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Colloidal particles can create reconfigurable nanomaterials, with applications such as color-changing, self-repairing, and self-regulating materials and reconfigurable drug delivery systems. However, top-down methods for manipulating…

Soft Condensed Matter · Physics 2024-07-26 Mark N. McDonald , Cameron K. Peterson , Douglas R. Tree

We study experimentally and numerically a (quasi) two dimensional colloidal suspension of self-propelled spherical particles. The particles are carbon-coated Janus particles, which are propelled due to diffusiophoresis in a near-critical…

Soft Condensed Matter · Physics 2013-06-10 Ivo Buttinoni , Julian Bialké , Felix Kümmel , Hartmut Löwen , Clemens Bechinger , Thomas Speck

The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled…

We simulate the collision of atomic clusters with a weakly attractive surface using molecular dynamics in a regime between soft-landing and fragmentation, where the cluster undergoes large deformation but remains intact. As a function of…

Materials Science · Physics 2007-05-23 A. Awasthi , S. C. Hendy , P. Zoontjens , S. A. Brown

The kinetics of phase transition processes often governs the resulting material microstruc-ture. Using optical microscopy, we here investigate the formation and stabilization of a po-rous crystalline microstructure forming in low-salt…

Soft Condensed Matter · Physics 2023-06-23 Nina Lorenz , Christopher Wittenberg , Thomas Palberg

Colloidal particles, amphiphiles, and functionalized nanoparticles are examples of systems that frequently exhibit short-range attractions coupled with long-range repulsions. In this work, we observe striking differences in the dynamics of…

Soft Condensed Matter · Physics 2017-06-01 Jakub Pȩkalski , Andrew P. Santos , Athanassios Z. Panagiotopoulos

Colloidal gels have strong industrial relevance as they can behave liquid- and solid-like. The latter allows them to support the buoyant weight against gravity. However, the system is intrinsically out-of-equilibrium, which means that the…

Soft Condensed Matter · Physics 2024-05-28 Kim William Torre , Joost de Graaf

Unlike atoms, colloidal particles are not identical, but can only be synthesised within a finite size tolerance. Colloids are therefore polydisperse, i.e. mixtures of infinitely many components with sizes drawn from a continuous…

Soft Condensed Matter · Physics 2009-11-07 R. M. L. Evans , C. B. Holmes

Simple models based on isotropic interparticle attractions often fail to capture experimentally observed structures of colloidal gels formed through spinodal decomposition and subsequent arrest: the resulting gels are typically denser and…

Soft Condensed Matter · Physics 2021-08-27 Jasper N. Immink , J. J. Erik Maris , Peter Schurtenberger , Joakim Stenhammar

Inorganic nanocrystal gels retain distinct properties of individual nanocrystals while offering tunable, network structure-dependent characteristics. We review different mechanisms for assembling gels from colloidal nanocrystals including…

We present Monte Carlo simulations of colloidal particles pulled into grafted polymer layers by external fields. The insertion free energy of a single colloid into the polymer layer is qualitatively different for surfaces with an ordered…

Soft Condensed Matter · Physics 2012-10-17 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

Monopole-like electrostatic interactions are ubiquitous in biology and condensed matter, but they are often screened by counter-ions and cannot be switched from attractive to repulsive. In colloidal science, where the prime goal is to…

Soft Condensed Matter · Physics 2020-01-06 Ye Yuan , Qingkun Liu , Bohdan Senyuk , Ivan I. Smalyukh

-- A scientific hurdle in manufacturing solid films by drying colloidal layers is preventing them from fracturing. This paper examines how the drying rate of colloidal liquids influences the particle packing at the nanoscale in correlation…

Soft Condensed Matter · Physics 2016-02-29 Keyvan Piroird , Véronique Lazarus , Georges Gauthier , Arnaud Lesaine , Daniel Bonamy , Cindy Rountree

We use a mesoscopic simulation technique to study the effect of short-ranged inter-particle attraction on the steady-state sedimentation of colloidal suspensions. Attractions increase the average sedimentation velocity $v_s$ compared to the…

Soft Condensed Matter · Physics 2010-02-19 A. Moncho Jordá , A. A. Louis , J. T. Padding

Micro- and nanogels are widely used to stabilise emulsions and simultaneously implement their responsiveness to the external stimuli. One of the factors that improves the emulsion stability is the nanogel softness. Here, we study how the…

Soft Condensed Matter · Physics 2023-02-08 Alexander V. Petrunin , Steffen Bochenek , Walter Richtering , Andrea Scotti

We report on the electrostatic complexation between polyelectrolyte-neutral copolymers and oppositely charged 6 nm-crystalline nanoparticles. For two different dispersions of oxide nanoparticles, the electrostatic complexation gives rise to…

Soft Condensed Matter · Physics 2007-09-10 J. -F. Berret , A. Sehgal , M. Morvan , O. Sandre , A. Vacher , M. Airiau

Adding a non-adsorbing polymer to passive colloids induces an attraction between the particles via the `depletion' mechanism. High enough polymer concentrations lead to phase separation. We combine experiments, theory and simulations to…

Soft Condensed Matter · Physics 2016-07-13 J. Schwarz-Linek , C. Valeriani , A. Cacciuto , M. E. Cates , D. Marenduzzo , A. N. Morozov , W. C. K. Poon

The self-assembly of binary nanoparticle superlattices from colloidal mixtures is a promising method for the fabrication of complex colloidal co-crystal structures. However, binary mixtures often form amorphous or metastable phases instead…

Soft Condensed Matter · Physics 2022-05-11 R. Allen LaCour , Timothy C. Moore , Sharon C. Glotzer

We study the dynamics of quasi-two-dimensional concentrated suspensions of colloidal particles in active gels by computer simulations. Remarkably, we find that activity induces a dynamic clustering of colloids even in the absence of any…

Soft Condensed Matter · Physics 2019-10-11 G. Foffano , J. S. Lintuvuori , K. Stratford , M. E. Cates , D. Marenduzzo

We study colloidal particle dynamics of a model glass system using confocal and fluorescence microscopy as the sample evolves from a hard-sphere glass to a liquid with attractive interparticle interactions. The transition from hard-sphere…

Soft Condensed Matter · Physics 2015-05-13 Andrzej Latka , Yilong Han , Ahmed M. Alsayed , Andrew B. Schofield , A. G. Yodh , Piotr Habdas
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