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Neutron powder diffraction experiments on La2/3Ca1/3MnO3 over a broad temperature range above and below the metal-insulator transition have been analyzed beyond the Rietveld average approach by use of Reverse Monte Carlo modelling. This…

We report a detailed neutron scattering study of the ordering of spins and holes in oxygen-doped La(2)NiO(4.133). The single-crystal sample exhibits the same oxygen-interstitial order but better defined charge-stripe order than that studied…

Strongly Correlated Electrons · Physics 2009-10-30 P. Wochner , J. M. Tranquada , D. J. Buttrey , V. Sachan

The atomic pair distribution function (PDF) of stoichiometric LaMnO_3 has been measured. This has been fit with a structural model to extract the local Jahn-Teller distortion for an ideal Mn(3+)O_6 octahedron. These results are compared to…

Materials Science · Physics 2009-10-31 Th. Proffen , R. G. DiFrancesco , S. J. L. Billinge , E. L. Brosha , G. H. Kwei

We report a detailed high-temperature powder neutron diffraction investigation of the structural behavior of the multiferroic GaFeO3 between 296 and 1368 K. Temperature dependent neutron diffraction patterns do not show any appreciable…

Materials Science · Physics 2015-06-12 S. K. Mishra , R. Mittal , R. Singh , M. Zbiri , T. Hansen , H. Schober

Neutron and x-ray diffraction techniques have been used to study the competing long and short-range polar order in the relaxor ferroelectric Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) under a [111] applied electric field. Despite reports of a…

Materials Science · Physics 2009-11-13 C. Stock , Guangyong Xu , P. M. Gehring , H. Luo , X. Zhao , H. Cao , J. F. Li , D. Viehland , G. Shirane

We have investigated the low temperature phase of a Nd0.5Sr0.5MnO3 single crystal by x-ray resonant scattering at the Mn K-edge of the (3 0 0), (0 3 0) and (0 5/2 0) reflections. Strong resonances were observed for the s-s' channel in the…

Strongly Correlated Electrons · Physics 2009-11-10 Javier Herrero-Martin , Joaquin Garcia Ruiz , Gloria Subias , Javier Blasco , Maria Concepcion-Sanchez

Electron microdiffraction study of phase transition in La2/3Ca1/3MnO3 revealed temperature dependent (h+1/2,0,l) diffraction spots. Their intensity peaks at Tc. Quantitative electron diffraction intensity analysis shows that they come from…

Strongly Correlated Electrons · Physics 2009-10-31 J. M. Zuo , J. Tao

Neutron scattering is a powerful probe of strongly correlated systems. It can directly detect common phenomena such as magnetic order, and can be used to determine the coupling between magnetic moments through measurements of the spin-wave…

Strongly Correlated Electrons · Physics 2014-10-02 Igor A. Zaliznyak , John M. Tranquada

Local structural distortions in Na0.5Bi0.5TiO3-based solid solutions have been proved to play a crucial role in understanding and tuning their enhanced piezoelectric properties near the morphotropic phase boundary. In this work all local…

Materials Science · Physics 2017-10-06 Alexandra Neagu , Cheuk-Wai Tai

Neutron diffraction and muon spin relaxation ($\mu$SR) studies are presented for the newly characterized polymorph of NiNb$_2$O$_6$ ($\beta$-NiNb$_2$O$_6$) with space group P4$_2$/n and $\mu$SR data only for the previously known columbite…

A method is suggested for estimation of structural properties of amorphous fullerene and its derivatives produced by vacuum annealing. The method is based on the fitting of the neutron or x-ray powder diffraction patterns for scattering…

Materials Science · Physics 2014-12-24 V. S. Neverov , P. A. Borisova , A. B. Kukushkin , V. V. Voloshinov

Hydrogen is an efficient energy carrier that can be produced from renewable sources, enabling the transition towards CO2-free energy. Hydrogen can be stored for a long period in the solid-state, with suitable alloys. Ti-rich TiFe0.90…

The Lead-iron-niobate, (PbFe0.5Nb0.5O3 or PFN) was synthesized by low temperature sintering Single Step / Solid State Reaction Method. The 700 C / 2 hrs calcined powder was sintered at 1050 C / 1 hr. The sintered pellets were characterized…

Materials Science · Physics 2015-01-06 Shidaling Matteppanavar , Basavaraj Angadi , Sudhindra Rayprol

The orthorhombic compound NdFe$_2$Al$_{10}$ has been studied by powder and single-crystal neutron diffraction. Below $T_N$ = 3.9 K, the Nd$^{3+}$ magnetic moments order in a double-$k$ [$\mathbf{k}_1 = (0, \frac{3}{4}, 0)$, $\mathbf{k}_2 =…

Strongly Correlated Electrons · Physics 2014-12-31 J. Robert , F. Damay , K. Saito , A. M. Bataille , F. Porcher , G. André , A. Gukasov , J. -M. Mignot , H. Tanida , M. Sera

The magnetic properties of RMn2O5 multiferrroics as obtained by unpolarized and polarized neutron diffraction experiments are reviewed. We discuss the qualitative features of the magnetic phase diagram both in zero magnetic field and in…

Materials Science · Physics 2009-11-13 P. G. Radaelli , L. C. Chapon

A hypothesis that the local rotations of ReO$_6$ octahedra persist in the crystallographically untilted ambient phase of ReO$_3$ is examined by the high-resolution neutron time-of-flight total scattering based atomic pair distribution…

Materials Science · Physics 2012-11-20 Emil S. Bozin , T. Chatterji , Simon J. L. Billinge

The crystal structure of Na0.5CoO2, determined by powder neutron diffraction, is reported. The structure consists of layers of edge-shared CoO6 octahedra in a triangular lattice, with Na ions occupying ordered positions in the interleaving…

Strongly Correlated Electrons · Physics 2009-11-10 Q. Huang , M. L. Foo , J. W. Lynn , H. W. Zandbergen , G. Lawes , Yayu Wang , B. H. Toby , A. P. Ramirez , N. P. Ong , R. J. Cava

The frst neutron powder diffraction based atomic pair distribution functions (PDFs) are reported from the new wide angular-range chopper spectrometer ARCS at the Spallation Neutron Source at Oak Ridge National Laboratory. The spectrometer…

Materials Science · Physics 2009-06-19 E. S. Bozin , P. Juhas , W. Zhou , M. B. Stone , D. L. Abernathy , A. Huq , S. J. L. Billinge

Measurements of the electrical and thermal conductivities, thermopower and paramagnetic susceptibility have been performed on single crystal samples of Bi1/2Sr1/2MnO3 and complemented with the X-ray powder diffraction data. A pronounced…

Strongly Correlated Electrons · Physics 2009-11-07 J. Hejtmanek , K. Knizek , Z. Jirak , M. Hervieu , C. Martin , M. Nevriva , P. Beran

We report on the ultrafast dynamics of charge order and structural response during the photoinduced suppression of charge and orbital order in a mixed-valence manganite. Employing femtosecond time-resolved resonant x-ray diffraction below…