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A molecular theory of the glass transition of network forming liquids is developed using a combination of self-consistent phonon and liquid state approaches. Both the dynamical transition and the entropy crisis characteristic of random…

Condensed Matter · Physics 2009-11-07 Randall W. Hall , Peter G. Wolynes

We review the inherent structure thermodynamical formalism and the formulation of an equation of state for liquids in equilibrium based on the (volume) derivatives of the statistical properties of the potential energy surface. We also show…

Soft Condensed Matter · Physics 2009-11-07 S. Mossa , E. La Nave , P. Tartaglia , F. Sciortino

The review of the modern results in the theoretical and experimental study of the localized interacting electrons is given. After theoretical prediction of the Coulomb gap and the new temperature law in the variable range hopping conduction…

Strongly Correlated Electrons · Physics 2007-05-23 A. L. Efros

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We study the statistical mechanics of supercooled liquids when the system evolves at a temperature $T$ with a field $\epsilon$ linearly coupled to its overlap with a reference configuration of the same liquid sampled at a temperature $T_0$.…

Statistical Mechanics · Physics 2022-04-05 Benjamin Guiselin , Ludovic Berthier , Gilles Tarjus

We analyze a simple dynamical model of glasses, based on the idea that each particle is trapped in a local potential well, which itself evolves due to hopping of neighbouring particles. The glass transition is signalled by the fact that the…

Condensed Matter · Physics 2009-10-28 Jean-Philippe Bouchaud , Alain Comtet , Cécile Monthus

We study the interplay between the fluid-crystal transition and the glass transition of elastic sphere system with polydispersity using nonequilibrium molecular dynamics simulations. It is found that the end point of the crystal-fluid…

Statistical Mechanics · Physics 2010-09-29 Tomoaki Nogawa , Nobuyasu Ito , Hiroshi Watanabe

We use computer simulations to study the glass transition of dense fluids made of polydisperse, repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Thomas A. Witten

A comprehensive microscopic dynamical theory is presented for the description of quantum fluids as they transform into glasses. The theory is based on a quantum extension of mode-coupling theory. Novel effects are predicted, such as…

Within the framework of the mode-coupling theory of super-cooled liquids, we investigate new phenomena in colloidal systems on approach to their glass transitions. When the inter-particle potential contains an attractive part, besides the…

Soft Condensed Matter · Physics 2009-11-07 K. A. Dawson , G. Foffi , F. Sciortino , P. Tartaglia , E. Zaccarelli

We perform kinetic Monte Carlo simulations of a distinguishable-particle lattice model of structural glasses with random particle interactions. By varying the interaction distribution and the average particle hopping energy barrier, we…

Soft Condensed Matter · Physics 2021-01-04 Chun-Shing Lee , Matteo Lulli , Ling-Han Zhang , Hai-Yao Deng , Chi-Hang Lam

Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled or compressed in such a fashion that it does not crystallise. Almost all types of materials are capable of glass formation -- polymers, metal…

Statistical Mechanics · Physics 2009-10-31 Srikanth Sastry

In active microrheology the mechanical properties of a material are tested by adding probe particles which are pulled by an external force. In case of supercooled liquids, strong forcing leads to a thinning of the host material which…

Soft Condensed Matter · Physics 2016-01-20 Carsten F. E. Schroer , Andreas Heuer

Molecular dynamics simulations of a glass-forming model system are performed under application of a microrheological perturbation on a tagged particle. The trajectory of that particle is studied in its underlying potential energy landscape.…

Statistical Mechanics · Physics 2015-06-11 Carsten F. E. Schroer , Andreas Heuer

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

Soft Condensed Matter · Physics 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

One of the most controversial hypotheses for explaining the heterogeneous dynamics of glasses postulates the temporary coexistence of two phases characterized by a high and by a low diffusivity. In this scenario, two phases with different…

Soft Condensed Matter · Physics 2015-07-16 R. Pastore , A. Coniglio , M. Pica Ciamarra

We present experimental confirmation of dynamic facilitation in monodisperse and bidisperse colloidal suspensions near the glass transition volume fraction. Correlations in particle dynamics are seen to exist not only in space (clusters and…

Soft Condensed Matter · Physics 2014-06-24 Scott V. Franklin , Eric R. Weeks

The onset of structural arrest and glass formation in a concentrated suspension of silica nanoparticles in a water-lutidine binary mixture near its consolute point is studied by exploiting the near-critical fluid degrees of freedom to…

Soft Condensed Matter · Physics 2009-11-13 Xinhui Lu , S. G. J. Mochrie , S. Narayanan , A. R. Sandy , M. Sprung

When liquids are classified using Tg -scaled Arrhenius plots of relaxation times (or relative rates of entropy increase above Tg) across a "strong-fragile" spectrum of behaviors, the "strong" liquids have always appeared rather…

Soft Condensed Matter · Physics 2015-06-12 C. Austen Angell , Mahin Hemmati

By characterizing the dynamics of idealized lattice models with a tunable kinetic constraint, we explore the different ways in which dynamical facilitation manifests itself within the local dynamics of glassy materials. Dynamical…

Statistical Mechanics · Physics 2012-06-25 Yael S. Elmatad , Aaron S. Keys