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A novel Thomas-Fermi (TF) approach to inhomogeneous superfluid Fermi-systems is presented and shown that it works well also in cases where the Local Density Approximation (LDA) breaks down. The novelty lies in the fact that the…

Nuclear Theory · Physics 2017-08-23 Peter Schuck , Xavier Viñas

The propensity for ion-pairing can often dictate the thermodynamic and kinetic properties of electrolyte solutions. Fast and accurate estimates of ion-pairing can thus be extremely valuable for supplementing design and screening efforts for…

Soft Condensed Matter · Physics 2022-02-23 Ajay Muralidharan , Arun Yethiraj

Ionic microgels are soft colloidal particles, composed of crosslinked polymer networks, that ionize and swell when dispersed in a good solvent. Swelling of these permeable, compressible particles involves a balance of electrostatic,…

Soft Condensed Matter · Physics 2020-01-29 Alan R. Denton , Mohammed O. Alziyadi

We consider an ionic fluid made with two species of mobile particles carrying either a positive or a negative charge. We derive a sum rule for the fourth moment of equilibrium charge correlations. Our method relies on the study of the…

Statistical Mechanics · Physics 2016-11-30 Angel Alastuey , Riccardo Fantoni

Using techniques of effective field theory, we consider the thermodynamical properties of a dilute two-dimensional plasma interacting via a $1/r$ potential. The first one-loop correction to the partition function is already logarithmically…

Plasma Physics · Physics 2008-11-26 Manuel A. Valle Basagoiti

We consider the system of particles with equal charges and nearest neighbour Coulomb interaction on the interval. We study local properties of this system, in particular the distribution of distances between neighbouring charges. For zero…

Mathematical Physics · Physics 2016-11-08 V. A. Malyshev , A. A. Zamyatin

We consider a single particle tunnelling in a tight-binding model with nearest-neighbour couplings, in the presence of a periodic high-frequency force. An effective Hamiltonian for the particle is derived using an averaging method…

Other Condensed Matter · Physics 2014-02-07 A. P. Itin , A. I. Neishtadt

A fermion ground state energy functional is set up in terms of particle density, relative pair density, and kinetic energy tensor density. It satisfies a minimum principle if constrained by a complete set of compatibility conditions. A…

Chemical Physics · Physics 2009-10-17 Bin Liu , Jerome K. Percus

In this paper we continue the study of the derivation of different types of kinetic equations which arise from scaling limits of interacting particle systems. We began this study in \cite{NVW}. More precisely, we consider the derivation of…

Mathematical Physics · Physics 2021-03-18 Alessia Nota , Juan J. L. Velázquez , Raphael Winter

Steric hindered frustrated Lewis pairs (FLPs) have been shown to activate hydrogen molecules, and their reactivity is strongly determined by the geometric parameters of the Lewis acid s and bases. A recent experimental study showed that…

Chemical Physics · Physics 2021-01-22 Xiaoqing Liu , Xiaojing Wang , Tianhao Yu , Weizhen Zhao , Lei Liu

In order to provide a formally correct thermodynamical description of inhomogeneous fluids valid on all length scales down to the classical limit we postulate that all extensive quantities have locally extensive analogues. We derive local…

Statistical Mechanics · Physics 2016-08-14 Aljaž Godec , Janko Jamnik , Franci Merzel

The accuracy of density-functional theory (DFT) is determined by the quality of the approximate functionals, such as exchange-correlation in electronic DFT and the excess functional in the classical DFT formalism of fluids. The exact…

Realistic fluid-solid interaction potentials are essential in description of confined fluids especially in the case of geometric heterogeneous surfaces. Correlated random field is considered as a model of random surface with high geometric…

Statistical Mechanics · Physics 2017-05-24 Aleksey Khlyupin , Timur Aslyamov

In a recent article, we described how the microscopic structure of density-density correlations in the fluid interfacial region, for systems with short-ranged forces, can be understood by considering the resonances of the local structure…

Statistical Mechanics · Physics 2019-09-04 Andrew O. Parry , Carlos Rascón

Analogue gravity offers an approach for testing the universality and robustness of quantum field theories in curved spacetimes and validating them using down-to-earth, laboratory-based experiments. Fluid interfaces are a promising framework…

General Relativity and Quantum Cosmology · Physics 2023-06-27 Vitor S. Barroso , Cameron R. D. Bunney , Silke Weinfurtner

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

Machine Learning (ML) interatomic models and potentials have been widely employed in simulations of materials. Long-range interactions often dominate in some ionic systems whose dynamics behavior is significantly influenced. However, the…

Materials Science · Physics 2022-12-01 Hongyu Yu , Liangliang Hong , Shiyou Chen , Xingao Gong , Hongjun Xiang

Two-dimensional ionic liquids with single site anion and cation-neutral dimer are studied by computer simulations and integral equation techniques, with the aim of characterizing differences with single site anion-cation mixtures, and also…

Chemical Physics · Physics 2018-10-17 Perera Aurélien , Urbic Tomaz

Active systems, which are driven out of equilibrium by local non-conservative forces, exhibit unique behaviors and structures with potential utility for the design of novel materials. An important and difficult challenge along the path…

Soft Condensed Matter · Physics 2022-08-09 Laura Tociu , Gregory Rassolov , Étienne Fodor , Suriyanarayanan Vaikuntanathan

The present work presents a density-functional microscopic model of soft biological tissue. The model was based on a prototype molecular structure from experimentally resolved collagen peptide residues and water clusters and has the…

Soft Condensed Matter · Physics 2014-04-15 E. T. Sato , A. R. Rocha , L. F. C. S. Carvalho , J. D. Almeida , H. Martinho