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Ionic conductivity blocking at grain boundaries in polycrystalline electrolytes is one of the main obstacles that need to be overcome in order to improve the performance of solid state fuel cells and batteries. To this aim, harnessing the…

Materials Science · Physics 2019-08-12 G. Sánchez-Santolino , J. Salafranca , S. T. Pantelides , S. J. Pennycook , C. León , M. Varela

In established theories of grain coarsening, grains disappear either by shrinking or by rotating as a rigid object to coalesce with an adjacent grain. Here we report a third mechanism for grain coarsening, in which a grain splits apart into…

Interface migration in microstructures is mediated by the motion of line defects with step and dislocation character, i.e., disconnections. We propose a continuum model for arbitrarily-curved grain boundaries or heterophase interfaces…

Materials Science · Physics 2023-05-15 Caihao Qiu , Marco Salvalaglio , David J. Srolovitz , Jian Han

We have performed V-I measurements on a thin film YBa2Cu3O7 4^o [001] tilt low angle grain boundary over an extensive range of temperature and field, verifying the presence of a linear characteristic. We report on the occurrence of the…

Superconductivity · Physics 2009-11-07 M. J. Hogg , F. Kahlmann , E. J. Tarte , Z. H. Barber , J. E. Evetts

A continuum dislocation model of formation of grains whose boundaries have a non-vanishing thickness is proposed. For a single crystal deforming in simple shear the lamellar structure of grains with thin layers containing dislocations as…

Materials Science · Physics 2015-06-12 Michael Koster , Khanh Chau Le

We present a detailed numerical study on structure and local magnetic properties of $\langle 100 \rangle$ symmetric tilt grain boundaries in bcc-iron. Particular attention is paid to connection between type of grain boundary relaxation and…

Materials Science · Physics 2017-02-13 E. Vitkovská , P. Ballo

X-ray nanodiffraction is applied to study the formation and correlation of domain boundaries in mesocrystalline superlattices of PbS nanocrystals with face-centered cubic structure. Each domain of the superlattice can be described with one…

Local chemical ordering strongly influences the behavior of complex concentrated alloys, yet its characterization remains challenging due to the nanoscale dimensions and scattered spatial distribution of the ordered domains. Here, we study…

Materials Science · Physics 2026-02-10 Ian Geiger , Yuan Tian , Ying Han , Yutong Bi , Xiaoqing Pan , Penghui Cao , Timothy J. Rupert

We have produced solution-processed thin films of 6,13-bis(triisopropyl-silylethynyl) pentacene with grain sizes from a few micrometers up to millimeter scale by lateral crystallization from a rectangular stylus. Grains are oriented along…

Materials Science · Physics 2015-06-04 Songtao Wo , Randall L. Headrick , John E. Anthony

We discuss the dynamics of dust grains subjected to uncompensated torques arising from H_2 formation. In particular, we discuss grain dynamics when a grain spins down and goes through a ``crossover''. As first pointed out by Spitzer &…

Astrophysics · Physics 2009-10-28 A. Lazarian , B. T. Draine

Twisted and rope-like assemblies of filamentous molecules are common and vital structural elements in cells and tissue of living organisms. We study the intrinsic frustration occurring in these materials between the two-dimensional…

Soft Condensed Matter · Physics 2015-06-03 Amir Azadi , Gregory M. Grason

Polycrystalline solids can exhibit material properties that differ significantly from those of equivalent single-crystal samples, in part, because of a spontaneous redistribution of mobile point defects into so-called space-charge regions…

We study the motion of a grain boundary that separates two sets of mutually perpendicular rolls in Rayleigh-B\'enard convection above onset. The problem is treated either analytically from the corresponding amplitude equations, or…

Soft Condensed Matter · Physics 2009-11-07 Denis Boyer , Jorge Viñals

Grain boundary roughness can affect electronic and mechanical properties of two-dimensional materials. This roughness depends crucially on the growth process by which the two-dimensional material is formed. To investigate the key mechanisms…

Materials Science · Physics 2022-04-06 Fabio D. A. Aarão Reis , Bastien Marguet , Olivier Pierre-Louis

Grain boundaries are commonly observed in carbon nanostructures, but their influence on thermal and electric properties are still not completely understood. Using a combined approach of density functional tight-binding theory and…

Materials Science · Physics 2015-06-30 Thomas Lehmann , Dmitry A. Ryndyk , Gianaurelio Cuniberti

The study of grain boundary phase transitions is an emerging field until recently dominated by experiments. The major bottleneck in exploration of this phenomenon with atomistic modeling has been the lack of a robust computational tool that…

Materials Science · Physics 2018-02-21 Qiang Zhu , Amit Samanta , Bingxi Li , Robert E. Rudd , Timofey Frolov

Grain boundaries (GBs) can be treated as two-dimensional (2-D) interfacial phases (also called 'complexions') that can undergo interfacial phase-like transitions. As bulk phase diagrams and calculation of phase diagram (CALPHAD) methods are…

Materials Science · Physics 2022-09-05 Jian Luo

The structure and evolution of grain boundaries underlies the nature of polycrystalline materials. Here we describe an experimental apparatus and light reflection technique for measuring disorder at grain boundaries in optically clear…

Materials Science · Physics 2009-10-27 E. S. Thomson , J. S. Wettlaufer , L. A. Wilen

By lithographically fabricating an optimised Wheatstone bridge geometry, we have been able to make accurate measurements of the resistance of grain boundaries in Y1-xCaxBa2Cu3O7-d between the superconducting transition temperature, Tc, and…

We have characterized the structure of 176 different single-layer graphene grain boundaries using $>$1000 experimental HRTEM images using a semi-automated structure processing routine. We introduce a new algorithm for generating grain…

Materials Science · Physics 2015-08-04 Colin Ophus , Ashivni Shekhawat , Haider I Rasool , Alex Zettl
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