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We report on the differences between colloidal systems left to evolve in the earth's gravitational field and the same systems for which a slow continuous rotation averaged out the effects of particle sedimentation on a distance scale small…

We theoretically study sedimentation-diffusion equilibrium of dilute binary, ternary, and polydisperse mixtures of colloidal particles with different buoyant masses and/or charges. We focus on the low-salt regime, where the entropy of the…

Soft Condensed Matter · Physics 2009-11-11 Jos Zwanikken , rene van Roij

We study theoretically the effect of a gravitational field on the equilibrium behaviour of a colloidal suspension of rods with different length-to-width aspect ratios. The bulk phases of the system are described with analytical equations of…

Soft Condensed Matter · Physics 2023-03-10 Tobias Eckert , Matthias Schmidt , Daniel de las Heras

We study the sedimentation of colloidal gels by using a combination of light scattering, polarimetry and video imaging. The asymptotic concentration profiles $\varphi(z,t\rightarrow \infty)$ exhibit remarkable scaling properties: profiles…

Soft Condensed Matter · Physics 2015-06-04 Stefano Buzzaccaro , Eleonora Secchi , Giovanni Brambilla , R. Piazza , Luca Cipelletti

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

Soft Condensed Matter · Physics 2009-11-13 William Kung , Monica Olvera de la Cruz

We examine sedimentation density profiles of star polymer solutions as an example of colloidal systems in sedimentation equilibrium which exhibit reentrant melting in their bulk phase diagram. Phase transitions between a fluid and a fluid…

Soft Condensed Matter · Physics 2009-11-07 J. Dzubiella , H. M. Harreis , C. N. Likos , H. Lowen

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For…

Soft Condensed Matter · Physics 2009-11-13 C. Patrick Royall , Joachim Dzubiella , Matthias Schmidt , Alfons van Blaaderen

We study crystal nucleation under the influence of sedimentation in a model of colloidal hard spheres via Brownian Dynamics simulations. We introduce two external fields acting on the colloidal fluid: a uniform gravitational field (body…

Soft Condensed Matter · Physics 2013-07-03 John Russo , Anthony C. Maggs , Daniel Bonn , Hajime Tanaka

We investigate the sedimentation equilibrium of a charge stabilized colloidal suspension in the regime of low ionic strength. We analyze the asymptotic behaviour of the density profiles on the basis of a simple Poisson--Boltzmann theory and…

Soft Condensed Matter · Physics 2009-10-31 Gabriel Tellez , Thierry Biben

Both polydispersity and the presence of a gravitational field are inherent to essentially any colloidal experiment. While several theoretical works have focused on the effect of polydispersity on the bulk phase behavior of a colloidal…

Soft Condensed Matter · Physics 2022-12-28 Tobias Eckert , Matthias Schmidt , Daniel de las Heras

Sedimentation-diffusion equilibrium density profiles of suspensions of charge-stabilized colloids are calculated theoretically and by Monte Carlo simulation, both for a one-component model of colloidal particles interacting through pairwise…

Soft Condensed Matter · Physics 2013-05-29 Aldemar Torres , Alejandro Cuetos , Marjolein Dijkstra , Rene van Roij

We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the…

Soft Condensed Matter · Physics 2009-11-07 J. Dzubiella , A. G. Moreira , P. A. Pincus

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

Soft Condensed Matter · Physics 2010-09-09 Chi-Lun Lee , Sio-Kit Ng

Gravity can affect colloidal suspensions since for micrometer-sized particles gravitational and thermal energies can be comparable over vertical length scales of a few millimeters. In mixtures, each species possesses a different buoyant…

Soft Condensed Matter · Physics 2021-09-08 Tobias Eckert , Matthias Schmidt , Daniel de las Heras

Interactions between charged colloidal particles are profoundly influenced by charge regulation and charge renormalization, rendering the effective potential highly sensitive to local particle density. In this work, we investigate how a…

Soft Condensed Matter · Physics 2025-11-10 Laura Jansen , Thijs ter Rele , Marjolein Dijkstra

We study a model in which particles interact with short-ranged attractive and long-ranged repulsive interactions, in an attempt to model the equilibrium cluster phase recently discovered in sterically stabilized colloidal systems in the…

Soft Condensed Matter · Physics 2009-11-10 Francesco Sciortino , Stefano Mossa , Emanuela Zaccarelli , Piero Tartaglia

The evolution of an initially prepared distribution of micron sized colloidal particles, trapped at a fluid interface and under the action of their mutual capillary attraction, is analyzed by using Brownian dynamics simulations. At a…

Soft Condensed Matter · Physics 2011-11-29 J. Bleibel , A. Dominguez , M. Oettel , S. Dietrich

We use a mesoscopic simulation technique to study the effect of short-ranged inter-particle attraction on the steady-state sedimentation of colloidal suspensions. Attractions increase the average sedimentation velocity $v_s$ compared to the…

Soft Condensed Matter · Physics 2010-02-19 A. Moncho Jordá , A. A. Louis , J. T. Padding

The structural and dynamical properties of ultra-soft colloids - star polymers - exposed to a uniform external force field are analyzed applying the multiparticle collision dynamics approach, a hybrid coarse-grain mesoscale simulation…

Soft Condensed Matter · Physics 2018-03-09 Sunil P. Singh , Gerhard Gompper , Roland G. Winkler

In equilibrium, colloidal suspensions governed by short-range attractive and long-range repulsive interactions form thermodynamically stable clusters. Using Brownian dynamics computer simulations, we investigate how this equilibrium…

Soft Condensed Matter · Physics 2015-09-30 Ethayaraja Mani , Hartmut Löwen
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