Related papers: Phase Transition in Small System
Drops of water at room temperature were released in hot oil, which had a temperature higher than that of the boiling point of water. Initially, the drop temperature increases slowly mainly due to heat transfer diffusion; convective heat…
The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the nuclear drop is assumed to be in thermodynamic equilibrium with its own evaporated nucleonic vapor conserving the total baryon number and…
When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…
Raising the temperature of a material enhances the thermal motion of particles. Such an increase in thermal energy commonly leads to the melting of a solid into a fluid and eventually vaporises the liquid into a gaseous phase of matter.…
We study first order phase transitions that occur when the temperature of the system increases and we identify the conditions that lead to super-heating, a phase where the system can heat up arbitrarily. First order phase transitions with…
The origin of predicted and observed anomalies in caloric curves of nuclei and other mesoscopic systems is investigated. It is shown that a straightforward thermodynamical treatment of an evaporating liquid drop leads to a backbending in…
Whether the glass transition is caused by an underlying singularity or is a purely kinetic phenomenon is a significant outstanding question. Studying an atomistic glass former, we introduce a sampling method to access temperatures…
For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for system in…
Evaporation of a liquid drop surrounded by either vapor of the same fluid, or vapor and air, is usually attributed to vapor diffusion -- which, however, does not apply to the former setting, as pure fluids do not diffuse. The present paper…
Transition boiling is an intermediate regime occurring between nucleate boiling, where bubbles at the surface efficiently carry heat away, and film boiling, where a layer of vapor formed over the surface insulates the system reducing heat…
There hardly is a fluid mechanics phenomenon attracting more attention than the impact of a droplet, due to its undeniable beauty, many applications and the numerous challenges it poses. One of the crucial factors turns out to be the…
We study heat transfer from a heated nanoparticle into surrounding fluid, using molecular dynamics simulations. We show that the fluid next to the nanoparticle can be heated well above its boiling point without a phase change. Under…
We show that the vacuum (zero-point) energy of a low-temperature quantum liquid is a variable property which changes with the state of the system, in notable contrast to the static vacuum energy in solids commonly considered. We further…
Classical phase transitions, like solid-liquid-gas or order-disorder spin magnetic phases, are all driven by thermal energy fluctuations by varying the temperature. On the other hand, quantum phase transitions happen at absolute zero…
Boiling is a very efficient way to transfer heat from a heater to the liquid carrier. We discuss the boiling crisis, a transition between two regimes of boiling: nucleate and film boiling. The boiling crisis results in a sharp decrease in…
Tetrahedral liquids such as water and silica-melt show unusual thermodynamic behavior such as a density maximum and an increase in specific-heat when cooled to low temperatures. There is a debate in the literature whether these phenomena…
The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the drop is assumed to be in thermodynamic equilibrium with the vapour emanated from it. Changing pressure along the liquid-gas coexistence line…
Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…
How high the temperature of a liquid be raised beyond its boiling point without vaporizing (known as the limit of superheat) is an interesting subject of investigation. A new method of finding the limit of superheat of liquids is presented…
This article is a continuation of our previous works (see Yukhnovskii I.R. et al., J. Stat. Phys, 1995, 80, 405 and references therein), where we have described the behavior of a simple system of interacting particles in the region of…