T. Stockburger

We present the numbers of ice model and eight-vertex model configurations (with Boltzmann factors equal to one), I(n) and E(n) respectively, on the two-dimensional Sierpinski gasket SG(n) at stage $n$. For the eight-vertex model, the number…

Statistical Mechanics · Physics 2013-02-19 Shu-Chiuan Chang , Lung-Chi Chen , Hsin-Yun Lee

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

Statistical Mechanics · Physics 2017-10-18 Xiangjun Xing

We shall prove that the celebrated R\'enyi entropy is the first example of a new family of infinitely many multi-parametric entropies. We shall call them the $Z$-entropies. Each of them, under suitable hypotheses, generalizes the celebrated…

Mathematical Physics · Physics 2017-02-07 Piergiulio Tempesta

Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…

Statistical Mechanics · Physics 2013-02-11 E. G. D. Cohen

The Bekenstein-Hawking entropy suggests that thermodynamics is an intrinsic ingredient of gravity. Here, we explore the idea that requirements of thermodynamic consistency could determine the gravitational entropy in other set-ups. We…

General Relativity and Quantum Cosmology · Physics 2011-12-23 Charis Anastopoulos , Ntina Savvidou