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A theoretical description for the radial density profile of a finite number of identical charged particles confined in a harmonic trap is developed for application over a wide range of Coulomb coupling (or, equivalently, temperatures) and…

Statistical Mechanics · Physics 2015-05-14 J. Wrighton , J. W. Dufty , H. Kählert , M. Bonitz

We develop a microscopic theory to analyze the phase behaviour and compute correlation functions of dense assemblies of soft repulsive particles both at finite temperature, as in colloidal materials, and at vanishing temperature, a…

Disordered Systems and Neural Networks · Physics 2011-11-09 Ludovic Berthier , Hugo Jacquin , Francesco Zamponi

We study ionic liquids interacting with electrified interfaces. The ionic fluid is modeled as a Coulomb lattice gas. We compare the ionic density profiles calculated using a popular modified Poisson-Boltzmann equation with the explicit…

Soft Condensed Matter · Physics 2017-12-21 Matheus Girotto , Thiago Colla , Alexandre P. dos Santos , Yan Levin

Universal properties of the Coulomb interaction energy apply to all many-electron systems. Bounds on the exchange-correlation energy, inparticular, are important for the construction of improved density functionals. Here we investigate one…

Chemical Physics · Physics 2015-05-13 Mariana M. Odashima , K. Capelle

According to extensive experimental findings, the Ginzburg temperature $t_{G}$ for ionic fluids differs substantially from that of nonionic fluids [Schr\"oer W., Weig\"{a}rtner H. 2004 {\it Pure Appl. Chem.} {\bf 76} 19]. A theoretical…

Soft Condensed Matter · Physics 2012-07-02 O. V. Patsahan , J. -M. Caillol , I. M. Mryglod

Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to…

Statistical Mechanics · Physics 2008-08-20 James F. Lutsko

In a recent article, we showed how the properties of the density-density correlation function and its integral, the local structure factor, in the fluid interfacial region, in systems with short-ranged forces, can be understood…

Soft Condensed Matter · Physics 2019-11-20 Andrew O. Parry , Carlos Rascón

We propose a local, O(N) molecular dynamics algorithm for the simulation of charged systems. The long ranged Coulomb potential is generated by a propagating electric field that obeys modified Maxwell equations. On coupling the…

Soft Condensed Matter · Physics 2009-11-10 Jörg Rottler , A. C. Maggs

We present a personal view on the current state of statistical mechanics of Coulomb fluids with special emphasis on the interactions between macromolecular surfaces, concentrating on the weak and the strong coupling limits. Both are…

Soft Condensed Matter · Physics 2015-06-16 Ali Naji , Matej Kanduč , Jan Forsman , Rudolf Podgornik

Using the collective variables method we revisit the estimates of the Ginzburg temperature for the Coulomb-dominated models of ionic fluids. We consider the charge-asymmetric primitive model supplemented by short-range attractive…

Statistical Mechanics · Physics 2013-04-30 Oksana Patsahan

The Poisson-Boltzmann mean-field description of ionic solutions has been successfully used in predicting charge distributions and interactions between charged macromolecules. While the electrostatic model of charged fluids, on which the…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Daniel Harries , Rudi Podgornik

Condensed ionic systems are described in the framework of a combined approach that takes into account both long-range and short-range interactions. Short-range interaction is expressed in terms of mean potentials and long-range interaction…

Statistical Mechanics · Physics 2019-10-03 G. Bokun , I. Kravtsiv , M. Holovko , V. Vikhrenko , D. di Caprio

We investigate the liquid-vapor interface of the restricted primitive model (RPM) for an ionic fluid using a density-functional approximation based on correlation functions of the homogeneous fluid as obtained from the mean-spherical…

Condensed Matter · Physics 2009-10-30 B. Groh , R. Evans , S. Dietrich

A molecular theory of liquid water is identified and studied on the basis of computer simulation of the TIP3P model of liquid water. This theory would be exact for models of liquid water in which the intermolecular interactions vanish…

Chemical Physics · Physics 2009-11-13 J. K. Shah , D. Asthagiri , L. R. Pratt , M. E. Paulaitis

Various strong coupling theories of the one-component plasma have successfully predicted the thermodynamic and structural properties by separating the Coulomb potential into short- and long-ranged parts in {\itshape ad hoc} ways. Moreover,…

Statistical Mechanics · Physics 2018-11-07 Hiroshi Frusawa

The lattice fluid model of the system with short range and long range Coulomb interactions is suggested. In the framework of the collective variables method, the screening of the Coulomb interactions in the bulk is considered. It is shown…

Other Condensed Matter · Physics 2019-01-24 George Bokun , Dung di Caprio , Myroslav Holovko , Vyacheslav Vikhrenko

The correlation functions of an ionic fluid with charge and size asymmetry are studied within the framework of the random phase approximation. The results obtained for the charge-charge correlation function demonstrate that the…

Statistical Mechanics · Physics 2016-08-31 Oksana Patsahan , Ihor Mryglod , Jean-Michel Caillol

The effect of long-ranged Coulomb interaction on the low energy properties (momentum distribution function, density of states, electron spectral function, and $4k_F$ correlation function) of one-dimensional electron systems is determined…

Strongly Correlated Electrons · Physics 2009-10-31 D. W. Wang , A. J. Millis , S. Das Sarma

We formulate a local picture of strongly correlated systems as a Feynman sum over atomic configurations. The hopping amplitudes between these atomic configurations are identified as the renormalization group charges, which describe the…

Condensed Matter · Physics 2015-06-25 Gabriel Kotliar , Qimiao Si

Accurate simulations of a condensed system of ions or polar molecules are concerned with proper handlings of the involved electrostatics. For such a Coulomb system at a charged planar interface, the Coulomb interaction averaged over the…

Chemical Physics · Physics 2024-07-29 Zhonghan Hu