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Single molecule imaging is one of the main target areas of X-ray free electron lasers. It relies on the possibility of orienting the large number of low counting statistics 2D diffraction patterns taken at random orientations of identical…

Atomic and Molecular Clusters · Physics 2012-11-30 Zoltan Jurek , Gyula Faigel

In this perspective, the various measures of electron correlation used in wavefunction theory, density functional theory and quantum information theory are briefly reviewed. We then focus on a more traditional metric based on dominant…

Chemical Physics · Physics 2023-04-07 Róbert Izsák , Aleksei V Ivanov , Nick S. Blunt , Nicole Holzmann , Frank Neese

Protein rotational kinetics are essential for understanding macromolecular behavior in crowded environments, yet measuring these dynamics at solid-liquid interfaces remains a significant challenge due to low signal strengths. Here, we…

We previously derived a theorem about the {\em coherent} quasielastic neutron-scattering signal from a $d$-dimensional lattice of $N$ molecules that are undergoing rotational jump diffusion (around an $n$-fold axis), assuming that there are…

Materials Science · Physics 2009-11-07 G. Coddens

The dependence of inter-particle correlations on the orientation of particle relative-momentum can yield unique information on the space-time features of emission in reactions with multiparticle final states. In the present paper, the…

Nuclear Theory · Physics 2008-11-26 Pawel Danielewicz , Scott Pratt

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to…

Quantum Physics · Physics 2012-12-18 Katharina Boguslawski , Paweł Tecmer , Örs Legeza , Markus Reiher

Single fluorescent molecules, behaving as ideal electric dipole emitters, are powerful nanoscopic probes of complex optical fields. Here, this property is exploited to precisely map the polarization and vectorial structure of tightly…

In the framework of the signal processing approach to single-atom resonance fluorescence with spectral resolution, we diagrammatically derive an analytical formula for arbitrary-order spectral correlation functions of the scattered fields…

Quantum Physics · Physics 2016-09-21 Vyacheslav N. Shatokhin , Sergei Ya. Kilin

We prove that it is impossible to distinguish two spatially coinciding fluorescent molecules from a single rotating molecule using polarization-sensitive imaging, even if one modulates the polarization of the illumination or the detection…

Optics · Physics 2025-03-11 Yiyang Chen , Yuanxin Qiu , Matthew D. Lew

Constitutive equations for the long-wavelength behaviour of the orientational dynamics of a super-cooled liquid are derived using a projection-operator technique and resulting expressions for light-scattering spectra are formulated. We thus…

Soft Condensed Matter · Physics 2007-05-23 Maximilian G. Schultz , Thomas Franosch

The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these…

Chemical Physics · Physics 2024-03-06 Jutta Toscano

The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic…

Condensed Matter · Physics 2009-10-22 N. Manini , S. Oss

The effects of short-range correlations derived from a realistic meson-exchange potential on the single-particle density matrix in finite nuclei are investigated by analyzing the one-body density in terms of the natural orbits. Basic…

Nuclear Theory · Physics 2016-09-08 A. Polls , H. Müther , W. H. Dickhoff

The Hamiltonian for a small number, N <= 11, of bosons in a rapidly rotating harmonic trap, interacting via a short range (contact potential) or a long range (Coulomb) interaction, is studied via an exact diagonalization in the lowest…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Leslie O. Baksmaty , Constantine Yannouleas , Uzi Landman

The nonlinear theory of anomalous diffusion is based on particle interactions giving an explicit microscopic description of diffusive processes leading to sub-, normal, or super-diffusion as a result competitive effects between attractive…

Statistical Mechanics · Physics 2016-01-20 Jean Pierre Boon , James F. Lutsko

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counter-clockwise rotating molecules (with respect to a fixed…

Chemical Physics · Physics 2021-05-05 Alexander A. Milner , Valery Milner

A full characterization of nonclassical space-time dependent correlations of radiation is formulated in terms of normally and time-ordered field correlation functions. It describes not only the properties of initially prepared multimode…

Quantum Physics · Physics 2009-11-13 Werner Vogel

We perform event-driven molecular dynamics simulations of a system composed by uniaxial hard ellipsoids for different values of the aspect-ratio and packing fraction . We compare the molecular orientational-dependent structure factors…

Soft Condensed Matter · Physics 2012-07-06 Cristiano De Michele , Antonio Scala , Rolf Schilling , Francesco Sciortino

Several laser techniques have been suggested and demonstrated recently for preparing polarizable molecules in rapidly spinning states with a disc-like angular distribution. We consider motion of these spinning discs in inhomogeneous fields,…

Chemical Physics · Physics 2015-05-20 Johannes Floss , Erez Gershnabel , Ilya Sh. Averbukh

A key to building functional devices on the basis of single molecule magnets in the framework of molecular electronics is the ability to deposit and study these molecules on a surface, because the structural, electronic and magnetic…

Mesoscale and Nanoscale Physics · Physics 2016-01-26 Judith Donner , Jan-Philipp Broschinski , Bastian Feldscher , Anja Stammler , Hartmut Bögge , Thorsten Glaser , Daniel Wegner