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The application of an external field often renders empirical criteria for identifying liquid-gas phase transitions ambiguous. Here, we demonstrate that the finite-size scaling of the density profile provides a definitive criterion to…

Statistical Mechanics · Physics 2025-10-28 Chong Zha , Yanshuang Chen , Cheng-Ran Du , Peng Tan , Yuliang Jin

A classical density functional theory is applied to study solvation of solutes in water. An approx- imate form of the excess functional is proposed for water. This functional requires the knowledge of pure solvent direct correlation…

Chemical Physics · Physics 2014-09-01 Guillaume Jeanmairet

Many-body interactions can play a relevant role in water properties. Here we study by Monte Carlo simulations a coarse-grained model for bulk water that includes many-body interactions associated to water cooperativity. The model is…

Statistical Mechanics · Physics 2016-10-04 Luis Enrique Coronas , Valentino Bianco , Arne Zantop , Giancarlo Franzese

A number of crystal structures of water have been `superheated' in Monte Carlo simulations. Two well known models for water were considered; namely the TIP4P model and the SPC/E model. By comparing the fluid-solid coexistence temperature to…

Statistical Mechanics · Physics 2009-02-24 Carl McBride , Carlos Vega , Eduardo Sanz , Luis G. MacDowell , Jose L. F. Abascal

Liquids displaying strong virial-potential energy correlations conform to an approximate density scaling of their structural and dynamical observables. This scaling property does not extend to the entire phase diagram, in general. The…

Soft Condensed Matter · Physics 2020-12-23 Thibaud Maimbourg , Jeppe C. Dyre , Lorenzo Costigliola

The Asakura-Oosawa model for colloid-polymer mixtures is studied by Monte Carlo simulations at densities inside the two-phase coexistence region of fluid and solid. Choosing a geometry where the system is confined between two flat walls,…

Soft Condensed Matter · Physics 2015-06-04 Debabrata Deb , Alexander Winkler , Peter Virnau , Kurt Binder

The temperature equilibration rate in dense hydrogen (for both T_{i}>T_{e} and T_i<T_e) has been calculated with molecular dynamics simulations for temperatures between 10 and 600 eV and densities between 10^{20}/cc to 10^{24}/cc. Careful…

A thermodynamically consistent particle-based model for fluid dynamics with continuous velocities and a non-ideal equation of state is presented. Excluded volume interactions are modeled by means of biased stochastic multiparticle…

Soft Condensed Matter · Physics 2009-11-11 Thomas Ihle , Erkan Tuzel , Daniel M. Kroll

The investigation of phase coexistence in systems with multi-component order parameters in finite systems is discussed, and as a generic example, Monte Carlo simulations of the two-dimensional q-state Potts model (q=30) on LxL square…

Statistical Mechanics · Physics 2013-03-18 A. Tröster , K. Binder

Maximum likelihood estimation is an important statistical technique for estimating missing data, for example in climate and environmental applications, which are usually large and feature data points that are irregularly spaced. In…

Numerical Analysis · Computer Science 2019-07-25 Sameh Abdulah , Hatem Ltaief , Ying Sun , Marc G. Genton , David E. Keyes

Liquid-vapor coexistence curves and critical parameters for hard-core 1:1 electrolyte models with diameter ratios lambda = sigma_{-}/\sigma_{+}=1 to 5.7 have been studied by fine-discretization Monte Carlo methods. Normalizing via the…

Statistical Mechanics · Physics 2016-08-31 J. M. Romero-Enrique , G. Orkoulas , A. Z. Panagiotopoulos , M. E. Fisher

In this paper the problem of consistency of smoothed particle hydrodynamics (SPH) is solved. A novel error analysis is developed in $n$-dimensional space using the Poisson summation formula, which enables the treatment of the kernel and…

Computational Physics · Physics 2019-04-09 Leonardo Di G. Sigalotti , Otto Rendón , Jaime Klapp , Carlos A. Vargas , Kilver Campos

According to excess-entropy scaling, dynamic properties of liquids like viscosity and diffusion coefficient are determined by the entropy. This link between dynamics and thermodynamics is increasingly studied and of interest also for…

Soft Condensed Matter · Physics 2024-08-13 Ian M. Douglass , Jeppe C. Dyre , Lorenzo Costigliola

A brief review is presented of the scaling of complex fluids, polymers and polyelectrolytes in solution and in confined geometry, in thermodynamical, structural and rheology properties using equilibrium and nonequilibrium dissipative…

Soft Condensed Matter · Physics 2016-12-06 Armando Gama Goicochea

The goal of this paper is to study convergence and error estimates of the Monte Carlo method for the Navier-Stokes equations with random data. To discretize in space and time, the Monte Carlo method is combined with a suitable deterministic…

Numerical Analysis · Mathematics 2022-05-10 Eduard Feireisl , Mária Lukáčová - Medviďová , Bangwei She , Yuhuan Yuan

Sequential Monte Carlo methods, also known as particle methods, are a widely used set of computational tools for inference in non-linear non-Gaussian state-space models. In many applications it may be necessary to compute the sensitivity,…

Statistics Theory · Mathematics 2011-06-14 Pierre Del Moral , Arnaud Doucet , Sumeetpal Singh

We analyze the critical gas-liquid phase behavior of arbitrary fluid mixtures in their coexistence region. We focus on the setting relevant for polydisperse colloids, where the overall density and composition of the system are being…

Soft Condensed Matter · Physics 2019-11-22 Pablo de Castro , Peter Sollich

The statistical mechanics of phase transitions in dense systems of polydisperse particles presents distinctive challenges to computer simulation and analytical theory alike. The core difficulty, namely dealing correctly with particle size…

Soft Condensed Matter · Physics 2013-09-03 Nigel B. Wilding , Peter Sollich

Monte Carlo simulations at constant pressure are performed to study coexistence and interfacial properties of the liquid-solid transition in hard spheres and in colloid-polymer mixtures. The latter system is described as a one-component…

Soft Condensed Matter · Physics 2015-05-18 T. Zykova-Timan , J. Horbach , K. Binder

We perform large-scale Quantum Monte Carlo (QMC) simulations for strongly interacting bosons in a 2D optical lattice trap, and confirm an excellent agreement with the benchmarking in-situ density measurements by the Chicago group [1]. We…

Quantum Gases · Physics 2011-03-16 Shiang Fang , Chia-Ming Chung , Ping Nang Ma , Pochung Chen , Daw-Wei Wang