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The influence of molecular vibration on the Seebeck coefficient is studied within a simple model. Results of a scattering theory approach are compared to those of a full self-consistent non-equilibrium Green's function scheme. We show, for…

Mesoscale and Nanoscale Physics · Physics 2008-06-18 Michael Galperin , Abraham Nitzan , Mark A. Ratner

We develop a classical mapping approach suitable to describe vibrationally coupled charge transport in molecular junctions based on the Cartesian mapping for many-electron systems [J. Chem. Phys. 137, 154107 (2012)]. To properly describe…

Strongly Correlated Electrons · Physics 2015-06-18 Bin Li , Eli. Y. Wilner , Michael Thoss , Eran Rabani , William H. Miller

We consider a transmission of electrons through a two-dimensional ballistic point contact in the low-conductance regime below the 0.7-anomaly. The scattering of electrons by Friedel oscillations of charge density results in a contribution…

Mesoscale and Nanoscale Physics · Physics 2013-01-10 Tatiana Krishtop , Kirill Nagaev

We investigate electronic transport through two types of conjugated molecules. Mechanically controlled break-junctions are used to couple thiol endgroups of single molecules to two gold electrodes. Current-voltage characteristics (IVs) of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Reichert , R. Ochs , D. Beckmann , H. B. Weber , M. Mayor , H. v. Loehneysen

For the study of molecular spin junctions, we take into account two types of couplings between the molecule and the metal leads: (i) electron transfer that gives rise to net current in the biased junction and (ii) energy transfer between…

Mesoscale and Nanoscale Physics · Physics 2009-04-23 M. Jouravlev , Kwang S. Kim

We theoretically analyze the spectrum of a magnetic molecule when its charge and spin can couple to the molecular vibrations. More specifically, we show that the interplay between charge-vibron and spin-vibron coupling leads to a…

Mesoscale and Nanoscale Physics · Physics 2018-07-04 Ahmed Kenawy , Janine Splettstoesser , Maciej Misiorny

We present a quaternion-inspired formalism specifically developed to evaluate the electric current that traverses a single molecule subjected to an externally applied voltage. The molecule of interest is covalently connected to two small…

Mesoscale and Nanoscale Physics · Physics 2014-08-06 Augusto C. L. Moreira , Celso P. de Melo

We introduce a theoretical and numerical method to investigate the flow of charged fluid mixtures under extreme confinement. We model the electrolyte solution as a ternary mixture, comprising two ionic species of opposite charge and a third…

Mesoscale and Nanoscale Physics · Physics 2012-09-13 Umberto Marini Bettolo Marconi , Simone Melchionna

The linear thermoelectric properties of molecular junctions are theoretically studied close to room temperature within a model including electron-electron and electron-vibration interactions on the molecule. A nonequilibrium adiabatic…

Mesoscale and Nanoscale Physics · Physics 2015-11-26 C. A. Perroni , D. Ninno , V. Cataudella

Vibrational heat transport in molecular junctions is a central issue in different contemporary research areas like Chemistry, material science, mechanical engineering, thermoelectrics and power generation. Our model system consists of a…

Statistical Mechanics · Physics 2025-07-04 Jayasmita Behera , Malay Bandyopadhyay

The interaction between electronic and vibrational degrees of freedom is an important mechanism in nonequilibrium charge transport through molecular nanojunctions. While adiabatic polaron-type coupling has been studied in great detail, new…

Mesoscale and Nanoscale Physics · Physics 2022-06-10 Christoph Kaspar , André Erpenbeck , Jakob Bätge , Christian Schinabeck , Michael Thoss

In this paper we address the topic of inelastic electron scattering in mesoscopic quantum transport. For systems where only elastic scattering is present, Landauer theory provides an adequate description of transport that relates the…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon G. Emberly , George Kirczenow

We present a scattering theory description for the inelastic current noise in the presence of electron-vibration interactions. In this description, we specify elastic and inelastic scattering contributions to the shot noise by examining…

Mesoscale and Nanoscale Physics · Physics 2017-09-15 Sejoong Kim

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

Mesoscale and Nanoscale Physics · Physics 2023-08-11 Koushik R. Das , Sudipta Dutta

We study the electronic transport in a molecular junction in which each site is coupled to a local phonon bath using the non-equilibrium Green's function method. We observe the length period of the oscillatory conductance in odd-numbered…

Strongly Correlated Electrons · Physics 2011-08-12 Ya-Lin Lo , Shih-Jye Sun , Ying-Jer Kao

The change of the vibrational energy within a molecule after collisions with another molecule plays an essential role in the evolution of molecular internal energy distributions, which is also the limiting process in the relaxation of the…

Chemical Physics · Physics 2024-09-16 Xiaorui Zhao , Xuefei Xu , Haitao Xu

Using molecular simulation and continuum dielectric theory, we consider how electrochemical kinetics are modulated by twist angle in bilayer graphene electrodes. By establishing a connection between twist angle and the screening length of…

Statistical Mechanics · Physics 2024-11-06 Leonardo Coello Escalante , David T. Limmer

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

Quantum transport of electrons through a molecule is a series of individual electron tunnelling events separated by stochastic waiting time intervals. We study the emergence of temporal correlations between successive waiting times for the…

Mesoscale and Nanoscale Physics · Physics 2017-09-19 Daniel S. Kosov

The influence of an electron-vibrational coupling on the laser control of electron transport through a molecular wire that is attached to several electronic leads is investigated. These molecular vibrational modes induce an effective…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jörg Lehmann , Sigmund Kohler , Volkhard May , Peter Hänggi
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