Related papers: Thermodynamics of means
The property that power means are monotonically increasing functions of their order is shown to be the basis of the second laws not only for processes involving heat conduction but also for processes involving deformations. In an…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
Thermodynamics imposes restrictions on what state transformations are possible. In the macroscopic limit of asymptotically many independent copies of a state---as for instance in the case of an ideal gas---the possible transformations…
Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…
It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…
The thermodynamics of an ideal gas enclosed in a box of volume a1 x a2 x a3 at temperature T is considered. The canonical partition function of the system is expressed in terms of complete elliptic integrals of the first kind, whose…
This work consists in the theorical development on the analysis of the Thermodynamic Laws and thermodynamic systems in relative motion, according to the laws of Classical Mechanics. The difference of this work for many of the literature is…
The thermodynamic limit of the internal energy and the entropy of the system of quantum interacting particles in random medium is shown to exist under the crucial requirements of stability and temperedness of interactions. The energy turns…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
Thermodynamics is traditionally constrained to the study of macroscopic systems whose energy fluctuations are negligible compared to their average energy. Here, we push beyond this thermodynamic limit by developing a mathematical framework…
The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single…
Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…
In many textbooks of thermodynamics, the polytropic process is usually introduced by defining its process equation rather than analyzing its actual origin. We realize a polytropic process of an ideal gas system when it is thermally contact…
The deep problems caused from the limitations of theoretical framework itself can only be clarified by extending and reconstructing of the theoretical framework, we extend classical theoretical framework of thermodynamics, break through the…
A simple and effective approach to thermodynamics is suggested, which solves the major difficulties in the traditional presentation of the subject. The internal energy is introduced from the behavior of deformable bodies, whereas the…
Microcanonical equations for several thermodynamic properties of a system, suitable for molecular dynamics simulations, are derived from the nonextensive Tsallis entropy functional. Two possible definitions of temperature, the usual one and…
Quantum measurement of a system can change its mean energy, as well as entropy. A selective measurement (classical or quantum) can be used as a "Maxwell's demon" to power a single-temperature heat engine, by decreasing the entropy. Quantum…