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Phonon spectra have been investigated by micro-Raman scattering from 290 to 20K. New peaks at 500 and 674 cm-1 appear below 250K in MgB2. These peaks are explained by the Fermi resonance, where Raman-active E2g intereacts with the overtone…

Superconductivity · Physics 2007-05-23 N. Ogita , T. Kariya , K. Hiraoka , J. Nagamatsu , T. Muranaka , H. Takagiwa , J. Akimitsu , M. Udagawa

Probing phonons, quasi-particle excitations and their coupling has enriched our understanding of these 2D materials and proved to be crucial for developing their potential applications. Here, we report comprehensive temperature, 4-330 K,…

Materials Science · Physics 2022-03-14 Deepu Kumar , Vivek Kumar , Rahul Kumar , Mahesh Kumar , Pradeep Kumar

We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

The Raman spectrum of the $B_{1g}$ phonon in the superconducting cuprate materials is investigated theoretically in detail in both the normal and superconducting phases, and is contrasted with that of the $A_{1g}$ phonon. A mechanism…

Condensed Matter · Physics 2009-10-22 T. P. Devereaux , A. Virosztek , A. Zawadowski

Single crystals of the spin-gap system $\rm (VO)_2P_2O_7$ have been investigated by means of Raman scattering. At temperatures below T=75 K~$\approx 2\Delta_{01}({\bf k}=0)$, with $\Delta_{01}$ the singlet-triplet gap, a shoulder appears at…

Superconductivity · Physics 2009-10-31 M. Grove , P. Lemmens , G. Güntherodt , B. C. Sales , F. Büllesfeld , W. Assmus

We present a systematic study of the interplay between lattice parameters and the energy of the optical phonons as well as the antiferromagnetic coupling strength, $J$, in the high-$T_{\text{c}}$ superconducting cuprate…

Strongly Correlated Electrons · Physics 2019-04-24 Silvia Müllner , Wayne Crump , Dirk Wulferding , Benjamin P. P. Mallett , Peter Lemmens , Amit Keren , Jeffery L. Tallon

We report measurements of the phonon dispersion relations in non-superconducting, oxygen-deficient PrBa2Cu3O6+x (x ~ 0.2) by inelastic neutron scattering. The data are compared with a model of the lattice dynamics based on a common…

Ruddlesden-Popper nickelates exhibit high-temperature superconductivity closely intertwined with charge and spin density wave order. However, fundamental questions persist regarding the interplay between the associated density wave (DW)…

Raman spectra from silicon nanostructures, recorded using excitation laser power density of 1.0 kW/cm^2, is employed here to reveal the dominance of thermal effects at temperatures higher than the room temperature. Room temperature Raman…

Mesoscale and Nanoscale Physics · Physics 2012-01-25 Rajesh Kumar , Vivek Kumar , A. K. Shukla

Phonon spectrum of cubic barium zirconate is calculated from first principles using the density functional theory. Unstable phonon mode with the $R_{25}$ symmetry in the phonon spectrum indicates an instability of the cubic structure with…

Materials Science · Physics 2015-08-18 A. I. Lebedev , I. A. Sluchinskaya

We report low-temperature Raman signatures of the Heisenberg quantum magnet Ca$_{10}$Cr$_7$O$_{28}$, showing clear anomalies in phonon mode frequencies and linewidths below $\sim$100 K. This crossover temperature lies in between the…

Strongly Correlated Electrons · Physics 2023-12-12 Srishti Pal , Arnab Seth , Anzar Ali , Yogesh Singh , D. V. S. Muthu , Subhro Bhattacharjee , A. K. Sood

We conduct first-principles theoretical studies to investigate the temperature-dependent phonon properties of orthorhombic SrZrO$_3$ (SZO) perovskite. Our calculations include the quasiharmonic approximation, in which we explored mode…

Materials Science · Physics 2023-09-06 P. K. Verma

We report a Raman scattering study of nematic degrees of freedom in the iron-based superconductor parent compound BaFe$_2$As$_2$ under tunable uniaxial strain. We demonstrate that the polarization resolved arsenic (As) phonon intensity can…

Superconductivity · Physics 2022-02-02 J. -C. Philippe , J. Faria , A. Forget , D. Colson , S. Houver , M. Cazayous , A. Sacuto , Y. Gallais

Polarized Raman scattering has been performed on CaC6 superconductor. We identify two of the three Raman active Eg phonon modes at 440 and 1508 cm-1 expected for the R-3m space group of CaC6. These first order scattering modes appear along…

Materials Science · Physics 2009-11-13 A. Mialitsin , J. S. Kim , R. K. Kremer , G. Blumberg

We performed Raman spectroscopy measurements under temperature changes from 10 K up to 850 K to probe the phonon-spin coupling in Y$_2$NiMnO$_6$. The spin-phonon coupling was observed as a softening of the stretching mode, indicating this…

With polarized and angle-resolved Raman spectroscopy studies on single two-dimensional layered perovskites (2DLP) flakes with different ammonium molecules as organic cations, in 2020 we revealed the very rich phonon spectra in the…

Materials Science · Physics 2024-08-20 Roman Krahne , Miao-Ling Lin , Ping-Heng Tan

The optical conductivity spectra of the rattling phonons in the clathrate Ba$_8$Ga$_{16}$Ge$_{30}$ are investigated in detail by use of the terahertz time-domain spectroscopy. The experiment has revealed that the lowest-lying vibrational…

Materials Science · Physics 2015-06-05 K. Iwamoto , S. Kushibiki , H. Honda , S. Kajitani , T. Mori , H. Matsumoto , N. Toyota , K. Suekuni , M. A. Avila , T. Takabatake

With the use of lattice dynamics calculation within hybrid HSE06 framework we were able to understand vibrational spectra of MAgF3 M = K, Rb, Cs compounds. Comparative theoretical study uncovered lack of monotonicity in calculated optical…

Materials Science · Physics 2022-01-17 Kacper Koteras , Jakub Gawraczynski , Gasper Tavcar , Zoran Mazej , Wojciech Grochala

We report a Raman scattering investigation of multiferroic bismuth ferrite BiFeO3 epitaxial (c-axis oriented) thin films from -192 to 1000C. Phonon anomalies have been observed in three temperature regions: in the gamma-phase from 930C to…

Materials Science · Physics 2015-05-14 R. Palai , J. F. Scott , R. S. Katiyar

We have measured the polarized Raman scattering spectra of Cd2Re2O7, the first superconducting pyrochlore, as a function of temperature. For temperatures below the cubic-to-tetragonal structural phase transition (SPT) at 200K, a peak with…

Materials Science · Physics 2007-05-23 C. A. Kendziora , I. A. Sergienko , R. Jin , J. He , V. Keppens , B. C. Sales , D. Mandrus
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