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The conventional approaches to the inverse density functional theory problem typically assume non-degeneracy of the Kohn-Sham (KS) eigenvalues, greatly hindering their use in open-shell systems. We present a generalization of the inverse…

Chemical Physics · Physics 2024-01-09 Bikash Kanungo , Jeffrey Hatch , Paul M. Zimmerman , Vikram Gavini

We examine the performance of our recently developed LFAs-PBE exchange-correlation (XC) potential [C.-R. Pan, P.-T. Fang, and J.-D. Chai, Phys. Rev. A, 2013, 87, 052510] for the high-order harmonic generation (HHG) spectra and related…

Chemical Physics · Physics 2016-06-14 Hsiao-Ling Sun , Wei-Tao Peng , Jeng-Da Chai

To explore whether the density-functional theory non-equilibrium Green's function formalism (DFT-NEGF) provides a rigorous framework for quantum transport, we carried out time-dependent density functional theory (TDDFT) calculations of the…

Materials Science · Physics 2011-07-01 ChiYung Yam , Xiao Zheng , GuanHua Chen , Yong Wang , Thomas Frauenheim , Thomas A. Niehaus

In density functional theory (DFT), the exchange-correlation functional can be exactly expressed by the adiabatic connection integral. It has been noticed that as lambda goes to infinity, the lambda^(-1) term in the expansion of W(lambda)…

Other Condensed Matter · Physics 2015-05-13 Zhenfei Liu , Kieron Burke

It is shown here that the Exact Exchange (EE) formalism provides a natural and rigorous approach for a Density Functional Theory (DFT) of the Integer Quantum Hall Effect (IQHE). Application of a novel EE method to a quasi two-dimensional…

Mesoscale and Nanoscale Physics · Physics 2017-12-06 D. Miravet , G. J. Ferreira , C. R. Proetto

Electronic stopping power models describing fuel heating processes in inertial fusion energy concepts typically assume linear-response behavior through quadratic scaling with the projectile charge. We report the results of real-time…

Plasma Physics · Physics 2025-11-04 Alina Kononov , Thomas W. Hentschel , Stephanie B. Hansen , Andrew D. Baczewski

The derivative discontinuity of the exchange-correlation (xc) energy at integer particle number is a property of the exact, unknown xc functional of density functional theory (DFT) which is absent in many popular local and semilocal…

Strongly Correlated Electrons · Physics 2015-06-11 Gao Xianlong , A-Hai Chen , I. V. Tokatly , S. Kurth

Time-dependent density functional theory (TDDFT) is a theory that describes the time evolution of quantum mechanical many-electron systems under the influence of external time-dependent electric and magnetic fields. INQ is a specially…

An extension of time-dependent density functional theory (TDDFT), the generalized time-dependent generator coordinate method (TDGCM), is applied to a study of induced nuclear fission dynamics. In the generalized TDGCM, the correlated…

Nuclear Theory · Physics 2025-04-11 B. Li , D. Vretenar , T. Nikši\' c , P. W. Zhao , J. Meng

Semilocal exchange-correlation functionals are the most accurate, realistic and widely used ones to describe the complex many-electron effects of two-dimensional quantum systems. Beyond local density approximation, the generalized gradient…

Materials Science · Physics 2017-04-12 Subrata Jana , Prasanjit samal

This chapter provides a basic introduction to excited-state extensions of density functional theory (DFT), including time-dependent (TD-)DFT in both its linear-response and its explicitly time-dependent formulations. As applied to the…

Chemical Physics · Physics 2023-05-02 John M. Herbert

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari

The exchange-only virial relation due to Levy and Perdew is revisited. Invoking the adiabatic connection, we introduce the exchange energy in terms of the right-derivative of the universal density functional w.r.t. the coupling strength…

Rabi oscillations have long been thought to be out of reach in simulations using time-dependent density functional theory (TDDFT), a prominent symptom of the failure of the adiabatic approximation for non-perturbative dynamics. We present a…

Chemical Physics · Physics 2024-06-21 Davood B. Dar , Anna Baranova , Neepa T. Maitra

In this contribution, we extend our framework for analyzing and visualizing correlated many-electron dynamics to non-variational, highly scalable electronic structure method. Specifically, an explicitly time-dependent electronic wave packet…

Chemical Physics · Physics 2017-04-27 Gunter Hermann , Vincent Pohl , Jean Christophe Tremblay

In the present communication the Bayesian conditional probability approach is applied to the wave function of a many-electron system that results in appearance of a quantum vector potential in the DFT Schrodinger equation due to electron…

Chemical Physics · Physics 2012-12-05 R. Tsekov , G. N. Vayssilov

An atomic-orbital basis set framework is presented for carrying out velocity- gauge real-time time-dependent density functional theory (TDDFT) simulations in periodic systems employing range-separated hybrid functionals. Linear optical…

Materials Science · Physics 2018-10-02 C. D. Pemmaraju

We describe a method for calculating the exchange and correlation (XC) contributions to the total energy, effective potential, and stress tensor in the generalized gradient approximation. We avoid using the analytical expressions for the…

Materials Science · Physics 2009-11-07 L. C. Balbas , Jose Luis Martins , Jose M. Soler

We present recent advances in Density Functional Theory (DFT) for applications to the field of quantum transport, with particular emphasis on transport through strongly correlated systems. We review the foundations of the popular…

Mesoscale and Nanoscale Physics · Physics 2017-10-11 S. Kurth , G. Stefanucci

The development of analytic-gradient methodology for excited states within conventional time-dependent density-functional theory (TDDFT) would seem to offer a relatively inexpensive alternative to better established quantum-chemical…

Other Condensed Matter · Physics 2010-08-11 Felipe Cordova , L. Joubert Doriol , Andrei Ipatov , Mark E. Casida , Claudia Filippi , Alberto Vela
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