Related papers: A generalization of Wolynes factor in activated pr…
The problem of Kramers' turnover is a central issue of dynamical theory of reaction rate. Since its classical solution in the Markovian limit in mid-eighties by Melnikov and Meshkov, the problem has been addressed by a number of groups in…
The aqueous ferrous-ferric system provides a classic example of an electron-transfer process in solution. There has been a long standing argument spanning more than three decades around the importance of nuclear tunnelling in this system,…
We describe a path-integral molecular dynamics implementation of our recently developed golden-rule quantum transition-state theory (GR-QTST). The method is applied to compute the reaction rate in various models of electron transfer and…
Based on a true phase space probability distribution function and an ensemble averaging procedure we have recently developed [Phys. Rev. E 65, 021109 (2002)] a non-Markovian quantum Kramers' equation to derive the quantum rate coefficient…
On the basis of a coherent state representation of quantum noise operator and an ensemble averaging procedure a scheme for quantum Brownian motion has been proposed recently [Banerjee {\it et al}, Phys. Rev. E {\bf65}, 021109 (2002);…
The Kramers' theory of activated processes is generalized for nonequilibrium open one-dimensional systems. We consider both the internal noise due to thermal bath and the external noise which are stationary, Gaussian and are characterized…
We consider the role of quantum effects in the transfer of hyrogen-like species in enzyme-catalysed reactions. This study is stimulated by claims that the observed magnitude and temperature dependence of kinetic isotope effects imply that…
We make a brief review of the Kramers escape rate theory for the probabilistic motion of a particle in a potential well U(x), and under the influence of classical fluctuation forces. The Kramers theory is extended in order to take into…
We have presented a simple approach to quantum theory of Brownian motion and barrier crossing dynamics. Based on an initial coherent state representation of bath oscillators and an equilibrium canonical distribution of quantum mechanical…
Based on the dynamical quantization method we derive a quantum phase-space non-Markovian Smoluchowski equation describing the non-inertial Brownian motion of a harmonic oscillator immersed in a generic environment. In the long-time regime…
Tunneling is a fascinating aspect of quantum mechanics that renders the local minima of a potential meta-stable, with important consequences for particle physics, for the early hot stage of the universe, and more speculatively, for the…
In this work, we study Hawking radiation from a general static black hole due to tunnelling of particle having nonzero mass. Hawking temperature has been calculated using both the tunnelling method and the Hamilton-Jacobi method and the…
We compute tunneling in a quantum field theory in 1+1 dimensions for a field potential $U(\Phi)$ of the asymmetric double well type. The system is localized initially in the ``false vacuum''. We consider the case of a {\em compact space}…
We consider in what sense quantum tunnelling is associated with non-classical probabilistic behaviour. We use the Wigner function quasi-probability description of quantum states. We give a definition of tunnelling that allows us to say…
Recent developments in the understanding of real-time path integrals led to the development of the ``steadyon picture'' for the semi-classical calculation of quantum tunneling rates. We discuss tunneling out of a generic localized initial…
The spontaneous switching of a quantum particle between the wells of a double-well potential is a phenomenon of general interest to physics and chemistry. It was broadly believed that the switching rate decreases steadily with the size of…
We study the effects of the environment on tunneling in an open system described by a static double-well potential. We describe the evolution of a quantum state localized in one of the minima of the potential at $t=0$, both in the limits of…
The constraints on the scaling properties of conserved charge densities in the vicinity of a zero temperature ($T$), second-order quantum phase transition are studied. We introduce a generalized Wilson ratio, characterizing the non-linear…
We rigorously investigate the quantum dissipative dynamics of a ratchet system described by a periodic potential model based on the Caldeira-Leggett Hamiltonian with a biharmonic force. In this model, we use the reduced hierarchy equations…
We investigate the thermodynamic properties of black holes in Conformal Weyl Gravity (CWG) using the Mannheim-Kazanas solution, with particular emphasis on quantum corrections that become significant near the Planck scale. Our analysis…