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We report systematic investigation of high pressure crystal structures and structural phase transition upto 46 GPa in CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder synchrotron x-ray diffraction experiments and Rietveld analysis of the…

Topological materials have been discovered so far largely by searching for existing compounds in crystallographic databases, but there are potentially new topological materials with desirable features that have not been synthesized. One of…

Materials Science · Physics 2022-09-21 Lin-Lin Wang

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

Canfieldite, Ag$_8$SnS$_6$, is a semiconducting mineral notable for its high ionic conductivity, photosensitivity, and low thermal conductivity. We report the solution growth of large single crystals of Ag$_8$SnS$_6$ of mass up to 1 g from…

The structural properties of EuCo2As2 have been studied up to 35 GPa, through the use of x-ray diffraction in a diamond anvil cell at a synchrotron source. At ambient conditions, EuCo2As2 (I4/mmm) has a tetragonal lattice structure with a…

Materials Science · Physics 2011-04-19 Matthew Bishop , Walter Uhoya , Georgiy Tsoi , Yogesh K. Vohra , Athena S. Sefat , Brian C. Sales

We have performed electrical resistivity measurements on single crystal BaFe2As2 under high pressure P up to 16 GPa with a cubic anvil apparatus, and up to 3 GPa with a modified Bridgman anvil cell. The samples were obtained from the same…

High pressure is a proven effective tool for modulating inter-layer interactions in semiconducting transition metal dichalcogenides, which leads to significant band structure changes. Here, we present an extended infrared study of the…

Tin sulfide (SnS) was successfully synthesized in single crystals by a melt and slow-cooling method. The obtained sample was characterized by an X-ray diffraction, an energy dispersive spectrometry, and an X-ray photoelectron spectroscopy.…

As an empirical tool in materials science and engineering, the iconic phase diagram owes its robustness and practicality to the topological characteristics rooted in the celebrated Gibbs phase law (F = C - P + 2). When crossing the phase…

We report high pressure structural phase transformation sequence in a layered Iron-based superconducting compound FeSe0.3Te0.7 to 31 GPa at room temperature. The ambient pressure PbO type tetragonal phase (Space Group - P4/nmm) transforms…

Materials Science · Physics 2011-05-05 Andrew K. Stemshorn , Yogesh K. Vohra , Phillip M. Wu , F. C. Hsu , Y. L. Huang , M. K. Wu , K. W. Yeh

We show that polycrystalline GeSb2Te4 in the fcc phase (f-GST), which is an insulator at low temperature at ambient pressure, becomes a superconductor at elevated pressures. Our study of the superconductor to insulator transition versus…

LaNiGa2 is a time-reversal symmetry breaking superconductor with symmetry protected band crossings, making it an ideal platform for investigating the interplay between unconventional superconductivity and electronic structure topology. Here…

Simultaneous high pressure x-ray diffraction and electrical resistance measurements have been carried out on a PbO type {\alpha}-FeSe0.92 compound to a pressure of 44 GPa and temperatures down to 4 K using designer diamond anvils at…

In the substitutionally disordered narrow-gap semiconductor Pb_{1-x}Ge_xTe, a finite-temperature cubic-rhombohedral transition appears above a critical concentration $x \approx 0.005$. As a first step towards a first-principles…

Materials Science · Physics 2009-10-30 Eric Cockayne , Karin M. Rabe

The evolution of pressure induced superconductivity in single crystal as well as polycrystalline samples of BaFe2As2 has been investigated through temperature dependent electrical resistivity studies in 0-7 GPa pressure range. While the…

Superconductivity · Physics 2015-05-13 Awadhesh Mani , Nilotpal Ghosh , S. Paulraj , A. Bharathi , C. S. Sundar

Analogous to 2D layered transition metal dichalcogenides, the TlSe family of 1D chain materials with Zintl-type structure exhibits exotic phenomena under high-pressure. In the present work, we have systematically investigated the…

The pressure-induced structural phase transition in the intermediate-valence compound CeNi has been investigated by X-ray and neutron powder diffraction techniques. For the first time it is shown that the structure of the pressure-induced…

Strongly Correlated Electrons · Physics 2016-06-17 A. Mirmelstein , A. Podlesnyak , Antnio M. dos Santos , G. Ehlers , O. Kerbel , V. Matvienko , A. S. Sefat , B. Saparov , G. J. Halder , J. G. Tobin

In a joint experimental and theoretical study, we investigate the isostructural collapse from the ambient pressure tetragonal phase to a collapsed tetragonal phase for non-superconducting metallic SrFe2As2 and SrFe_1.8Ru_0.2As_2. The…

The effects of pressure up to $\sim 20$ kbar, on the structural phase transition of lightly Sn-doped BaFe$_2$As$_2$, as well as on the superconducting transition temperature and upper critical field of (Ba$_{0.55}$K$_{0.45}$)Fe$_2$As$_2$…

Superconductivity · Physics 2008-07-08 M. S. Torikachvili , N. Ni , S. L. Bud'ko , P. C. Canfield

We have investigated structural and magnetic phase transitions under high pressures in a quaternary rare earth transition metal arsenide oxide NdCoAsO compound that is isostructural to high temperature superconductor NdFeAsO. Four-probe…