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Based on the domain variational point of view, we carry on stability analysis on two shape optimization problems from thermal insulation background. The novelty is that, we do not require that the second variation is normal to the boundary.…
The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…
Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…
We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…
We follow the Boltzmann-Clausius-Maxwell (BCM) proposal to solve a long-standing problem of identifying the underlying cause of the second law (SL) of spontaneous irreversibility, a stochastic universal principle, as the mechanical…
We study the late-time dynamics of two particles confined in one spatial dimension and subject to two-body losses. The dynamics is exactly described by a non-Hermitian Hamiltonian that can be analytically studied both in the continuum and…
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…
Time-integrated quantities such as work and heat increase incessantly in time during nonequilibrium processes near steady states. In the long-time limit, the average values of work and heat become asymptotically equivalent to each other,…
Chemical equilibrium is fully characterized by thermodynamics, while the rates of chemical reactions can be calculated for ideal solutions by using mass-action equations. The evaluation of the rates of reactions in a non-ideal system is…
The Thermal Boundary Resistance at the interface between a nanosized Al film and an Al_{2}O_{3} substrate is investigated at an atomistic level. A room temperature value of 1.4 m^{2}K/GW is found. The thermal dynamics occurring in…
Out of thermal equilibrium, an environment imposes effective mechanical forces on microscopical nanofabricated devices, chemical or biological systems. Here we address the question of how to calculate these forces together with the response…
We consider a one-dimensional system consisting of two infinite ideal fluids, with equal pressures but different temperatures T_1 and T_2, separated by an adiabatic movable piston whose mass M is much larger than the mass m of the fluid…
In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…
We prove a limit theorem for an integral functional of a Markov process. The Markovian dynamics is characterized by a linear Boltzmann equation modeling a one-dimensional test particle of mass $\lambda^{-1}\gg 1$ in an external periodic…
An explicit dynamical model for non relativistic quantum mechanics with an effective gravitational interaction is proposed, which, as being well defined, allows in principle for the evaluation of every physical quantity. Its non unitary…
A theoretical analysis of the thermodynamic properties of the Robin wall characterized by the extrapolation length $\Lambda$ in the electric field $\mathscr{E}$ that pushes the particle to the surface is presented both in the canonical and…
The principle of microscopic reversibility is a fundamental element in the formulation of fluctuation relations and the Onsager reciprocal relations. As such, a clear description of whether and how this principle is adapted to the quantum…
We consider a free fermion chain with uniform nearest-neighbor hopping and let it evolve from an arbitrary initial state with a fixed macroscopic number of particles. We then prove that, at a sufficiently large and typical time, the…
In special relativity the mathematical expressions, defining physical observables as the momentum, the energy etc, emerge as one parameter (light speed) continuous deformations of the corresponding ones of the classical physics. Here, we…
Jarzynski's equality sets a strong bound on the probability of violating the second law of thermodynamics by extracting work beyond the free energy difference. We derive finite-time refinements to this bound for driven systems in contact…