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We report the discovery of a new pyrochlore oxide superconductor RbOs2O6. The compound crystallizes in the same beta-pyrochlore structure as the recently discovered superconductor KOs2O6, where Os atoms form a corner-sharing tetrahedral…

Superconductivity · Physics 2009-11-10 S. Yonezawa , Y. Muraoka , Y. Matsushita , Z. Hiroi

We report the basic thermodynamic properties of the new geometrically frustrated beta-pyrochlore bulk superconductor RbOs2O6 with a critical temperature Tc = 6.4 K. Specific heat measurements are performed in magnetic fields up to 12 T. The…

Superconductivity · Physics 2009-11-10 M. Brühwiler , S. M. Kazakov , N. D. Zhigadlo , J. Karpinski , B. Batlogg

Rattling-induced superconductivity in the beta-pyrochlore oxide RbOs2O6 is investigated under high pressures up to 6 GPa. Resistivity measurements in a high-quality single crystal show that the superconducting transition temperature Tc…

Superconductivity · Physics 2011-10-04 Nao Takeshita , Hiroki Ogusu , Jun-ichi Yamaura , Yoshihiko Okamoto , Zenji Hiroi

RbOs2O6, the third superconducting pyrochlore oxide (known so far), has been synthesized by encapsulation and by high pressure techniques. Suitable post chemical treatment of the as-prepared sample allowed us to eliminate the impurity…

Superconductivity · Physics 2009-11-10 S. M. Kazakov , N. D. Zhigadlo , M. Brühwiler , B. Batlogg , J. Karpinski

Two beta-pyrochlore oxide superconductors, CsOs2O6 and RbOs2O6, are studied thermodynamically by measuring specific heat on polycrystalline samples. It is found that a Sommerfeld coefficient ? is nearly equal, 20 mJ/K2 mol Os, in the two…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Shigeki Yonezawa , Takaki Muramatsu , Jun-Ichi Yamaura , Yuji Muraoka

The discovery of a new beta-pyrochlore oxide superconductor CsOs2O6 with Tc = 3.3 K is reported. It is the third superconductor in the family of beta-pyrochlore oxides, following KOs2O6 with Tc = 9.6 K and RbOs2O6 with Tc = 6.3 K. The Tc of…

Superconductivity · Physics 2009-11-10 Shigeki Yonezawa , Yuji Muraoka , Zenji Hiroi

Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…

Superconductivity · Physics 2009-11-13 K. Miyoshi , Y. Takaichi , Y. Takamatsu , M. Miura , J. Takeuchi

Superconductivity in the potassium osmium oxide KOs2O6 crystallizing in the beta-pyrochlore structure is studied by means of electrical resistivity, magnetic susceptibility and specific heat. It is the second superconductor in the family of…

Superconductivity · Physics 2009-11-10 Z. Hiroi , S. Yonezawa , Y. Muraoka

We report a precise $^{59}$Co nuclear quadrupolar resonance (NQR) measurement on the recently discovered cobalt oxyhydrate Na$_{0.35}$CoO$_{2}$$\cdot y$H$_{2}$O superconductor from $T$=40 K down to 0.2 K. We find that in the normal state…

Superconductivity · Physics 2009-11-10 T. Fujimoto , G. -q. Zheng , Y. Kitaoka , R. L. Meng , J. Cmaidalka , C. W. Chu

We have investigated a gap structure in a newly-discovered superconductor, MgB2 through the measurement of 11B nuclear spin-lattice relaxation rate, ^{11}(1/T_1). ^{11}(1/T_1) is proportional to the temperature (T) in the normal state, and…

Superconductivity · Physics 2009-11-07 H. Kotegawa , K. Ishida , Y. Kitaoka , T. Muranaka , J. Akimitsu

We develop a general procedure for the analysis of bulk thermodynamic data of a superconductor for samples containing a metallic non-superconducting second phase. The method is based on the condensation energy and it allows the extraction…

Superconductivity · Physics 2009-11-11 M. Brühwiler , S. M. Kazakov , J. Karpinski , B. Batlogg

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…

Superconductivity · Physics 2015-06-25 Z Hiroi , S Yonezawa , J Yamaura

The superconducting properties of two beta-pyrochlore oxides, CsOs2O6 and RbOs2O6, are studied by thermodynamic and transport measurements using high-quality single crystals. It is shown that the character of superconductivity changes…

Superconductivity · Physics 2009-08-05 Yohei Nagao , Jun-ichi Yamaura , Hiroki Ogusu , Yoshihiko Okamoto , Zenji Hiroi

{\ss}-pyrochore KOs2O6, which shows superconductivity below ~ 9.7K, has been converted into KxOs2O6 (x < 2/3 - 1/2) electrochemically to show spin glass-like behavior below ~ 6.1K. Room temperature sample surface potential versus charge…

Superconductivity · Physics 2015-05-27 C. C. Lee , W. L. Lee , J. -Y. Lin , C. C. Tsuei , J. G. Lin , F. C. Chou

Superconducting and normal-state properties of the beta-pyrochlore oxide KOs2O6 are studied by means of thermodynamic and transport measurements. It is shown that the superconductivity is of conventional s-wave type and lies in the…

Superconductivity · Physics 2009-11-13 Z. Hiroi , S. Yonezawa , Y. Nagao , J. Yamaura

We report the $^{121/123}$Sb-NMR/nuclear quadrupole resonance (NQR) measurements on the newly-discovered superconductor BaTi$_2$Sb$_2$O with a two-dimensional Ti$_2$O square-net layer formed with Ti$^{3+}$ (3$d^1$). NQR measurements…

Superconductivity · Physics 2013-03-04 S. Kitagawa , K. Ishida , K. Nakano , T. Yajima , H. Kageyama

We report $^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies on the superconductor Rb$_{2}$Cr$_{3}$As$_{3}$ with a quasi one-dimensional crystal structure. Below $T\sim$ 100 K, the spin-lattice…

Superconductivity · Physics 2015-10-07 J. Yang , Z. T. Tang , G. H. Cao , Guo-qing Zheng

A high quality superconducting Li$_{0.68}$NbO$_2$ polycrystalline sample was synthesized by deintercalation of Li ions from Li$_{0.93}$NbO$_2$. The field dependent resistivity and specific heat were measured down to 0.5 K. The upper…

Superconductivity · Physics 2009-11-11 G. T. liu , J. L. Luo , Z. Li , Y. Q. Guo , N. L. Wang , D. Jin , T. Xiang

Electronic, magnetic, and dynamical properties of the new superconducting $\beta$-pyrochlore KOs$_2$O$_6$ and related RbOs$_2$O$_6$ and CsOs$_2$O$_6$ compounds are calculated and compared with experiment and contrasted with structurally…

Superconductivity · Physics 2009-11-10 J. Kunes , T. Jeong , W. E. Pickett
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