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The optical/infrared properties of films of vanadium dioxide (VO2) and vanadium sesquioxide (V2O3) have been investigated via ellipsometry and near-normal incidence reflectance measurements from far infrared to ultraviolet frequencies.…

Strongly Correlated Electrons · Physics 2009-11-13 M. M. Qazilbash , A. A. Schafgans , K. S. Burch , S. J. Yun , B. G. Chae , B. J. Kim , H. T. Kim , D. N. Basov

We present a density-functional theory (DFT) study of the structural, electronic, and chemical bonding behaviour in germanium (Ge)-doped vanadium dioxide (VO$_2$). Our motivation is to explain the reported increase of the metal-insulator…

Materials Science · Physics 2023-02-03 Peter Mlkvik , Claude Ederer , Nicola A. Spaldin

$VO_2$ undergoes the insulator-metal transition (IMT) and monoclinic-rutile structural phase transition (SPT) near $67^oC$. The IMT switching has many applications. However, there is an unresolved issue whether the IMT is a Mott transition…

Strongly Correlated Electrons · Physics 2021-01-18 Chang-Yong Kim , Tetiana Slusar , Jinchul Cho , Hyun-Tak Kim

Many strongly correlated electronic materials, including high-temperature superconductors, colossal magnetoresistance and metal-insulator-transition (MIT) materials, are inhomogeneous on a microscopic scale as a result of domain structure…

Mesoscale and Nanoscale Physics · Physics 2012-09-05 Jiang Wei , Zenghui Wang , Wei Chen , David H. Cobden

Ultrafast phase transitions induced by femtosecond light pulses present a new opportunity for manipulating the properties of materials. Understanding how these transient states are different from, or similar to, their thermal counterparts…

Electrically driven metal-insulator transition in vanadium dioxide (VO2) is of interest in emerging memory devices, neural computation, and high speed electronics. We report on the fabrication of out-of-plane VO2 metal-insulator-metal (MIM)…

Mesoscale and Nanoscale Physics · Physics 2013-07-16 You Zhou , Xiaonan Chen , Changhyun Ko , Zheng Yang , Chandra Mouli , Shriram Ramanathan

The temperature dependence of the Mott metal-insulator transition (MIT) is studied with a VO_2-based two-terminal device. When a constant voltage is applied to the device, an abrupt current jump is observed with temperature. With increasing…

Strongly Correlated Electrons · Physics 2015-06-25 Bong-Jun Kim , Yong Wook Lee , Byung-Gyu Chae , Sun Jin Yun , Soo-Young Oh , Young-Sik Lim , Hyun-Tak Kim

V2O3 is the prototype system for the Mott transition, one of the most fundamental phenomena of electronic correlation. Temperature, doping or pressure induce a metal to insulator transition (MIT) between a paramagnetic metal (PM) and a…

We present a spectroscopic study that reveals that the metal-insulator transition of strained VO$_2$ thin films may be driven towards a purely electronic transition, which does not rely on the Peierls dimerization, by the application of…

Correlated electron materials (CEMs) host a rich variety of condensed matter phases. Vanadium dioxide (VO2) is a prototypical CEM with a temperature-dependent metal-to-insulator (MIT) transition with a concomitant crystal symmetry change.…

Among the complex many-body systems, the metal-insulator transition stands out as a cornerstone and a particularly fertile ground for scientific inquiry. The established models including Mott insulator, Anderson localization and Peierls…

Strongly Correlated Electrons · Physics 2025-11-11 Liucheng Chen , Jiayi Yue , Jingwen Cheng , Jianli Bai , Zexiao Zhang , Xiaoli Ma , Fang Hong , Genfu Chen , Jian-Tao Wang , Zhijun Wang , Xiaohui Yu

The electronic structure of the vanadium dioxide VO_2 in the tetragonal R and two monocinic M_1 and M_2 structural modifications was calculated in frames of the local-density functional (LDA) approach and the LSDA + U formalism of…

Strongly Correlated Electrons · Physics 2007-05-23 M. A. Korotin , N. A. Skorikov , V. I. Anisimov

Appropriate consideration of the electron correlation is essential to reproduce the intriguing metal-insulator transition accompanying the Peierls-type structural transition in VO$_2$. In the density functional theory-based approach, this…

Strongly Correlated Electrons · Physics 2021-03-16 Sooran Kim

Coupled structural and electronic phase transitions underlie the multifunctional properties of strongly-correlated materials. For example, colossal magnetoresistance1,2 in manganites involves phase transition from paramagnetic insulator to…

Strongly Correlated Electrons · Physics 2010-03-23 Joyeeta Nag , Richard Haglund , Andrew Payzant , Karren More

We report the simultaneous measurement of the structural and electronic components of the metal-insulator transition of VO$_2$ using electron and photoelectron spectroscopies and microscopies. We show that these evolve over different…

Strongly Correlated Electrons · Physics 2014-11-18 J. Laverock , S. Kittiwatanakul , A. A. Zakharov , Y. R. Niu , B. Chen , S. A. Wolf , J. W. Lu , K. E. Smith

The metal-insulator transition (MIT) in correlated oxide systems opens up a new paradigm to trigger the abruption in multiple physical functionalities, enabling the possibility in unlocking exotic quantum states beyond conventional phase…

Strongly Correlated Electrons · Physics 2025-10-23 Xiaohui Yao , Jiahui Ji , Xuanchi Zhou

We discuss the mechanisms behind the electrically driven insulator-metal transition in single crystalline VO$_2$ nanobeams. Our DC and AC transport measurements and the versatile harmonic analysis method employed show that non-uniform Joule…

Strongly Correlated Electrons · Physics 2019-08-17 Sujay Singh , Gregory Horrocks , Peter M Marley , Zhenzhong Shi , Sarbajit Banerjee , G. Sambandamurthy

We present a detailed account of the physics of Vanadium sesquioxide (${\rm V_2O_3}$), a benchmark system for studying correlation induced metal-insulator transition(s). Based on a detailed perusal of a wide range of experimental data, we…

Strongly Correlated Electrons · Physics 2009-11-11 M. S. Laad , L. Craco , E. Müller-Hartmann

The electrodynamics near the metal-to-insulator transitions (MIT) induced, in V3O5 single crystals, by both temperature (T) and pressure (P) has been studied by infrared spectroscopy. The T- and P-dependence of the optical conductivity may…

Strongly Correlated Electrons · Physics 2009-11-13 L. Baldassarre , A. Perucchi , E. Arcangeletti , D. Nicoletti , D. Di Castro , P. Postorino , V. A. Sidorov , S. Lupi

Vanadium dioxide is of broad interest as a spin-1/2 electron system that realizes a metal-insulator transition near room temperature, due to a combination of strongly correlated and itinerant electron physics. Here, resonant inelastic X-ray…

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